Synthesis of the small pore silicoaluminophosphate STA-6 by using supramolecular self-assembled organic structure directing agents

Martínez Franco, Raquel; Cantin Sanz, Angel; Moliner Marin, Manuel; Corma Canós, Avelino

doi:10.1021/cm5005483

Synthesis of the small pore silicoaluminophosphate STA-6 by using supramolecular self-assembled organic structure directing agents

Archivos

cm5005483.pdf (6.87 MB)

Fecha

2014-08-12

Autores

Martínez Franco, Raquel

Cantin Sanz, Angel

Moliner Marin, Manuel

Corma Canós, Avelino

Unidades organizativas

Instituto Universitario Mixto de Tecnología Química

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Handle

https://riunet.upv.es/handle/10251/61329

Cita bibliográfica

Martínez Franco, R.; Cantin Sanz, A.; Moliner Marin, M.; Corma Canós, A. (2014). Synthesis of the small pore silicoaluminophosphate STA-6 by using supramolecular self-assembled organic structure directing agents. Chemistry of Materials. 26(15):4346-4353. https://doi.org/10.1021/cm5005483

Resumen

By means of organic structure directing agents (OSDA) formed by bulky paired quinolinium derived molecules, obtained by self-assembled monomers, it has been possible to synthesize for the first time the pure silicoaluminophosphate form of the small pore STA-6 zeotype. This synthesis method allows obtaining samples with very well dispersed framework silicon atoms, opening the possibility for its use in catalysis.