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Dehydrogenative coupling of silanes with alcohols catalyzed by Cu-3(BTC)(2)

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Dehydrogenative coupling of silanes with alcohols catalyzed by Cu-3(BTC)(2)

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2020-04-06T08:56:26Z
dc.date.available 2020-04-06T08:56:26Z
dc.date.issued 2016 es_ES
dc.identifier.issn 1359-7345 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140212
dc.description.abstract [EN] Cu-3(BTC)(2) is an efficient and reusable heterogeneous catalyst for the dehydrogenative coupling of silanes with alcohols. Activity data and CO adsorption suggest that Cu(II) and in situ generated Cu(I) are the active species. Other MOFs such as Fe(BTC), MIL-101(Cr) and UiO-66(Zr) are unable to promote this cross-coupling. es_ES
dc.description.sponsorship ADM thanks the University Grants Commission, New Delhi, for the award of Assistant Professorship under its Faculty Recharge Programme. ADM also thanks the Department of Science and Technology, India, for the financial support through Fast Track project (SB/FT/CS-166/2013) and the Generalidad Valenciana for financial aid supporting his stay at Valencia through the Prometeo programme. Financial support from the Spanish Ministry of Economy and Competitiveness (CTQ-2012-32315 and Severo Ochoa) and Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation DST/ SB/FT/CS-166/2013 es_ES
dc.relation GV/Prometeo 2012-014 es_ES
dc.relation MINECO/CTQ-2012-32315 es_ES
dc.relation.ispartof Chemical Communications es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Dehydrogenative coupling of silanes with alcohols catalyzed by Cu-3(BTC)(2) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c5cc10216b es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; Concepción Heydorn, P.; García Gómez, H. (2016). Dehydrogenative coupling of silanes with alcohols catalyzed by Cu-3(BTC)(2). Chemical Communications. 52(13):2725-2728. https://doi.org/10.1039/c5cc10216b es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c5cc10216b es_ES
dc.description.upvformatpinicio 2725 es_ES
dc.description.upvformatpfin 2728 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 52 es_ES
dc.description.issue 13 es_ES
dc.relation.pasarela S\328550 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder University Grants Commission, India es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Department of Science and Technology, India es_ES


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