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Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst

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Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Asiri, Abdullah M. es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2018-07-09T06:39:08Z
dc.date.available 2018-07-09T06:39:08Z
dc.date.issued 2017 es_ES
dc.identifier.issn 1359-7345 es_ES
dc.identifier.uri http://hdl.handle.net/10251/105528
dc.description.abstract [EN] A convenient method for the synthesis of borasiloxanes from silanes and pinacolboranes using Cu-3(BTC)(2) as a heterogeneous catalyst in acetonitrile at 70 degrees C is reported. This procedure is more convenient than Ru and Pd based homogeneous catalysts because it avoids the use of noble metals, easy handling of starting materials and the catalyst can be reused. es_ES
dc.description.sponsorship AD thanks the University Grants Commission (UGC), New Delhi, for the award of an Assistant Professorship under its Faculty Recharge Programme. AD also thanks the Department of Science and Technology, India, for the financial support through Extra Mural Research Funding (EMR/2016/006500). Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2015-69153-CO2-1) is gratefully acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Communications es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c7cc05221a es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-1-R/ES/EXPLOTANDO EL USO DEL GRAFENO EN CATALISIS. USO DEL GRAFENO COMO CARBOCATALIZADOR O COMO SOPORTE/ es_ES
dc.rights.accessRights Abierto es_ES
dc.date.embargoEndDate 2018-09-16 es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; Asiri, AM.; Concepción Heydorn, P.; García Gómez, H. (2017). Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst. Chemical Communications. 53(72):9998-10001. https://doi.org/10.1039/c7cc05221a es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c7cc05221a es_ES
dc.description.upvformatpinicio 9998 es_ES
dc.description.upvformatpfin 10001 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 53 es_ES
dc.description.issue 72 es_ES
dc.relation.pasarela S\357369 es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
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