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Manganese(III)-mediated oxidative carbon-carbon bond cleavage of 1,10-phenanthroline-5,6-dione ligand

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Manganese(III)-mediated oxidative carbon-carbon bond cleavage of 1,10-phenanthroline-5,6-dione ligand

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dc.contributor.author Ruiz, R. es_ES
dc.contributor.author Caneschi, A. es_ES
dc.contributor.author Gatteschi, D. es_ES
dc.contributor.author Gaspar, A. B. es_ES
dc.contributor.author Real, J. A. es_ES
dc.contributor.author Fernández, I. es_ES
dc.contributor.author Muñoz Roca, María Del Carmen es_ES
dc.date.accessioned 2020-03-16T14:46:58Z
dc.date.available 2020-03-16T14:46:58Z
dc.date.issued 1999-11-01 es_ES
dc.identifier.issn 1387-7003 es_ES
dc.identifier.uri http://hdl.handle.net/10251/138968
dc.description.abstract [EN] A new manganese(III)-1,10-phenanthroline-5,6-dione (phendione) complex possessing a putative Mn-2(mu-O) (mu-O2CMe)(2) core has been found to undergo a Ligand-based oxidative cleavage of the C(5)-C(6) bond in weak acid aqueous MeOH under aerobic conditions at room temperature to yield 2,2'-bipyridyl-3,3'-dicarboxylate with co-reduction to the corresponding Mn-II-phendione species. es_ES
dc.description.sponsorship This work was supported by the DGICYT, Ministerio de Educación y Ciencia (Spain) through projects PB97-1397 and PB97-1411. R.R. thanks the 3MD-EU Network (contract no. ERB 4061, PL 97-0197) for a grant. We would also like to express our gratitude to Prof. A. Dei for fruitful discussions and continuous interest in this work. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation EC/ERB 4061 es_ES
dc.relation EC/PL 97-0197 es_ES
dc.relation Direccion General de Ensenanza Superior e Investigacion Cientifica/PB97-1397 es_ES
dc.relation DGICYT/PB97-1411 es_ES
dc.relation.ispartof Inorganic Chemistry Communications es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Carboxylato complexes es_ES
dc.subject Crystal structures es_ES
dc.subject Manganese complexes es_ES
dc.subject Oxidation es_ES
dc.subject Polynuclear complexes es_ES
dc.subject Quinone complexes es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Manganese(III)-mediated oxidative carbon-carbon bond cleavage of 1,10-phenanthroline-5,6-dione ligand es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/S1387-7003(99)00144-6 es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Ruiz, R.; Caneschi, A.; Gatteschi, D.; Gaspar, AB.; Real, JA.; Fernández, I.; Muñoz Roca, MDC. (1999). Manganese(III)-mediated oxidative carbon-carbon bond cleavage of 1,10-phenanthroline-5,6-dione ligand. Inorganic Chemistry Communications. 2(11):521-523. https://doi.org/10.1016/S1387-7003(99)00144-6 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/S1387-7003(99)00144-6 es_ES
dc.description.upvformatpinicio 521 es_ES
dc.description.upvformatpfin 523 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 2 es_ES
dc.description.issue 11 es_ES
dc.relation.pasarela S\17447 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Dirección General de Investigación Científica y Técnica es_ES
dc.contributor.funder Direccion General de Ensenanza Superior e Investigacion Cientifica es_ES


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