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dc.contributor.author | Rogge, S. M. J. | es_ES |
dc.contributor.author | Bavykina, Anastasiya | es_ES |
dc.contributor.author | Hajek, J. | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.contributor.author | Olivos-Suarez, A. I. | es_ES |
dc.contributor.author | Sepulveda-Escribano, A. | es_ES |
dc.contributor.author | Vimont, A. | es_ES |
dc.contributor.author | Clet, G. | es_ES |
dc.contributor.author | Bazin, P. | es_ES |
dc.contributor.author | Kapteijn, Freek | es_ES |
dc.contributor.author | Daturi, M. | es_ES |
dc.contributor.author | Ramos-Fernandez, Enrique V. | es_ES |
dc.contributor.author | Llabrés i Xamena, Francesc Xavier | es_ES |
dc.contributor.author | Van Speybroeck, Veronique | es_ES |
dc.contributor.author | Gascon, Jorge | es_ES |
dc.date.accessioned | 2018-10-29T10:24:48Z | |
dc.date.available | 2018-10-29T10:24:48Z | |
dc.date.issued | 2017 | es_ES |
dc.identifier.issn | 0306-0012 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/111485 | |
dc.description.abstract | [EN] Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions. | es_ES |
dc.description.sponsorship | S. M. J. Rogge, J. Hajek, and V. Van Speybroeck acknowledge the Fund for Scientific Research - Flanders (FWO), the Research Board of Ghent University (BOF) and BELSPO in the frame of IAP/7/05 for financial support. V. Van Speybroeck acknowledges funding from the European Union's Horizon 2020 research and innovation programme (consolidator ERC grant agreement no. 647755 - DYNPOR (2015-2020)). This project has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement no. 641887 (project acronym: DEFNET). W. Dewitte and C. Caratelli are acknowledged for technical support with the figures. J. Gascon acknowledges funding from the European Union's 2020 research and innovation programme (ERC grant agreement no. 335746 - CrystEng-MOF-MMM) and from the Dutch Organization for Scientific Research (NWO, VIDI grant agreement 723.012.107 - MetMOFCat). | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | The Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Chemical Society Reviews | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Metal-organic and covalent organic frameworks as single-site catalysts | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/c7cs00033b | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/647755/EU/First principle molecular dynamics simulations for complex chemical transformations in nanoporous materials/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/FWO//UGENT-BELSPO%2FIAP%2F7%2F05/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/335746/EU/Crystal Engineering of Metal Organic Frameworks for application in Mixed Matrix Membranes/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/NWO//723.012.107/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/ 641887/EU/ | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Rogge, SMJ.; Bavykina, A.; Hajek, J.; García Gómez, H.; Olivos-Suarez, AI.; Sepulveda-Escribano, A.; Vimont, A.... (2017). Metal-organic and covalent organic frameworks as single-site catalysts. Chemical Society Reviews. 46(11):3134-3184. https://doi.org/10.1039/c7cs00033b | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.description.upvformatpinicio | 3134 | es_ES |
dc.description.upvformatpfin | 3184 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 46 | es_ES |
dc.description.issue | 11 | es_ES |
dc.identifier.pmid | 28338128 | en_EN |
dc.identifier.pmcid | PMC5708534 | en_EN |
dc.relation.pasarela | S\342176 | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | European Research Council | es_ES |
dc.contributor.funder | Research Foundation Flanders | |
dc.contributor.funder | Ghent University | |
dc.contributor.funder | Belgian Federal Science Policy Office | |
dc.contributor.funder | Netherlands Organization for Scientific Research |