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Catalyst Screening for Oxidative Coupling of Methane Integrated in Membrane Reactors

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Catalyst Screening for Oxidative Coupling of Methane Integrated in Membrane Reactors

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dc.contributor.author García-Fayos, Julio es_ES
dc.contributor.author Lobera González, Maria Pilar es_ES
dc.contributor.author Balaguer Ramirez, Maria es_ES
dc.contributor.author Serra Alfaro, José Manuel es_ES
dc.date.accessioned 2019-06-29T20:01:40Z
dc.date.available 2019-06-29T20:01:40Z
dc.date.issued 2018 es_ES
dc.identifier.uri http://hdl.handle.net/10251/122899
dc.description.abstract [EN] Increased availability of methane from shale gas and stranded gas deposits in the recent years may facilitate the production of ethylene by means of potentially more competitive routes than the state-of-the-art steam cracking processes. One appealing route is the oxidative coupling of methane (OCM), which is considered in this work for the production of ethylene by means of the use of catalytic membrane reactors (CMR) based on Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) ceramic material. In a first approach, a screening of 15 formulations as catalysts for the ethylene-ethane production was conducted on CMR consisting of disk-shaped planar BSCF membranes. At 900 degrees C, the maximum C-2 selectivity was 70%, reached with Ba0.5Sr0.5FeO3-delta and La0.5Ce0.1Sr0.4Co0.8Fe0.2O3-delta catalysts. On the other hand, low CH4 conversions (X-CH4) resulted in C-2 yields below 3%. Operation at 1,000 degrees C significantly shifted X-CH4 for all the activated membranes due to the decrease in CH4/O-2 ratios, thus obtaining C-2 yields close to 9% and productivities of ca. 1.2ml.min(-1).cm(-2) with Ce0.9Gd0.1O2-delta and Ba0.5Sr0.5Co0.8Fe0.2O3-delta impregnated with Mn-Na2WO4 catalysts. The performance of OCM reaction was also studied in a tubular catalytic membrane reactor. Tubular configuration improved C-2 yield by minimizing CH4/O-2 ratios up to 1.7, obtaining a maximum of 15.6% at 900 degrees C with a BSCF capillary membrane activated with a packed bed of 2 wt% Mn/5 wt% Na2WO4 on SiO2 catalyst. es_ES
dc.description.sponsorship Financial support by the Spanish Government (ENE2014-57651 and SEV-2012-0267 grants) and by the EU through FP7 GREEN-CC Project (GA 608524), is gratefully acknowledged. The authors want also acknowledge the Electron Microscopy Service from the Universitat Politecnica de Valencia for their support in the SEM analysis performed in this work. es_ES
dc.language Inglés es_ES
dc.publisher Frontiers Media SA es_ES
dc.relation.ispartof Frontiers in Materials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Catalytic membrane reactor es_ES
dc.subject Oxygen transport membrane es_ES
dc.subject BSCF es_ES
dc.subject OCM es_ES
dc.subject Ethylene production es_ES
dc.subject Ionic conductor es_ES
dc.title Catalyst Screening for Oxidative Coupling of Methane Integrated in Membrane Reactors es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3389/fmats.2018.00031 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/608524/EU/Graded Membranes for Energy Efficient New Generation Carbon Capture Process/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2014-57651-R/ES/ALMACENAMIENTO DE ENERGIA VIA REDUCCION DE CO2 A COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation García-Fayos, J.; Lobera González, MP.; Balaguer Ramirez, M.; Serra Alfaro, JM. (2018). Catalyst Screening for Oxidative Coupling of Methane Integrated in Membrane Reactors. Frontiers in Materials. 5. https://doi.org/10.3389/fmats.2018.00031 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.3389/fmats.2018.00031 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.identifier.eissn 2296-8016 es_ES
dc.relation.pasarela S\371793 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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