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Structure-reactivity correlations in Vanadium containing catalysts for the one-pot glycerol oxidehydration to acrylic acid

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Structure-reactivity correlations in Vanadium containing catalysts for the one-pot glycerol oxidehydration to acrylic acid

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dc.contributor.author Chieregato, Alessandro es_ES
dc.contributor.author Bandinelli, Claudia es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Soriano Rodríguez, Mª Dolores es_ES
dc.contributor.author Puzzo, Francesco es_ES
dc.contributor.author Basile, Francesco es_ES
dc.contributor.author Cavani, Fabrizio es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2018-07-09T06:44:08Z
dc.date.available 2018-07-09T06:44:08Z
dc.date.issued 2017 es_ES
dc.identifier.issn 1864-5631 es_ES
dc.identifier.uri http://hdl.handle.net/10251/105540
dc.description.abstract [EN] The design of suitable catalysts for the one-pot conversion of glycerol into acrylic acid (AA) is a complex matter, as only fine-tuning of the redox and acid properties makes it possible to obtain significant yields of AA. However, fundamental understanding behind the catalytic phenomenon is still unclear. Structure-reactivity correlations are clearly behind these results, and acid sites are involved in the dehydration of glycerol into acrolein with vanadium as the main (or only) redox element. For the first time, we propose an in-depth study to shed light on the molecular-level relations behind the overall catalytic results shown by several types of V-containing catalysts. Different multifunctional catalysts were synthesized, characterized (>X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, temperature-programmed reduction, and temperature-programmed desorption of ammonia), and tested in a flow reactor. Combining the obtained results with those acquired from an in situ FTIR spectroscopy study with acrolein (a reaction intermediate), it was possible to draw conclusions on the role played by the various physicochemical features of the different oxides in terms of the adsorption, surface reactions, and desorption of the reagents and reaction products. es_ES
dc.description.sponsorship The Instituto de Tecnologia Quimica thanks the Spanish Government-MINECO projects (CTQ2015-68951-C3-1-R and SEV-2012-0267). CIRI Energia e Ambiente (University of Bologna) is acknowledged for a Ph.D. grant to A.C. Consorzio INSTM (Firenze) is acknowledged for a Ph.D. grant to C.B. en_EN
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof ChemSusChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Vanadium containing catalysts es_ES
dc.subject One-pot glycerol oxidehydration es_ES
dc.subject Acrylic acid es_ES
dc.subject Bronzes es_ES
dc.title Structure-reactivity correlations in Vanadium containing catalysts for the one-pot glycerol oxidehydration to acrylic acid es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/cssc.201600954 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-1-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Chieregato, A.; Bandinelli, C.; Concepción Heydorn, P.; Soriano Rodríguez, MD.; Puzzo, F.; Basile, F.; Cavani, F.... (2017). Structure-reactivity correlations in Vanadium containing catalysts for the one-pot glycerol oxidehydration to acrylic acid. ChemSusChem. 10(1):234-244. https://doi.org/10.1002/cssc.201600954 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/cssc.201600954 es_ES
dc.description.upvformatpinicio 234 es_ES
dc.description.upvformatpfin 244 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 1 es_ES
dc.relation.pasarela S\332649 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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