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Metal organic framework nanosheets in polymer composite materials for gas separation

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Metal organic framework nanosheets in polymer composite materials for gas separation

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dc.contributor.author Ródenas Torralba, Tania es_ES
dc.contributor.author Luz Mínguez, Ignacio es_ES
dc.contributor.author Prieto González, Gonzalo es_ES
dc.contributor.author Seoane, Beatriz es_ES
dc.contributor.author Miro, Hozanna es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Kapteijn, Freek es_ES
dc.contributor.author Llabrés i Xamena, Francesc Xavier es_ES
dc.contributor.author Gascon, Jorge es_ES
dc.date.accessioned 2018-07-06T04:25:51Z
dc.date.available 2018-07-06T04:25:51Z
dc.date.issued 2015 es_ES
dc.identifier.issn 1476-1122 es_ES
dc.identifier.uri http://hdl.handle.net/10251/105345
dc.description.abstract [EN] Composites incorporating two-dimensional nanostructures within polymeric matrices have potential as functional components for several technologies, including gas separation. Prospectively, employing metal-organic frameworks (MOFs) as versatile nanofillers would notably broaden the scope of functionalities. However, synthesizing MOFs in the form of freestanding nanosheets has proved challenging. We present a bottom-up synthesis strategy for dispersible copper 1,4-benzenedicarboxylate MOF lamellae of micrometre lateral dimensions and nanometre thickness. Incorporating MOF nanosheets into polymer matrices endows the resultant composites with outstanding CO2 separation performance from CO2/CH4 gas mixtures, together with an unusual and highly desired increase in the separation selectivity with pressure. As revealed by tomographic focused ion beam scanning electron microscopy, the unique separation behaviour stems from a superior occupation of the membrane cross-section by the MOF nanosheets as compared with isotropic crystals, which improves the efficiency of molecular discrimination and eliminates unselective permeation pathways. This approach opens the door to ultrathin MOF-polymer composites for various applications. es_ES
dc.description.sponsorship The research leading to these results has received funding (J.G., B.S.) from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement no. 335746, CrystEng-MOF-MMM. T.R. is grateful to TUDelft for funding. G.P. acknowledges the A. von Humboldt Foundation for a research grant. A.C., I.L. and F.X.L.i.X. thank Consolider-Ingenio 2010 (project MULTICAT) and the ‘Severo Ochoa’ programme for support. I.L. also thanks CSIC for a JAE doctoral grant. es_ES
dc.language Inglés es_ES
dc.publisher Nature Publishing Group es_ES
dc.relation.ispartof Nature Materials es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Electron Microscopy Service of the UPV es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Metal organic framework nanosheets in polymer composite materials for gas separation es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1038/nmat4113 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/335746/EU/Crystal Engineering of Metal Organic Frameworks for application in Mixed Matrix Membranes/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Ródenas Torralba, T.; Luz Mínguez, I.; Prieto González, G.; Seoane, B.; Miro, H.; Corma Canós, A.; Kapteijn, F.... (2015). Metal organic framework nanosheets in polymer composite materials for gas separation. Nature Materials. 14(1):48-55. https://doi.org/10.1038/nmat4113 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1038/nmat4113 es_ES
dc.description.upvformatpinicio 48 es_ES
dc.description.upvformatpfin 55 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 14 es_ES
dc.description.issue 1 es_ES
dc.identifier.pmid 25362353 en_EN
dc.identifier.pmcid PMC4270742 en_EN
dc.relation.pasarela S\278029 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Delft University of Technology es_ES
dc.contributor.funder Alexander von Humboldt Foundation es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES
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