Thermodynamic analysis of framework deformation in Na,Cs-RHO zeolite upon CO2 adsorption

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorPera-Titus, Marces_ES
dc.contributor.authorPalomino Roca, Miguel
dc.contributor.authorValencia Valencia, Susana
dc.contributor.authorRey Garcia, Fernando
dc.date.accessioned2017-07-17T10:48:09Z
dc.date.available2017-07-17T10:48:09Z
dc.date.issued2014
dc.description.abstract[EN] Fully dehydrated and partially sodium-cesium containing RHO zeolite (Na,Cs-RHO) shows a genuine inflection in the CO2 isotherms in the temperature range 293-333 K that can be attributed to a sorbate-induced framework deformation from an acentric (A) to a centric (C) phase due to a partial cation rearrangement. This peculiar sorption pattern can be captured by the formulation of thermodynamic isotherms, providing a direct enthalpic and entropic signature of the CO2 adsorption-desorption process during deformation. Using this formulation, the energy barrier between the acentric and centric phases for CO2 adsorption-desorption was estimated in the range 4.7-9.6 J g(-1) of solid (15-32 kJ mol(-1)), reflecting a higher CO2 affinity for the acentric phase, whereas the elastic energy involved during framework distortion was estimated in the range 6-12 J g(-1) of solid (19-39 kJ mol(-1)) with a relative maximum at 303 K and showing a dominant entropic contribution.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationPera-Titus, M.; Palomino Roca, M.; Valencia Valencia, S.; Rey Garcia, F. (2014). Thermodynamic analysis of framework deformation in Na,Cs-RHO zeolite upon CO2 adsorption. Physical Chemistry Chemical Physics. 16(44):24391-24400. doi:10.1039/C4CP03409Kes_ES
dc.description.issue44es_ES
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dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsCerradoes_ES
dc.subjectRHO zeolitees_ES
dc.subjectCO2 adsorptiones_ES
dc.subjectThermodynamic isothermses_ES
dc.subjectPhase transformationes_ES
dc.subjectZeolitees_ES
dc.subjectAdsorptiones_ES
dc.titleThermodynamic analysis of framework deformation in Na,Cs-RHO zeolite upon CO2 adsorptiones_ES
dc.typeArtículoes_ES
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