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Are the Accompanying Cations of Doping Anions Influential in Conducting Organic Polymers? The Case of the Popular PEDOT

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Are the Accompanying Cations of Doping Anions Influential in Conducting Organic Polymers? The Case of the Popular PEDOT

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dc.contributor.author Fuentes, I. es_ES
dc.contributor.author Mostazo-Lopez, Maria Jose es_ES
dc.contributor.author Kelemen, Zsolt es_ES
dc.contributor.author Compañ Moreno, Vicente es_ES
dc.contributor.author Andrio, Andreu es_ES
dc.contributor.author Morallon, Emilia es_ES
dc.contributor.author Cazorla-Amoros, Diego es_ES
dc.contributor.author Viñas, Clara es_ES
dc.contributor.author Teixidor, Françesc es_ES
dc.date.accessioned 2020-03-24T06:14:22Z
dc.date.available 2020-03-24T06:14:22Z
dc.date.issued 2019-11-13 es_ES
dc.identifier.issn 0947-6539 es_ES
dc.identifier.uri http://hdl.handle.net/10251/139242
dc.description "This is the peer reviewed version of the following article: I. Fuentes, M. J. Mostazo-López, Z. Kelemen, V. Compañ, A. Andrio, E. Morallón, D. Cazorla-Amorós, C. Viñas, F. Teixidor, Chem. Eur. J. 2019, 25, 14308. , which has been published in final form at ttps://doi.org/10.1002/chem.201902708. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving." es_ES
dc.description.abstract [EN] Conducting organic polymers (COPs) are made of a conjugated polymer backbone supporting a certain degree of oxidation. These positive charges are compensated by the doping anions that are introduced into the polymer synthesis along with their accompanying cations. In this work, the influence of these cations on the stoichiometry and physicochemical properties of the resulting COPs have been investigated, something that has previously been overlooked, but, as here proven, is highly relevant. As the doping anion, metallacarborane [Co(C2B9H11)(2)](-) was chosen, which acts as a thistle. This anion binds to the accompanying cation with a distinct strength. If the binding strength is weak, the doping anion is more prone to compensate the positive charge of the polymer, and the opposite is also true. Thus, the ability of the doping anion to compensate the positive charges of the polymer can be tuned, and this determines the stoichiometry of the polymer. As the polymer, PEDOT was studied, whereas Cs+, Na+, K+, Li+, and H+ as cations. Notably, with the [Co(C2B9H11)(2)](-) anions, these cations are grouped into two sets, Cs+ and H+ in one and Na+, K+, and Li+ in the second, according to the stoichiometry of the COPs: 2:1 EDOT/[Co(C2B9H11)(2)](-) for Cs+ and H+, and 3:1 EDOT/[Co(C2B9H11)(2)](-) for Na+, K+, and Li+. The distinct stoichiometries are manifested in the physicochemical properties of the COPs, namely in the electrochemical response, electronic conductivity, ionic conductivity, and capacitance. es_ES
dc.description.sponsorship We gratefully acknowledge the Spanish Ministerio de Economa y Competitividad (MINECO; projects ENE/2015-69203-R and CTQ2016-75150-R) and the Generalitat de Catalunya (2014/SGR/149) for financial support. I.F. is enrolled in the Ph.D. program of the UAB. Z.K. is grateful for the general support of the European Union's Horizon 2020 Research and Innovation Program through a Marie Sklodowska-Curie grant (MSCA-IF-2016-751587). es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Conducting organic polymers es_ES
dc.subject PEDOT es_ES
dc.subject Electronic conductivity es_ES
dc.subject Ionic conductivity es_ES
dc.subject Capacitance es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Are the Accompanying Cations of Doping Anions Influential in Conducting Organic Polymers? The Case of the Popular PEDOT es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201902708 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/751587/EU/Tuning both the photoluminescence and conductive properties of new COP materials/
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2016-75150-R/ES/MATERIALES BASADOS EN CLUSTERES DE BORO PARA ENERGIA SOSTENIBLE Y APLICACIONES MEDIOAMBIENTALES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Generalitat de Catalunya//2014 SGR 149/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2015-69203-R/ES/DESARROLLO Y EVALUACION DE NUEVAS MEMBRANAS POLIMERICAS REFORZADAS CON NANOFIBRAS PARA SU APLICACION EN PILAS DE COMBUSTIBLE CON ELEVADA ESTABILIDAD TERMICA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.description.bibliographicCitation Fuentes, I.; Mostazo-Lopez, MJ.; Kelemen, Z.; Compañ Moreno, V.; Andrio, A.; Morallon, E.; Cazorla-Amoros, D.... (2019). Are the Accompanying Cations of Doping Anions Influential in Conducting Organic Polymers? The Case of the Popular PEDOT. Chemistry - A European Journal. 25(63):14308-14319. https://doi.org/10.1002/chem.201902708 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/chem.201902708 es_ES
dc.description.upvformatpinicio 14308 es_ES
dc.description.upvformatpfin 14319 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 25 es_ES
dc.description.issue 63 es_ES
dc.relation.pasarela S\402564 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Generalitat de Catalunya es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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dc.subject.ods 07.- Asegurar el acceso a energías asequibles, fiables, sostenibles y modernas para todos es_ES


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