Tailoring La(2-x)A(x)Ni(1-y)ByO(4+delta) cathode performance by simultaneous A and B doping for IT-SOFC

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorNavarrete Algaba, Lauraes_ES
dc.contributor.authorFabuel Robledo, Maria
dc.contributor.authorYoo, C.-Y.es_ES
dc.contributor.authorSerra Alfaro, José Manuel
dc.contributor.funderGeneralitat Valencianaes_ES
dc.contributor.funderAgencia Estatal de Investigaciónes_ES
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.date.accessioned2021-07-16T03:31:42Z
dc.date.available2021-07-16T03:31:42Z
dc.date.issued2020-06-08es_ES
dc.description.abstract[EN] The present work focuses on the study of different Ruddlesden-Popper based cathode materials for Solid Oxide Fuel Cells at Intermediate Temperature (IT-SOFC). The partial substitution of La and Ni by Pr and Co, respectively, were studied in the La(2-x)A(x)Ni(1-y)ByO(4+delta) system, with the purpose of enhancing their mixed ionic-electronic conductivity and the electrocatalytic activity for the O-2-reduction while the crystal structure was preserved. All synthesized compounds were characterized by electrochemical impedance spectroscopy (EIS), DC conductivity measurements, X-Ray diffraction (XRD), iodometric titration and scanning electron microscopy (SEM). XRD analyses by Rietveld refinement revealed the influence of the ionic radius on the crystalline phase for the different dopants, i.e., variation of the cell parameters and M-O bond lengths. The substitution in both La and Ni sites improves La2NiO4+delta electrochemical properties as IT-SOFC cathode, since higher conductivity and lower polarization resistance were obtained. Finally, La1.5Pr0.5Ni0.8Co0.2O4+delta cathode exhibited the lowest electrode polarization resistance and activation energy values in the temperature range of 450-900 degrees C. La1.5Pr0.5Ni0.8Co0.2O4+delta was applied on an anode supported cell and a maximum power density of similar to 400 mW cm(-2) was obtained at 700 degrees C using pure hydrogen and air.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationNavarrete Algaba, L.; Fabuel Robledo, M.; Yoo, C.; Serra Alfaro, JM. (2020). Tailoring La(2-x)A(x)Ni(1-y)ByO(4+delta) cathode performance by simultaneous A and B doping for IT-SOFC. International Journal of Hydrogen Energy. 45(31):15589-15599. https://doi.org/10.1016/j.ijhydene.2020.03.150es_ES
dc.description.issue31es_ES
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dc.description.sponsorshipThis work was financially supported by Spanish Government (Grants SEV-2016-0683 and RTI2018-102161) and Generalitat Valenciana (PROMETEO/2018/006). Vicente B. Vert, Ji Haeng Yu and Dae Sik Yun are kindly acknowledged for their support during this work preparation and Forschungszentrum Julich for providing the anode supported cell.es_ES
dc.description.upvformatpfin15599es_ES
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dc.description.volume45es_ES
dc.identifier.doi10.1016/j.ijhydene.2020.03.150es_ES
dc.identifier.issn0360-3199es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/169349
dc.languageIngléses_ES
dc.publisherElsevieres_ES
dc.relation.ispartofInternational Journal of Hydrogen Energyes_ES
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dc.relation.projectIDinfo:eu-repo/grantAgreement/GVA//PROMETEO%2F2018%2F006/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-102161-B-I00/ES/CONVERSION DIRECTA DE CO2 EN PORTADORES DE ENERGIA QUIMICA UTILIZANDO REACTORES ELECTROCATALITICOS DE MEMBRANA/es_ES
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dc.rightsReconocimiento - No comercial - Sin obra derivada (by-nc-nd)es_ES
dc.rights.accessRightsAbiertoes_ES
dc.titleTailoring La(2-x)A(x)Ni(1-y)ByO(4+delta) cathode performance by simultaneous A and B doping for IT-SOFCes_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
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