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Kinetic Analysis of the Thermal Degradation of Recycled Acrylonitrile-Butadiene-Styrene by non-Isothermal Thermogravimetry

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Kinetic Analysis of the Thermal Degradation of Recycled Acrylonitrile-Butadiene-Styrene by non-Isothermal Thermogravimetry

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dc.contributor.author Balart, Rafael es_ES
dc.contributor.author Garcia-Sanoguera, David es_ES
dc.contributor.author Quiles-Carrillo, Luis es_ES
dc.contributor.author Montanes, Nestor es_ES
dc.contributor.author Torres-Giner, S. es_ES
dc.date.accessioned 2020-04-24T07:13:09Z
dc.date.available 2020-04-24T07:13:09Z
dc.date.issued 2019 es_ES
dc.identifier.uri http://hdl.handle.net/10251/141430
dc.description.abstract [EN] This work presents an in-depth kinetic study of the thermal degradation of recycled acrylonitrile-butadiene-styrene (ABS) polymer. Non-isothermal thermogravimetric analysis (TGA) data in nitrogen atmosphere at different heating rates comprised between 2 and 30 K min¿1 were used to obtain the apparent activation energy (Ea) of the thermal degradation process of ABS by isoconversional (differential and integral) model-free methods. Among others, the differential Friedman method was used. Regarding integral methods, several methods with different approximations of the temperature integral were used, which gave different accuracies in Ea. In particular, the Flynn-Wall-Ozawa (FWO), the Kissinger-Akahira-Sunose (KAS), and the Starink methods were used. The results obtained by these methods were compared to the Kissinger method based on peak temperature (Tm) measurements at the maximum degradation rate. Combined Kinetic Analysis (CKA) was also carried out by using a modified expression derived from the general Sestak-Berggren equation with excellent results compared with the previous methods. Isoconversional methods revealed negligible variation of Ea with the conversion. Furthermore, the reaction model was assessed by calculating the characteristic "y(¿)" and "z(¿)" functions and comparing them with some master plots, resulting in a nth order reaction model with n = 1.4950, which allowed calculating the pre-exponential factor (A) of the Arrhenius constant. The results showed that Ea of the thermal degradation of ABS was 163.3 kJ mol¿1, while ln A was 27.5410 (A in min¿1). The predicted values obtained by integration of the general kinetic expression with the calculated kinetic triplet were in full agreement with the experimental data, thus giving evidence of the accuracy of the obtained kinetic parameters. es_ES
dc.description.sponsorship This research was supported by the Spanish Ministry of Economy and Competitiveness (MINECO) program numbers MAT2017-84909-C2-2-R. L.Q.-C. wants to thank the Generalitat Valenciana (GVA) for his FPI grant (ACIF/2016/182) and the Spanish Ministry of Education, Culture, and Sports (MECD) for his FPU grant (FPU15/03812), while S.T.-G. is a recipient of a Juan de la Cierva - Incorporacion contract (IJCI-2016-29675) from MINECO. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Polymers es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Thermal degradation es_ES
dc.subject Acrylonitrile-butadiene-styrene (ABS) es_ES
dc.subject Thermogravimetric analysis (TGA) es_ES
dc.subject Model free kinetics (MFK) es_ES
dc.subject Combined kinetic analysis (CKA) es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Kinetic Analysis of the Thermal Degradation of Recycled Acrylonitrile-Butadiene-Styrene by non-Isothermal Thermogravimetry es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/polym11020281 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//IJCI-2016-29675/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//ACIF%2F2016%2F182/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//FPU15%2F03812/ES/FPU15%2F03812/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Balart, R.; Garcia-Sanoguera, D.; Quiles-Carrillo, L.; Montanes, N.; Torres-Giner, S. (2019). Kinetic Analysis of the Thermal Degradation of Recycled Acrylonitrile-Butadiene-Styrene by non-Isothermal Thermogravimetry. Polymers. 11(2). https://doi.org/10.3390/polym11020281 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/polym11020281 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 11 es_ES
dc.description.issue 2 es_ES
dc.identifier.eissn 2073-4360 es_ES
dc.relation.pasarela S\377656 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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