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Analyzing chemical changes in verdigris pictorial specimens upon bacteria and fungi biodeterioration using voltammetry of microparticles

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Analyzing chemical changes in verdigris pictorial specimens upon bacteria and fungi biodeterioration using voltammetry of microparticles

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dc.contributor.author Ortiz-Miranda, Annette es_ES
dc.contributor.author Domenech Carbo, Antonio es_ES
dc.contributor.author Domenech Carbo, Mª Teresa es_ES
dc.contributor.author Osete Cortina, Laura es_ES
dc.contributor.author Bolivar-Galiano, Fernando es_ES
dc.contributor.author Martín-Sánchez, Inés es_ES
dc.date.accessioned 2018-09-17T08:55:52Z
dc.date.available 2018-09-17T08:55:52Z
dc.date.issued 2017 es_ES
dc.identifier.uri http://hdl.handle.net/10251/107466
dc.description.abstract [EN] It is reported the application of the voltammetry of microparticles (VMP), complemented with attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and field emission scanning electron microscopy (FESEM) techniques, to monitor the deterioration of verdigris pictorial specimens under the action of different biological agents. This methodology would be of application for identifying the type of biological agent causing deterioration of paintings, which is an important problem affecting cultural heritage. The analysis of biodeterioration processes is complicated by the fact that the action of microorganisms can affect both pigment and binding media. The deterioration of pictorial specimens combining verdigris with egg and egg-linseed oil binders by Penicillium chrysogenum, Aspergillus niger, Acremonium chrysogenum, Trychoderma pseudokoningi and Mucor rouxii fungi and Bacillus amyloliquefaciens, Arthrobacter oxydans and Streptomyces cellulofans bacteria were tested using sample-modified graphite electrodes immersed into aqueous electrolytes. A model is presented to describe the involved electrochemistry resulting in specific voltammetric features for the electrochemical reduction of verdigris associated to the proteinaceous and lipidic fractions of the binders. The experimental results and model proposed have been discussed and compared with those previously obtained for cadmium yellow reconstructed paint film specimens. es_ES
dc.description.sponsorship This work as been performed by members of the microcluster Grupo de analisis cientifico de bienes culturales y patrimoniales y estudios de ciencia de la conservacion (Ref. 1362) belonging to the Valencia International Campus of Excellence. Financial support is gratefully acknowledged from the Spanish "I+D+I MINECO" projects CTQ2014-53736-C3-1-P and CTQ2014-53736-C3-2-P supported by ERDF funds. es_ES
dc.language Inglés es_ES
dc.publisher BioMed Central es_ES
dc.relation.ispartof Heritage Science es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Electrochemistry es_ES
dc.subject Biodeterioration es_ES
dc.subject Verdigris es_ES
dc.subject Cadmium sulfide es_ES
dc.subject Egg tempera es_ES
dc.subject Egg-oil emulsion es_ES
dc.subject.classification PINTURA es_ES
dc.title Analyzing chemical changes in verdigris pictorial specimens upon bacteria and fungi biodeterioration using voltammetry of microparticles es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1186/s40494-017-0121-x es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2014-53736-C3-1-P/ES/APLICACION DE LAS TECNICAS NANOELECTROQUIMICAS Y BIOTECNOLOGIAS EN EL ESTUDIO Y CONSERVACION DEL PATRIMONIO EN METAL/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Conservación y Restauración de Bienes Culturales - Departament de Conservació i Restauració de Béns Culturals es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario de Restauración del Patrimonio - Institut Universitari de Restauració del Patrimoni es_ES
dc.description.bibliographicCitation Ortiz-Miranda, A.; Domenech Carbo, A.; Domenech Carbo, MT.; Osete Cortina, L.; Bolivar-Galiano, F.; Martín-Sánchez, I. (2017). Analyzing chemical changes in verdigris pictorial specimens upon bacteria and fungi biodeterioration using voltammetry of microparticles. Heritage Science. 5. https://doi.org/10.1186/s40494-017-0121-x es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1186/s40494-017-0121-x es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.identifier.eissn 2050-7445 es_ES
dc.relation.pasarela S\358599 es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
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