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Temperature dependence of anomalous protonic and superprotonic transport properties in mixed salts based on CsH2PO4

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Temperature dependence of anomalous protonic and superprotonic transport properties in mixed salts based on CsH2PO4

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dc.contributor.author Andrio Balado, Andreu es_ES
dc.contributor.author Hernández, S. I. es_ES
dc.contributor.author García-Alcantara, C. es_ES
dc.contributor.author Del Castillo, L. F. es_ES
dc.contributor.author Compañ Moreno, Vicente es_ES
dc.contributor.author Santamaría-Holek, Ivàn es_ES
dc.date.accessioned 2020-04-17T12:49:44Z
dc.date.available 2020-04-17T12:49:44Z
dc.date.issued 2019-06-28 es_ES
dc.identifier.issn 1463-9076 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140893
dc.description.abstract [EN] We present an experimental study and a theoretical interpretation of the temperature dependence of the transport properties of doped CsH2PO4 salts in both protonic and superprotonic phases. Cesium phosphate based solid electrolytes are technologically relevant because their operational temperature range is about 100 to 300 degrees C in which a superprotonic transition may manifest depending on its mixed composition. The experimental study was carried out using impedance spectroscopy at the temperature range of 150-230 degrees C, and the protonic and superprotonic transport properties and proton concentrations were calculated and analyzed by using the electrode polarization, and the Debye and Cole-Cole models for the dielectric constant. We have shown that the transport properties predicted by the Cole-Cole model are consistent with the conductivity measurements whereas the Debye model shows some inconsistencies. We attribute this to the fact that the Cole-Cole model incorporates the effects of interactions among charge carriers better than the more commonly used Debye model. In this way, our work shows a more consistent approach to determine the transport properties of solid electrolytes and, therefore, provides a more reliable tool to analyze the transport properties of heterogeneous solid electrolytes that can be used in electrochemical devices, including fuel cells and supercapacitors. es_ES
dc.description.sponsorship This research was supported by Ministerio de Economia y Competitividad (MINECO) by means of the project reference: ENE/2015-69203-R. ISH, CGA and SIH are grateful to projects UNAM-DGAPA-PAPIIT-IN116617, IN117419 and IA104319. SIH is grateful to project LANCAD-UNAM-DGTIC-276. LFC is grateful to projects DGAPA-PAPIIT IG-100618 and DGAPA-PAPIIT IN114818. We gratefully acknowledge Profs Dr Francesc Teixidor and Dr Clara Vinas for technical assistance in SEM image and EDX analysis and preparation of samples for such studies. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Physical Chemistry Chemical Physics es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Temperature dependence of anomalous protonic and superprotonic transport properties in mixed salts based on CsH2PO4 es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8cp07472k es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNAM//IN116617/ES/Termodinámica de no equilibrio de sistemas pequeños autoconfinados (continuación)/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNAM//IN117419/MX/Termodinámica irreversible de sistemas electroquímicos y complejos./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNAM/PAPIIT/IA100919/MX/Homogeneización y cálculo de propiedades efectivas de materiales compuestos/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNAM//IN114818/MX/Fenómenos de transporte y propiedades termodinámicas en materia blanda/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNAM//IG100618/MX/Separación adsortiva de olefinas y parafinas/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNAM//LANCAD-UNAM-DGTIC-276/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2015-69203-R/ES/DESARROLLO Y EVALUACION DE NUEVAS MEMBRANAS POLIMERICAS REFORZADAS CON NANOFIBRAS PARA SU APLICACION EN PILAS DE COMBUSTIBLE CON ELEVADA ESTABILIDAD TERMICA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.description.bibliographicCitation Andrio Balado, A.; Hernández, SI.; García-Alcantara, C.; Del Castillo, LF.; Compañ Moreno, V.; Santamaría-Holek, I. (2019). Temperature dependence of anomalous protonic and superprotonic transport properties in mixed salts based on CsH2PO4. Physical Chemistry Chemical Physics. 21(24):12948-12960. https://doi.org/10.1039/c8cp07472k es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8cp07472k es_ES
dc.description.upvformatpinicio 12948 es_ES
dc.description.upvformatpfin 12960 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 21 es_ES
dc.description.issue 24 es_ES
dc.relation.pasarela S\402558 es_ES
dc.contributor.funder Universidad Nacional Autónoma de México es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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