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Faster plasticizers production by microwave irradiation

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Faster plasticizers production by microwave irradiation

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dc.contributor.author Jermolovicius, Luiz es_ES
dc.contributor.author Pouzada, Eduardo es_ES
dc.contributor.author Castro, Edmilson es_ES
dc.contributor.author Nascimento, Renata es_ES
dc.contributor.author Senise, José es_ES
dc.date.accessioned 2019-11-13T08:59:36Z
dc.date.available 2019-11-13T08:59:36Z
dc.date.issued 2019-10-15
dc.identifier.isbn 9788490487198
dc.identifier.uri http://hdl.handle.net/10251/130887
dc.description.abstract [EN] In this work the microwave effect of enhancing chemical reactions was applied to maleic anhydride esterification with 2-ethylhexanol-1 catalyzed by p-toluene sulfonic acid. The analysis of this reaction was simplified considering the industrial practice of withdrawn the reaction water, which makes the whole reaction act as a pseudo irreversible one. A statistical design of experiments was applied to determine an empirical chemical kinetics equation with three levels of catalyst concentration and two levels related to the kind of heating (microwave and conventional); six chemical kinetics equations (three for microwave heating and three for conventional heating) were determined. A batch/plug flow simulation was done and a spreadsheet developed for the reactor’s behavior. The most interesting result was the confirmation of a synergic effect between microwaves and acid catalysis that accelerated this esterification reaction, transforming it in a fast reaction. es_ES
dc.description.sponsorship The authors would like to thank C. Tognela. Support from Instituto Mauá de Tecnologia – IMT – and from Fundação de Amparo à Pesquisa do Estado de São Paulo – FAPESP – (Grant 2017/24238-7) are gratefully acknowledged. es_ES
dc.format.extent 9 es_ES
dc.language Inglés es_ES
dc.publisher Editorial Universitat Politècnica de València es_ES
dc.relation FAPESP/2017/24238-7
dc.relation.ispartof AMPERE 2019. 17th International Conference on Microwave and High Frequency Heating es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Energy Production by Microwaves es_ES
dc.subject Microwave CVD es_ES
dc.subject EM Modelling es_ES
dc.subject Microwave Material interaction es_ES
dc.subject Dielectric Properties es_ES
dc.subject Dielectric Properties Measurement es_ES
dc.subject Solid State Microwave es_ES
dc.subject Microwave Processing es_ES
dc.subject Microwave Chemistry es_ES
dc.subject Microwave applicators design es_ES
dc.title Faster plasticizers production by microwave irradiation es_ES
dc.type Capítulo de libro es_ES
dc.type Comunicación en congreso es_ES
dc.identifier.doi 10.4995/AMPERE2019.2019.9777
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Jermolovicius, L.; Pouzada, E.; Castro, E.; Nascimento, R.; Senise, J. (2019). Faster plasticizers production by microwave irradiation. En AMPERE 2019. 17th International Conference on Microwave and High Frequency Heating. Editorial Universitat Politècnica de València. 379-387. https://doi.org/10.4995/AMPERE2019.2019.9777 es_ES
dc.description.accrualMethod OCS es_ES
dc.relation.conferencename Ampere 2019 es_ES
dc.relation.conferencedate Septiembre 09-12,2019 es_ES
dc.relation.conferenceplace Valencia, Spain es_ES
dc.relation.publisherversion http://ocs.editorial.upv.es/index.php/AMPERE2019/AMPERE2019/paper/view/9777 es_ES
dc.description.upvformatpinicio 379 es_ES
dc.description.upvformatpfin 387 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.relation.pasarela OCS\9777 es_ES
dc.contributor.funder Instituto Mauá de Tecnologia, Brasil
dc.contributor.funder Fundação de Amparo à Pesquisa do Estado de São Paulo


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