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Improvement of the Electrochemical Behavior of (Sb, Sn, Cu)O Ceramic Electrodes as Electrochemical Advanced Oxidation Anodes

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Improvement of the Electrochemical Behavior of (Sb, Sn, Cu)O Ceramic Electrodes as Electrochemical Advanced Oxidation Anodes

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dc.contributor.author Giner-Sanz, Juan José es_ES
dc.contributor.author Sánchez-Rivera, María J. es_ES
dc.contributor.author García Gabaldón, Montserrat es_ES
dc.contributor.author Ortega Navarro, Emma María es_ES
dc.contributor.author Mestre, Sergio es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.date.accessioned 2020-04-29T07:05:47Z
dc.date.available 2020-04-29T07:05:47Z
dc.date.issued 2019-05-02 es_ES
dc.identifier.uri http://hdl.handle.net/10251/141980
dc.description This is the peer reviewed version of the following article: Giner-Sanz, J. J., Sanchez-Rivera, M. J., Garcia-Gabaldon, M., Ortega, E. M., Mestre, S., & Perez-Herranz, V. (2019). Improvement of the Electrochemical Behavior of (Sb, Sn, Cu)O Ceramic Electrodes as Electrochemical Advanced Oxidation Anodes. ChemElectroChem, 6(9), 2430-2437. https://doi.org/10.1002/celc.201801766, which has been published in final form at https://doi.org/10.1002/celc.201801766. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. es_ES
dc.description.abstract [EN] This work explores the possibility of increasing the active surface of a Sb-doped SnO2 ceramic electrode using CuO as sintering aid, by incorporating petroleum coke as a pore generator. In order to fulfil this goal, three series of (Sb, Sn, Cu)O electrodes with different coke contents were synthetized. The properties of the electrodes, and their microstructure, change significantly as a function of the coke content before sintering. The electrochemical characterization of the synthesized electrodes showed that the coke addition before sintering causes two antagonist effects on the performance of the (Sn, Sb, Cu)O as anodes in electrochemical advanced oxidation processes (EAOP). On one hand, it significantly improves the electrochemical roughness factor of the electrode, solving the densification problem in this way. On the other hand, it worsens the electrochemical behavior of the electrode: narrowing its electrochemical window; and ¿activating¿ it slightly. The addition of coke before sintering changes the kinetic parameters, leading to a kinetic situation in which the accumulation of hydroxyl radicals is slightly lower. A balance must be sought: an intermediate coke content will improve significantly the electrochemical roughness factor of the electrode, but will only worsen slightly its electrochemical behavior, leading to an optimum (Sn, Sb, Cu)O EAOP anode. es_ES
dc.description.sponsorship The authors are very grateful to the Ministerio de Economia y Competitividad (Projects: CTQ2015-65202-C2-1-R and CTQ2015- 65202-C2-2-R) and to the European Regional Development Fund (FEDER), for their economic support. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof ChemElectroChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Antimony-doped tin oxide electrodes es_ES
dc.subject Ceramic anodes es_ES
dc.subject Electrooxidation process es_ES
dc.subject Petroleum coke es_ES
dc.subject Pore generator es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.subject.classification INGENIERIA NUCLEAR es_ES
dc.title Improvement of the Electrochemical Behavior of (Sb, Sn, Cu)O Ceramic Electrodes as Electrochemical Advanced Oxidation Anodes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/celc.201801766 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-65202-C2-2-R/ES/NUEVOS ELECTRODOS CERAMICOS MEJORADOS MEDIANTE NANOTECNOLOGIA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-65202-C2-1-R/ES/CARACTERIZACION ELECTROQUIMICA DE ELECTRODOS CERAMICOS Y APLICACION A PROCESOS ELECTROQUIMICOS DE OXIDACION AVANZADA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//IDIFEDER%2F2018%2FA%2F044/ES/MODIFICACIÓN DE FOTOCATALIZADORES DE ÓXIDOS METÁLICOS NANOESTRUCTURADOS PARA LA ELIMINACIÓN DE FÁRMACOS Y PRODUCCIÓN ENERGÉTICA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Giner-Sanz, JJ.; Sánchez-Rivera, MJ.; García Gabaldón, M.; Ortega Navarro, EM.; Mestre, S.; Pérez-Herranz, V. (2019). Improvement of the Electrochemical Behavior of (Sb, Sn, Cu)O Ceramic Electrodes as Electrochemical Advanced Oxidation Anodes. ChemElectroChem. 6(9):2430-2437. https://doi.org/10.1002/celc.201801766 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/celc.201801766 es_ES
dc.description.upvformatpinicio 2430 es_ES
dc.description.upvformatpfin 2437 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 6 es_ES
dc.description.issue 9 es_ES
dc.identifier.eissn 2196-0216 es_ES
dc.relation.pasarela S\390457 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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