Rogge, SMJ.; Bavykina, A.; Hajek, J.; García Gómez, H.; Olivos-Suarez, AI.; Sepulveda-Escribano, A.; Vimont, A.... (2017). Metal-organic and covalent organic frameworks as single-site catalysts. Chemical Society Reviews. 46(11):3134-3184. https://doi.org/10.1039/c7cs00033b
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/111485
Título:
|
Metal-organic and covalent organic frameworks as single-site catalysts
|
Autor:
|
Rogge, S. M. J.
Bavykina, Anastasiya
Hajek, J.
García Gómez, Hermenegildo
Olivos-Suarez, A. I.
Sepulveda-Escribano, A.
Vimont, A.
Clet, G.
Bazin, P.
Kapteijn, Freek
Daturi, M.
Ramos-Fernandez, Enrique V.
Llabrés i Xamena, Francesc Xavier
Van Speybroeck, Veronique
Gascon, Jorge
|
Entidad UPV:
|
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
|
Fecha difusión:
|
|
Resumen:
|
[EN] Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic ...[+]
[EN] Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.
[-]
|
Derechos de uso:
|
Reserva de todos los derechos
|
Fuente:
|
Chemical Society Reviews. (issn:
0306-0012
)
|
DOI:
|
10.1039/c7cs00033b
|
Editorial:
|
The Royal Society of Chemistry
|
Código del Proyecto:
|
info:eu-repo/grantAgreement/EC/H2020/647755/EU/First principle molecular dynamics simulations for complex chemical transformations in nanoporous materials/
info:eu-repo/grantAgreement/FWO//UGENT-BELSPO%2FIAP%2F7%2F05/
info:eu-repo/grantAgreement/EC/FP7/335746/EU/Crystal Engineering of Metal Organic Frameworks for application in Mixed Matrix Membranes/
info:eu-repo/grantAgreement/NWO//723.012.107/
info:eu-repo/grantAgreement/EC/H2020/ 641887/EU/
|
Agradecimientos:
|
S. M. J. Rogge, J. Hajek, and V. Van Speybroeck acknowledge the Fund for Scientific Research - Flanders (FWO), the Research Board of Ghent University (BOF) and BELSPO in the frame of IAP/7/05 for financial support. V. Van ...[+]
S. M. J. Rogge, J. Hajek, and V. Van Speybroeck acknowledge the Fund for Scientific Research - Flanders (FWO), the Research Board of Ghent University (BOF) and BELSPO in the frame of IAP/7/05 for financial support. V. Van Speybroeck acknowledges funding from the European Union's Horizon 2020 research and innovation programme (consolidator ERC grant agreement no. 647755 - DYNPOR (2015-2020)). This project has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement no. 641887 (project acronym: DEFNET). W. Dewitte and C. Caratelli are acknowledged for technical support with the figures. J. Gascon acknowledges funding from the European Union's 2020 research and innovation programme (ERC grant agreement no. 335746 - CrystEng-MOF-MMM) and from the Dutch Organization for Scientific Research (NWO, VIDI grant agreement 723.012.107 - MetMOFCat).
[-]
|
Tipo:
|
Artículo
|