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Effect of different compatibilizers on environmentally friendly composites from poly(lactic acid) and diatomaceous earth

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Effect of different compatibilizers on environmentally friendly composites from poly(lactic acid) and diatomaceous earth

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dc.contributor.author Agüero-Rodríguez, Ángel es_ES
dc.contributor.author Quiles-Carrillo, Luis es_ES
dc.contributor.author Jorda-Vilaplana, Amparo es_ES
dc.contributor.author Fenollar, Octavio es_ES
dc.contributor.author Montanes, Nestor es_ES
dc.date.accessioned 2020-04-24T07:14:10Z
dc.date.available 2020-04-24T07:14:10Z
dc.date.issued 2019 es_ES
dc.identifier.issn 0959-8103 es_ES
dc.identifier.uri http://hdl.handle.net/10251/141454
dc.description.abstract [EN] Environmentally friendly composites from poly(lactic acid) (PLA) and diatomaceous earth (DE) were successfully manufactured by extrusion, followed by injection moulding. DE was used as a filler; several compatibilizer/coupling agents, namely (3-glycidyloxypropyl)trimethoxysilane, epoxy styrene acrylic oligomer and maleinized linseed oil, were used to improve polymer¿filler interactions. Mechanical characterization was carried out by standard tensile, impact and hardness tests while morphological characterization of the fractured surfaces was conducted by field emission scanning electron microscopy. The effect of DE was evaluated by differential scanning calorimetry and dynamic mechanical thermal behaviour. The results show that the addition of DE provides an improved tensile modulus and induces more brittle composites due to stress concentration phenomena. The addition of compatibilizers in PLA-DE positively contributes to improve ductile properties, thus leading to high environmental efficiency materials with balancedmechanical properties. Specifically, the compatibility improvement between the PLA and DE was good with maleinized linseed oil and contributed to improving the impact strength, which is a key factor in PLA-based composites due to the intrinsic brittleness of neat PLA. es_ES
dc.description.sponsorship This research was supported by the Spanish Ministry of Economy and Competitiveness (MINECO) program number MAT2017-84909-C2-2-R. L. Quiles-Carrillo wants to thank GV for his FPI grant (ACIF/2016/182) and the MECD for his FPU grant (FPU15/03812). es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Polymer International es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Poly(lactic acid) es_ES
dc.subject Diatomaceous earth es_ES
dc.subject Composites es_ES
dc.subject Natural fillers es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification EXPRESION GRAFICA EN LA INGENIERIA es_ES
dc.title Effect of different compatibilizers on environmentally friendly composites from poly(lactic acid) and diatomaceous earth es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/pi.5779 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//ACIF%2F2016%2F182/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//FPU15%2F03812/ES/FPU15%2F03812/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Gráfica - Departament d'Enginyeria Gràfica es_ES
dc.description.bibliographicCitation Agüero-Rodríguez, Á.; Quiles-Carrillo, L.; Jorda-Vilaplana, A.; Fenollar, O.; Montanes, N. (2019). Effect of different compatibilizers on environmentally friendly composites from poly(lactic acid) and diatomaceous earth. Polymer International. 68(5):893-903. https://doi.org/10.1002/pi.5779 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/pi.5779 es_ES
dc.description.upvformatpinicio 893 es_ES
dc.description.upvformatpfin 903 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 68 es_ES
dc.description.issue 5 es_ES
dc.relation.pasarela S\382194 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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