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Phosphoric Acid Doped Polybenzimidazole (PBI)/Zeolitic Imidazolate Framework Composite Membranes with Signioficantly Enhanced Proton Conductivity under Low Humidity Conditions

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Phosphoric Acid Doped Polybenzimidazole (PBI)/Zeolitic Imidazolate Framework Composite Membranes with Signioficantly Enhanced Proton Conductivity under Low Humidity Conditions

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dc.contributor.author Escorihuela Fuentes, Jorge es_ES
dc.contributor.author Sahuquillo, Oscar es_ES
dc.contributor.author Garcia Bernabe, Abel es_ES
dc.contributor.author Giménez Torres, Enrique es_ES
dc.contributor.author Compañ Moreno, Vicente es_ES
dc.date.accessioned 2020-02-21T21:01:34Z
dc.date.available 2020-02-21T21:01:34Z
dc.date.issued 2018 es_ES
dc.identifier.uri http://hdl.handle.net/10251/137582
dc.description.abstract [EN] The preparation and characterization of composite polybenzimidazole (PBI) membranes containing zeolitic imidazolate framework 8 (ZIF-8) and zeolitic imidazolate framework 67 (ZIF-67) is reported. The phosphoric acid doped composite membranes display proton conductivity values that increase with increasing temperatures, maintaining their conductivity under anhydrous conditions. The addition of ZIF to the polymeric matrix enhances proton transport relative to the values observed for PBI and ZIFs alone. For example, the proton conductivity of PBI@ZIF-8 reaches 3.1 x 10(-3) S.cm(-1) at 200 degrees C and higher values were obtained for PBI@ZIF-67 membranes, with proton conductivities up to 4.1 x 10(-2) S.cm(-1). Interestingly, a composite membrane containing a 5 wt.% binary mixture of ZIF-8 and ZIF-67 yielded a proton conductivity of 9.2 x 10(-2) S.cm(-1), showing a synergistic effect on the proton conductivity. es_ES
dc.description.sponsorship This research was funded by the Spanish Ministerio de Economia y Competitividad (MINECO) under the project ENE/2015-69203-R. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Nanomaterials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Proton exchange membrane es_ES
dc.subject Polybenzimidazole es_ES
dc.subject Zeolitic imidazoleate framework es_ES
dc.subject Proton conductivity es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Phosphoric Acid Doped Polybenzimidazole (PBI)/Zeolitic Imidazolate Framework Composite Membranes with Signioficantly Enhanced Proton Conductivity under Low Humidity Conditions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/nano8100775 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2015-69203-R/ES/DESARROLLO Y EVALUACION DE NUEVAS MEMBRANAS POLIMERICAS REFORZADAS CON NANOFIBRAS PARA SU APLICACION EN PILAS DE COMBUSTIBLE CON ELEVADA ESTABILIDAD TERMICA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.description.bibliographicCitation Escorihuela Fuentes, J.; Sahuquillo, O.; Garcia Bernabe, A.; Giménez Torres, E.; Compañ Moreno, V. (2018). Phosphoric Acid Doped Polybenzimidazole (PBI)/Zeolitic Imidazolate Framework Composite Membranes with Signioficantly Enhanced Proton Conductivity under Low Humidity Conditions. Nanomaterials. 8(10):1-13. https://doi.org/10.3390/nano8100775 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/nano8100775 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 13 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 10 es_ES
dc.identifier.eissn 2079-4991 es_ES
dc.relation.pasarela S\372361 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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