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Anion transport through ceramic electrodialysis membranes made with hydrated cerium dioxide

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Anion transport through ceramic electrodialysis membranes made with hydrated cerium dioxide

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dc.contributor.author Mora-Gómez, Julia es_ES
dc.contributor.author García Gabaldón, Montserrat es_ES
dc.contributor.author Martí Calatayud, Manuel César es_ES
dc.contributor.author Mestre, Sergio es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.date.accessioned 2018-07-08T04:26:41Z
dc.date.available 2018-07-08T04:26:41Z
dc.date.issued 2017 es_ES
dc.identifier.issn 0002-7820 es_ES
dc.identifier.uri http://hdl.handle.net/10251/105487
dc.description This is the peer reviewed version of the following article: Mora-Gómez, Julia, García Gabaldón, Montserrat, Martí Calatayud, Manuel César, Mestre, Sergio, Pérez-Herranz, Valentín. (2017). Anion transport through ceramic electrodialysis membranes made with hydrated cerium dioxide.Journal of the American Ceramic Society, 100, 9, 4180-4189. DOI: 10.1111/jace.14978, which has been published in final form at http://doi.org/10.1111/jace.14978. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
dc.description.abstract [EN] In this research, low-cost ceramic anion-exchange membranes have been developed from porous supports manufactured, using a chamotte as a pore former. An inorganic anion-exchanger (hydrated cerium dioxide) has been deposited into the support and fixed by thermal treatment. The effects of some process variables (such as the temperature of the thermal treatment or the pH of the electrolyte) on the properties of the anion-exchange membranes have been investigated. The electrochemical performance of the resulting membranes has been compared to that exhibited by ceramic anion-exchange membranes based on another anion exchanger (hydrated zirconium dioxide) deposited into alumina-kaolin supports. The temperature of the thermal treatment applied to fix the hydrated cerium dioxide (HCeD) does not affect the structure nor the electrochemical properties of the membranes. The porosity of the supports obtained, using a chamotte as the pore former was lower than that of the alumina-kaolin ones, which led to a lower deposition of hydrated cerium dioxide than that obtained for hydrated zirconium dioxide (HZrD) in alumina-kaolin supports. The higher porosity registered for the HZrD-based membrane also implies higher membrane conductivities. The selective transport of anions through the membranes was enhanced by increasing the number of infiltrating steps, as confirmed from current to voltage curves. However, this behavior was only apparent at acidic or neutral pH, thus confirming the amphoteric character of the anion-exchanger. Comparing the parameter (equivalents of ion exchanger per gram of deposited oxide), it is concluded that the porosity of the ceramic supports, consequence of their distinct microstructure, is the main parameter responsible for the difference in the ion-exchange capacity obtained for HZrD and HCeD membranes. Consequently, the CeO2 particles used in this work are also good candidates to impart ion-exchange properties to microporous ceramic supports. es_ES
dc.description.sponsorship Ministerio de Economia y Competitividad (Spain), Grant/Award Number: CTQ2012-3750-C02-01/PPQ, CTQ2012-3750-C02-02/PPQ es_ES
dc.language Inglés es_ES
dc.publisher Blackwell Publishing es_ES
dc.relation.ispartof Journal of the American Ceramic Society es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Ceramic anion-exchange membranes es_ES
dc.subject Chronopotentiometry es_ES
dc.subject Hydrated cerium dioxide es_ES
dc.subject Ion-exchange capacity es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Anion transport through ceramic electrodialysis membranes made with hydrated cerium dioxide es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1111/jace.14978 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-37450-C02-01/ES/CARACTERIZACION ELECTROQUIMICA DE MEMBRANAS CERAMICAS NANOESTRUCTURADAS DE INTERCAMBIO IONICO PARA SU APLICACION EN REACTORES ELECTROQUIMICOS Y SISTEMAS ELECTRODIALITICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.date.embargoEndDate 2018-09-01 es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Seguridad Industrial, Radiofísica y Medioambiental - Institut de Seguretat Industrial, Radiofísica i Mediambiental es_ES
dc.description.bibliographicCitation Mora-Gómez, J.; García Gabaldón, M.; Martí Calatayud, MC.; Mestre, S.; Pérez-Herranz, V. (2017). Anion transport through ceramic electrodialysis membranes made with hydrated cerium dioxide. Journal of the American Ceramic Society. 100(9):4180-4189. https://doi.org/10.1111/jace.14978 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1111/jace.14978 es_ES
dc.description.upvformatpinicio 4180 es_ES
dc.description.upvformatpfin 4189 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 100 es_ES
dc.description.issue 9 es_ES
dc.relation.pasarela S\343110 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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