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A comparative study on the effect of different reactive compatibilizers on injection-molded pieces of bio-based high-density polyethylene/polylactide blends

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A comparative study on the effect of different reactive compatibilizers on injection-molded pieces of bio-based high-density polyethylene/polylactide blends

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dc.contributor.author Quiles-Carrillo, Luis es_ES
dc.contributor.author Montanes, Nestor es_ES
dc.contributor.author Jorda-Vilaplana, Amparo es_ES
dc.contributor.author Balart, Rafael es_ES
dc.contributor.author Torres-Giner, S. es_ES
dc.date.accessioned 2020-04-29T07:04:49Z
dc.date.available 2020-04-29T07:04:49Z
dc.date.issued 2019-04 es_ES
dc.identifier.issn 0021-8995 es_ES
dc.identifier.uri http://hdl.handle.net/10251/141958
dc.description This is the peer reviewed version of the following article: Quiles-Carrillo, L., Montanes, N., Jorda-Vilaplana, A., Balart, R. and Torres-Giner, S. (2019), A comparative study on the effect of different reactive compatibilizers on injection-molded pieces of bio-based high-density polyethylene/polylactide blends. J. Appl. Polym. Sci., 136, 47396, which has been published in final form at https://doi.org/10.1002/APP.47396. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. es_ES
dc.description.abstract [EN] The present study reports on the development of binary blends consisting of bio-based high-density polyethylene (bio-HDPE) with polylactide (PLA), in the 5¿20 wt % range, prepared by melt compounding and then shaped into pieces by injection molding. In order to enhance the miscibility between the green polyolefin and the biopolyester, different reactive compatibilizers were added during the melt-blending process, namely polyethylene grafted maleic anhydride (PE-g-MA), poly(ethylene-co-glycidyl methacrylate) (PE-co-GMA), maleinized linseed oil (MLO), and a combination of MLO with dicumyl peroxide (DCP). Among the tested compatibilizers, the dual addition of MLO and DCP provided the binary blend pieces with the most balanced mechanical performance in terms of rigidity and impact strength as well as the highest thermal stability. The fracture surface of the binary blend piece processed with MLO and DCP revealed the formation of a continuous structure in which the dispersed PLA phase was nearly no discerned in the bio-HDPE matrix. The resultant miscibility improvement was ascribed to both the high solubility and plasticizing effect of MLO on the PLA phase as well as the crosslinking effect of DCP on both biopolymers. The latter effect was particularly related to the formation of macroradicals of each biopolymer that, thereafter, led to the in situ formation of bio HDPE-co-PLA copolymers and also to the development of a partially crosslinked network in the binary blend. As a result, cost-effective and fully bio-based polymer pieces with improved mechanical strength, high toughness, and enhanced thermal resistance were obtained. es_ES
dc.description.sponsorship This research was funded by the EU H2020 project YPACK (reference number 773872) and by the Ministry of Science, Innovation, and Universities (MICIU, project numbers MAT2017-84909-C2-2-R and AGL2015-63855-C2-1-R). Quiles-Carrillo and Torres-Giner are recipients of a FPU grant (FPU15/03812) from the Spanish Ministry of Education, Culture, and Sports (MECD) and a Juan de la Cierva contract (IJCI-2016-29675) from the MICIU, respectively. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Journal of Applied Polymer Science es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Biodegradable es_ES
dc.subject Biomaterials es_ES
dc.subject Morphology es_ES
dc.subject Mechanical Properties es_ES
dc.subject.classification EXPRESION GRAFICA EN LA INGENIERIA es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title A comparative study on the effect of different reactive compatibilizers on injection-molded pieces of bio-based high-density polyethylene/polylactide blends es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/APP.47396 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/773872/EU/HIGH PERFORMANCE POLYHYDROXYALKANOATES BASED PACKAGING TO MINIMISE FOOD WASTE/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//AGL2015-63855-C2-1-R/ES/DESARROLLO DE UN CONCEPTO DE ENVASE MULTICAPA ALIMENTARIO DE ALTA BARRERA Y CON CARACTER ACTIVO Y BIOACTIVO DERIVADO DE SUBPRODUCTOS ALIMENTARIOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//IJCI-2016-29675/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//FPU15%2F03812/ES/FPU15%2F03812/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Gráfica - Departament d'Enginyeria Gràfica es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Quiles-Carrillo, L.; Montanes, N.; Jorda-Vilaplana, A.; Balart, R.; Torres-Giner, S. (2019). A comparative study on the effect of different reactive compatibilizers on injection-molded pieces of bio-based high-density polyethylene/polylactide blends. Journal of Applied Polymer Science. 136(16). https://doi.org/10.1002/APP.47396 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/APP.47396 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 136 es_ES
dc.description.issue 16 es_ES
dc.relation.pasarela S\374543 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
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