On the selective transformation of ethanol over Mg- and/or La-containing mixed oxides catalysts

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorBallesteros Plata, D.es_ES
dc.contributor.authorBalestra, G.es_ES
dc.contributor.authorCecilia, J.A.es_ES
dc.contributor.authorBarroso Martín, I.es_ES
dc.contributor.authorInfantes-Molina, A.es_ES
dc.contributor.authorTabanelli, T.es_ES
dc.contributor.authorCavani, F.es_ES
dc.contributor.authorLópez Nieto, José Manuel
dc.contributor.authorMontaña, M.es_ES
dc.contributor.authorRodríguez Castellón, E.es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderAgencia Estatal de Investigaciónes_ES
dc.contributor.funderEuropean Regional Development Fundes_ES
dc.contributor.funderMinisterio de Ciencia e Innovaciónes_ES
dc.contributor.funderUniversitat Politècnica de Valènciaes_ES
dc.date.accessioned2024-06-06T18:16:03Z
dc.date.available2024-06-06T18:16:03Z
dc.date.issued2024-03-01es_ES
dc.description.abstract[EN] MgO-La2O3 catalysts with different Mg/La molar ratio were synthesized by a precipitation method and a subsequent calcination and then characterized by x-ray diffraction, N2 adsorption-desorption isotherms (at-196 degrees C), CO2- and NH3-thermoprogrammed desorption and x-ray photoelectronic spectroscopy. The coexistence of acid and basic sites promoted the selective transformation of ethanol into valuable products. Thus, MgO catalyst promoted the Guerbet reaction obtaining n-butanol as product while the incorporation of La2O3 in the catalytic system improved the ethanol conversion notably, obtaining ethylene as the main product due to a dehydration reaction. The highest ethylene yield was obtained for the catalyst with a Mg/La molar ratio of 1.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationBallesteros Plata, D.; Balestra, G.; Cecilia, J.; Barroso Martín, I.; Infantes-Molina, A.; Tabanelli, T.; Cavani, F.... (2024). On the selective transformation of ethanol over Mg- and/or La-containing mixed oxides catalysts. Catalysis Today. 429. https://doi.org/10.1016/j.cattod.2023.114470es_ES
dc.description.sponsorshipThe funding received for this study from the Spanish Ministry of Science and Innovation, PID2021-126235OB-C31 and PID2021-126235OB-C32 funded by MCIN/AEI/10.13039/501100011033 and FEDER funds, and projects TED2021-130756B-C31 and TED2021-130756B-C32 funded by MCIN/AEI/10.13039/501100011033 and by "ERDF A way of making Europe" by the European Union NextGenerationEU/PRTR, is acknowledged.es_ES
dc.description.volume429es_ES
dc.identifier.doi10.1016/j.cattod.2023.114470es_ES
dc.identifier.issn0920-5861es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/204769
dc.languageIngléses_ES
dc.publisherElsevieres_ES
dc.relation.ispartofCatalysis Todayes_ES
dc.relation.pasarelaS\513596es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-126235OB-C31/ES/CO2 COMO MATERIA PRIMA EN LA TERMOCATALISIS Y SU TRANSFORMACION EN COMBUSTIBLES Y PRODUCTOS QUIMICOS/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-126235OB-C32/ES/DESIGN OF SUSTAINABLE MATERIALS FOR N2O Y CO2 CAPTURE AND CATALYTIC VALORIZATION/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI//TED2021-130756B-C32/ES/Desarrollo de nuevos catalizadores para reformado en seco y reacciones WGS de biogás y su impacto en la producción sostenible de hidrógeno verde a partir de biogás/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//TED2021-130756B-C31/es_ES
dc.relation.publisherversionhttps://doi.org/10.1016/j.cattod.2023.114470es_ES
dc.rightsReconocimiento - No comercial - Sin obra derivada (by-nc-nd)es_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectEthanoles_ES
dc.subjectEthylenees_ES
dc.subjectAcetaldehydees_ES
dc.subjectButanoles_ES
dc.subjectGas-phasees_ES
dc.subjectHeterogenous catalystes_ES
dc.titleOn the selective transformation of ethanol over Mg- and/or La-containing mixed oxides catalystses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
opencost.amount.paid3150es_ES
person.identifier188746
person.identifier.orcid0000-0002-6960-3219
relation.isAuthorOfPublication66ccfe1a-9f3d-4005-b82b-586747838f24
relation.isAuthorOfPublication.latestForDiscovery66ccfe1a-9f3d-4005-b82b-586747838f24
relation.isOrgUnitOfPublicationb97c2806-5147-442a-a1a8-a2c75cc2a941
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upv.uuidd70fb9d7-82db-457a-ba45-4b255df87ff0es_ES

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