Corma Canós, A.; Navas Escrig, J.; Ródenas Torralba, T.; Sabater Picot, MJ. (2013). One-Pot Palladium-Catalyzed Borrowing Hydrogen Synthesis of Thioethers. Chemistry - A European Journal. 19(51):17464-17471. https://doi.org/10.1002/chem.201302226
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/141289
Title:
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One-Pot Palladium-Catalyzed Borrowing Hydrogen Synthesis of Thioethers
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Author:
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Corma Canós, Avelino
Navas Escrig, Javier
Ródenas Torralba, Tania
Sabater Picot, Mª José
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UPV Unit:
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Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
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Issued date:
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Abstract:
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[EN] Palladium on magnesium oxide is able to allow a one-pot reaction to synthesize thioethers from thiols and aldehydes formed in situ from the respective alcohol by means of a borrowing hydrogen method. The reaction is ...[+]
[EN] Palladium on magnesium oxide is able to allow a one-pot reaction to synthesize thioethers from thiols and aldehydes formed in situ from the respective alcohol by means of a borrowing hydrogen method. The reaction is initiated by dehydrogenation of the alcohol to give a palladium hydride intermediate and an aldehyde. The latter reacts with a thiol involving most probably the intermediacy of a thionium ion RCHS+R, which can be reduced in situ by the metal hydride to afford thioethers.
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Subjects:
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Heterogeneous catalysis
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Hydrogen transfer
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Palladium
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Synthetic methods
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Thioethers
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Copyrigths:
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Reserva de todos los derechos
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Source:
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Chemistry - A European Journal. (issn:
0947-6539
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DOI:
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10.1002/chem.201302226
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Publisher:
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John Wiley & Sons
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Publisher version:
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https://doi.org/10.1002/chem.201302226
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Project ID:
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Generalitat Valenciana/PROMETEO/2008/130
...[+]
Generalitat Valenciana/PROMETEO/2008/130
MICIIN/MICIIN (MAT2011-28009)
MICINN/Consolider-Ingenio 2010
CSIC/I3-P fellowships
MICINN/Severo Ochoa
CSIC/JAE
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Description:
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This is the peer reviewed version of the following article: One-Pot Palladium-Catalyzed Borrowing Hydrogen Synthesis of Thioethers], which has been published in final form at [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."
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Thanks:
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Financial support by Consolider-Ingenio 2010 (project MULTICAT), Spanish MICINN (project MAT2011-28009), Generalitat Valenciana (project PROMETEO/2008/130), and Programa Severo Ochoa is acknowledged. T.R. and J.N. express ...[+]
Financial support by Consolider-Ingenio 2010 (project MULTICAT), Spanish MICINN (project MAT2011-28009), Generalitat Valenciana (project PROMETEO/2008/130), and Programa Severo Ochoa is acknowledged. T.R. and J.N. express their gratitude to Consejo Superior de Investigaciones Cientificas for I3-P and JAE fellowships.
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Type:
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Artículo
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