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A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution

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A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution

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dc.contributor.author Lo-Presti, Maria es_ES
dc.contributor.author Martínez-Máñez, Ramón es_ES
dc.contributor.author Ros-Lis, José Vicente es_ES
dc.contributor.author Batista, Rosa M. F. es_ES
dc.contributor.author Costa, Susana P. G. es_ES
dc.contributor.author Raposo, M. Manuela M. es_ES
dc.contributor.author Sancenón Galarza, Félix es_ES
dc.date.accessioned 2018-06-10T04:26:54Z
dc.date.available 2018-06-10T04:26:54Z
dc.date.issued 2018 es_ES
dc.identifier.issn 1144-0546 es_ES
dc.identifier.uri http://hdl.handle.net/10251/103743
dc.description.abstract [EN] We report herein the synthesis and chromo-fluorogenic behaviour of a new probe 1 containing a boron-dipyrromethene (BODIPY) unit electronically connected with a dithia-dioxa-aza macrocycle. Acetonitrile and water¿acetonitrile 95 : 5 v/v solutions of the probe showed an ICT band in the visible zone and are nearly non-emissive. When acetonitrile was used as a solvent, addition of Hg(II) and trivalent metal cations induced an hypsochromic shift of the absorption band and moderate emission enhancements. A highly selective response was obtained when using competitive media such as water¿ acetonitrile 95 : 5 v/v. In this case only Hg(II) induced a hypsochromic shift of the absorption band and a marked emission enhancement. es_ES
dc.description.sponsorship We thank the Spanish Government (MAT2015-64139-C4-1-R) and Generalitat Valenciana (PROMETEOII/2014/047). M. L. P. thanks Generalitat Valenciana for her Grisolia fellowship. Thanks are also due to Fundaça˜o para a Cieˆncia e Tecnologia (Portugal) for financial support to the Portuguese NMR network (PTNMR, Bruker Avance III 400-Univ. Minho), FCT and FEDER (European Fund for Regional Development)-COMPETEQRENEU for financial support to the research centre CQ/UM [PEst-C/ QUI/UI0686/2013 (FCOMP-01-0124-FEDER-037302)], and a postdoctoral grant to R. M. F. Batista (SFRH/BPD/79333/2011).
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof New Journal of Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Mercury es_ES
dc.subject Bodipy es_ES
dc.subject Water es_ES
dc.subject Coordination es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c7nj04699e es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-64139-C4-1-R/ES/NANOMATERIALES INTELIGENTES, SONDAS Y DISPOSITIVOS PARA EL DESARROLLO INTEGRADO DE NUEVAS HERRAMIENTAS APLICADAS AL CAMPO BIOMEDICO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/COMPETE/132953/PT/2013-2014/
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2014%2F047/ES/Nuevas aproximaciones para el diseño de materiales de liberación controlada y la detección de compuestos peligrosos/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F79333%2F2011/PT/SYNTHESIS AND CHARACTERIZATION OF NOVEL HETEROCYCLE-BASED TWO-PHOTON ABSORBING (TPA) ORGANIC MOLECULES FOR NANOSCALE IMAGING AND OPTICAL DATA STORAGE APPLICATIONS/
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Lo-Presti, M.; Martínez-Máñez, R.; Ros-Lis, JV.; Batista, RMF.; Costa, SPG.; Raposo, MMM.; Sancenón Galarza, F. (2018). A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution. New Journal of Chemistry. 42(10):7863-7868. https://doi.org/10.1039/c7nj04699e es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1039/c7nj04699e es_ES
dc.description.upvformatpinicio 7863 es_ES
dc.description.upvformatpfin 7868 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 42 es_ES
dc.description.issue 10 es_ES
dc.relation.pasarela S\354440 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
dc.contributor.funder Fundação para a Ciência e a Tecnologia, Portugal


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