- -

Dehydrogenative coupling of silanes with alcohols catalyzed by Cu-3(BTC)(2)

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Dehydrogenative coupling of silanes with alcohols catalyzed by Cu-3(BTC)(2)

Mostrar el registro sencillo del ítem

Ficheros en el ítem

[Cerrado]
Nombre: Dhakshinamoorthy; ...
Tamaño: 1.619Mb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2020-04-06T08:56:26Z
dc.date.available 2020-04-06T08:56:26Z
dc.date.issued 2016 es_ES
dc.identifier.issn 1359-7345 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140212
dc.description.abstract [EN] Cu-3(BTC)(2) is an efficient and reusable heterogeneous catalyst for the dehydrogenative coupling of silanes with alcohols. Activity data and CO adsorption suggest that Cu(II) and in situ generated Cu(I) are the active species. Other MOFs such as Fe(BTC), MIL-101(Cr) and UiO-66(Zr) are unable to promote this cross-coupling. es_ES
dc.description.sponsorship ADM thanks the University Grants Commission, New Delhi, for the award of Assistant Professorship under its Faculty Recharge Programme. ADM also thanks the Department of Science and Technology, India, for the financial support through Fast Track project (SB/FT/CS-166/2013) and the Generalidad Valenciana for financial aid supporting his stay at Valencia through the Prometeo programme. Financial support from the Spanish Ministry of Economy and Competitiveness (CTQ-2012-32315 and Severo Ochoa) and Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Communications es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Dehydrogenative coupling of silanes with alcohols catalyzed by Cu-3(BTC)(2) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c5cc10216b es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DST//SB%2FFT%2FCS-166%2F2013/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F014/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; Concepción Heydorn, P.; García Gómez, H. (2016). Dehydrogenative coupling of silanes with alcohols catalyzed by Cu-3(BTC)(2). Chemical Communications. 52(13):2725-2728. https://doi.org/10.1039/c5cc10216b es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c5cc10216b es_ES
dc.description.upvformatpinicio 2725 es_ES
dc.description.upvformatpfin 2728 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 52 es_ES
dc.description.issue 13 es_ES
dc.relation.pasarela S\328550 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder University Grants Commission, India es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Department of Science and Technology, Ministry of Science and Technology, India es_ES
dc.description.references Belelli, P. ., Ferreira, M. ., & Damiani, D. . (2000). A theoretical and experimental study of the possible phenytriethoxysilane species found on treated silica. Journal of Molecular Catalysis A: Chemical, 159(2), 315-325. doi:10.1016/s1381-1169(00)00186-2 es_ES
dc.description.references Díaz, I., & Pérez-Pariente, J. (2002). Synthesis of Spongelike Functionalized MCM-41 Materials from Gels Containing Amino Acids. Chemistry of Materials, 14(11), 4641-4646. doi:10.1021/cm020128a es_ES
dc.description.references Stratakis, M., & Garcia, H. (2012). Catalysis by Supported Gold Nanoparticles: Beyond Aerobic Oxidative Processes. Chemical Reviews, 112(8), 4469-4506. doi:10.1021/cr3000785 es_ES
dc.description.references Primo, A., Esteve-Adell, I., Blandez, J. F., Dhakshinamoorthy, A., Álvaro, M., Candu, N., … García, H. (2015). High catalytic activity of oriented 2.0.0 copper(I) oxide grown on graphene film. Nature Communications, 6(1). doi:10.1038/ncomms9561 es_ES
dc.description.references Chui, S. S. (1999). A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n. Science, 283(5405), 1148-1150. doi:10.1126/science.283.5405.1148 es_ES
dc.description.references Tranchemontagne, D. J., Mendoza-Cortés, J. L., O’Keeffe, M., & Yaghi, O. M. (2009). Secondary building units, nets and bonding in the chemistry of metal–organic frameworks. Chemical Society Reviews, 38(5), 1257. doi:10.1039/b817735j es_ES
dc.description.references Natarajan, S., & Mahata, P. (2009). Metal–organic framework structures – how closely are they related to classical inorganic structures? Chemical Society Reviews, 38(8), 2304. doi:10.1039/b815106g es_ES
dc.description.references Dhakshinamoorthy, A., & Garcia, H. (2014). Metal–organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles. Chem. Soc. Rev., 43(16), 5750-5765. doi:10.1039/c3cs60442j es_ES
dc.description.references Dhakshinamoorthy, A., Alvaro, M., Concepcion, P., & Garcia, H. (2011). Chemical instability of Cu3(BTC)2 by reaction with thiols. Catalysis Communications, 12(11), 1018-1021. doi:10.1016/j.catcom.2011.03.018 es_ES
dc.description.references Dhakshinamoorthy, A., Alvaro, M., & Garcia, H. (2015). Deactivation of Cu3(BTC)2 in the Synthesis of 2-Phenylquinoxaline. Catalysis Letters, 145(8), 1600-1605. doi:10.1007/s10562-015-1497-4 es_ES
dc.description.references Dhakshinamoorthy, A., Alvaro, M., & Garcia, H. (2010). Aerobic Oxidation of Benzylic Alcohols Catalyzed by Metal−Organic Frameworks Assisted by TEMPO. ACS Catalysis, 1(1), 48-53. doi:10.1021/cs1000703 es_ES
dc.description.references Schlichte, K., Kratzke, T., & Kaskel, S. (2004). Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound Cu3(BTC)2. Microporous and Mesoporous Materials, 73(1-2), 81-88. doi:10.1016/j.micromeso.2003.12.027 es_ES
dc.description.references Dhakshinamoorthy, A., Alvaro, M., & Garcia, H. (2010). Metal-Organic Frameworks as Efficient Heterogeneous Catalysts for the Regioselective Ring Opening of Epoxides. Chemistry - A European Journal, 16(28), 8530-8536. doi:10.1002/chem.201000588 es_ES
dc.description.references Dhakshinamoorthy, A., Alvaro, M., & Garcia, H. (2009). Metal organic frameworks as efficient heterogeneous catalysts for the oxidation of benzylic compounds with t-butylhydroperoxide. Journal of Catalysis, 267(1), 1-4. doi:10.1016/j.jcat.2009.08.001 es_ES
dc.description.references Opanasenko, M., Dhakshinamoorthy, A., Shamzhy, M., Nachtigall, P., Horáček, M., Garcia, H., & Čejka, J. (2013). Comparison of the catalytic activity of MOFs and zeolites in Knoevenagel condensation. Catal. Sci. Technol., 3(2), 500-507. doi:10.1039/c2cy20586f es_ES
dc.description.references Dhakshinamoorthy, A., Asiri, A. M., & Garcia, H. (2015). Metal–organic frameworks catalyzed C–C and C–heteroatom coupling reactions. Chemical Society Reviews, 44(7), 1922-1947. doi:10.1039/c4cs00254g es_ES
dc.description.references Dhakshinamoorthy, A., Alvaro, M., & Garcia, H. (2011). Metal–organic frameworks as heterogeneous catalysts for oxidation reactions. Catalysis Science & Technology, 1(6), 856. doi:10.1039/c1cy00068c es_ES
dc.description.references Rendler, S., Plefka, O., Karatas, B., Auer, G., Fröhlich, R., Mück-Lichtenfeld, C., … Oestreich, M. (2008). Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes. Chemistry - A European Journal, 14(36), 11512-11528. doi:10.1002/chem.200801377 es_ES
dc.description.references Fukumoto, K., Kasa, M., & Nakazawa, H. (2015). Dehydrogenative coupling of alcohol with hydrosilane catalyzed by an iron complex. Inorganica Chimica Acta, 431, 219-221. doi:10.1016/j.ica.2015.02.019 es_ES
dc.description.references Li, Y., & Yang, R. T. (2007). Gas Adsorption and Storage in Metal−Organic Framework MOF-177. Langmuir, 23(26), 12937-12944. doi:10.1021/la702466d es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem