Nanolayered cobalt-molybdenum sulphides (Co-Mo-S) catalyse borrowing hydrogen C-S bond formation reactions of thiols or H2S with alcohols

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorSorribes-Terrés, Ivánes_ES
dc.contributor.authorCorma Canós, Avelino
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.date.accessioned2020-11-13T04:33:03Z
dc.date.available2020-11-13T04:33:03Z
dc.date.issued2019-03-14es_ES
dc.description.abstract[EN] Nanolayered cobalt-molybdenum sulphide (Co-Mo-S) materials have been established as excellent catalysts for C-S bond construction. These catalysts allow for the preparation of a broad range of thioethers in good to excellent yields from structurally diverse thiols and readily available primary as well as secondary alcohols. Chemoselectivity in the presence of sensitive groups such as double bonds, nitriles, carboxylic esters and halogens has been demonstrated. It is also shown that the reaction takes place through a hydrogen-autotransfer (borrowing hydrogen) mechanism that involves Co-Mo-Smediated dehydrogenation and hydrogenation reactions. A novel catalytic protocol based on the thioetherification of alcohols with hydrogen sulphide (H2S) to furnish symmetrical thioethers has also been developed using these earth-abundant metal-based sulphide catalysts.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationSorribes-Terrés, I.; Corma Canós, A. (2019). Nanolayered cobalt-molybdenum sulphides (Co-Mo-S) catalyse borrowing hydrogen C-S bond formation reactions of thiols or H2S with alcohols. Chemical Science. 10(10):3130-3142. https://doi.org/10.1039/c8sc05782fes_ES
dc.description.issue10es_ES
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dc.description.sponsorshipFinancial support by the Spanish Government-MINECO through the program "Severo Ochoa" (SEV-2016-0683) is gratefully acknowledged. I. S. also acknowledges the Vice-Rectorate for Research, Innovation and Transfer of the Universitat Politecnica de Valencia (UPV) for a postdoctoral fellowship and the Spanish Government-MINECO for a "Juan de la Cierva-Incorporacion" fellowship. The authors also acknowledge the Microscopy Service of the UPV and Dr Jose Maria Moreno for kind help with TEM and STEM measurements.es_ES
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dc.rightsReconocimiento - No comercial (by-nc)es_ES
dc.rights.accessRightsAbiertoes_ES
dc.subject.classificationQUIMICA ORGANICAes_ES
dc.subject.classificationQUIMICA ANALITICAes_ES
dc.titleNanolayered cobalt-molybdenum sulphides (Co-Mo-S) catalyse borrowing hydrogen C-S bond formation reactions of thiols or H2S with alcoholses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
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