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A Deeper Microscopic Study of the Interaction between Gum Rosin Derivatives and a Mater-Bi Type Bioplastic

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A Deeper Microscopic Study of the Interaction between Gum Rosin Derivatives and a Mater-Bi Type Bioplastic

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dc.contributor.author Aldas-Carrasco, Miguel Fernando es_ES
dc.contributor.author Rayón, Emilio es_ES
dc.contributor.author López-Martínez, Juan es_ES
dc.contributor.author Arrieta, Marina P. es_ES
dc.date.accessioned 2020-04-07T05:49:39Z
dc.date.available 2020-04-07T05:49:39Z
dc.date.issued 2020-01-16 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140419
dc.description.abstract [EN] The interaction between gum rosin and gum rosin derivatives with Mater-Bi type bioplastic, a biodegradable and compostable commercial bioplastic, were studied. Gum rosin and two pentaerythritol esters of gum rosin (Lurefor 125 resin and Unik Tack P100 resin) were assessed as sustainable compatibilizers for the components of Mater-Bi® NF 866 polymeric matrix. To study the influence of each additive in the polymeric matrix, each gum rosin-based additive was compounded in 15 wt % by melt-extrusion and further injection molding process. Then, the mechanical properties were assessed, and the tensile properties and impact resistance were determined. Microscopic analyses were carried out by field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM) and atomic force microscopy with nanomechanical assessment (AFM-QNM). The oxygen barrier and wettability properties were also assayed. The study revealed that the commercial thermoplastic starch is mainly composed of three phases: A polybutylene adipate-co-terephthalate (PBAT) phase, an amorphous phase of thermoplastic starch (TPSa), and a semi-crystalline phase of thermoplastic starch (TPSc). The poor miscibility among the components of the Mater-Bi type bioplastic was confirmed. Finally, the formulations with the gum rosin and its derivatives showed an improvement of the miscibility and the solubility of the components depending on the additive used es_ES
dc.description.sponsorship This research was funded by Spanish Ministry of Economy and Competitiveness (MINECO), project: PROMADEPCOL (MAT2017-84909-C2-2-R) and M.P.A. s contract: Juan de la Cierva-Incorporación (FJCI-2017-33536). es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Polymers es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Microscopic es_ES
dc.subject Gum Rosin es_ES
dc.subject Biodegradable polymers es_ES
dc.subject Thermoplastic starch es_ES
dc.subject Gum rosin esters es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title A Deeper Microscopic Study of the Interaction between Gum Rosin Derivatives and a Mater-Bi Type Bioplastic es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/polym12010226 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//FJCI-2017-33536/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Aldas-Carrasco, MF.; Rayón, E.; López-Martínez, J.; Arrieta, MP. (2020). A Deeper Microscopic Study of the Interaction between Gum Rosin Derivatives and a Mater-Bi Type Bioplastic. Polymers. 12(1):1-17. https://doi.org/10.3390/polym12010226 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.3390/polym12010226 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 17 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 1 es_ES
dc.identifier.eissn 2073-4360 es_ES
dc.relation.pasarela S\400827 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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dc.subject.ods 12.- Garantizar las pautas de consumo y de producción sostenibles es_ES


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