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dc.contributor.author | Aldas-Carrasco, Miguel Fernando | es_ES |
dc.contributor.author | Pavón-Vargas, Cristina Paola | es_ES |
dc.contributor.author | López-Martínez, Juan | es_ES |
dc.contributor.author | Arrieta, Marina Patricia | es_ES |
dc.date.accessioned | 2020-06-02T05:37:31Z | |
dc.date.available | 2020-06-02T05:37:31Z | |
dc.date.issued | 2020-04-08 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/144823 | |
dc.description.abstract | [EN] Fully bio-based materials based on thermoplastic starch (TPS) were developed starting from corn starch plasticized with glycerol. The obtained TPS was further blended with five pine resin derivatives: gum rosin (GR), disproportionated gum rosin (dehydroabietic acid, RD), maleic anhydride modified gum rosin (CM), pentaerythritol ester of gum rosin (LF), and glycerol ester of gum rosin (UG). The TPS¿resin blend formulations were processed by melt extrusion and further by injection moulding to simulate the industrial conditions. The obtained materials were characterized in terms of mechanical, thermal and structural properties. The results showed that all gum rosin-based additives were able to improve the thermal stability of TPS, increasing the degradation onset temperature. The carbonyl groups of gum rosin derivatives were able to interact with the hydroxyl groups of starch and glycerol by means of hydrogen bond interactions producing a significant increase of the glass transition temperature with a consequent stiffening effect, which in turn improve the overall mechanical performance of the TPS-resin injected moulded blends. The developed TPS¿resin blends are of interest for rigid packaging applications. | es_ES |
dc.description.sponsorship | This research was funded by the Spanish Ministry of Economy and Competitiveness (MINECO), project: PROMADEPCOL (MAT2017-84909-C2-2-R) as well as by Santander-UCM (PR87/19-22628) project. M.A. thanks Secretaria Nacional de Educación Superior, Ciencia, Tecnología e Innovación (SENESCYT-Ecuador) and Escuela Politécnica Nacional. C.P. thanks Santiago Grisolía fellowship (GRISOLIAP/2019/113) from Generalitat Valenciana and M.P.A. thanks MINECO for her postdoctoral contract: Juan de la Cierva-Incorporación (FJCI-2017-33536). | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | MDPI AG | es_ES |
dc.relation.ispartof | Applied Sciences | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Bioplastic | es_ES |
dc.subject | Corn starch | es_ES |
dc.subject | Glycerol | es_ES |
dc.subject | Thermoplastic starch | es_ES |
dc.subject | Gum rosin | es_ES |
dc.subject | Injection-moulding | es_ES |
dc.subject.classification | CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA | es_ES |
dc.title | Pine Resin Derivatives as Sustainable Additives to Improve the Mechanical and Thermal Properties of Injected Moulded Thermoplastic Starch | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.3390/app10072561 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/UCM//PR87%2F19-22628/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI//FJCI-2017-33536/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//GRISOLIAP%2F2019%2F113/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials | es_ES |
dc.description.bibliographicCitation | Aldas-Carrasco, MF.; Pavón-Vargas, CP.; López-Martínez, J.; Arrieta, MP. (2020). Pine Resin Derivatives as Sustainable Additives to Improve the Mechanical and Thermal Properties of Injected Moulded Thermoplastic Starch. Applied Sciences. 10(7):1-17. https://doi.org/10.3390/app10072561 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.3390/app10072561 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 17 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 10 | es_ES |
dc.description.issue | 7 | es_ES |
dc.identifier.eissn | 2076-3417 | es_ES |
dc.relation.pasarela | S\407338 | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Santander Universidades | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Universidad Complutense de Madrid | es_ES |
dc.contributor.funder | Escuela Politécnica Nacional, Ecuador | es_ES |
dc.contributor.funder | Secretaría de Educación Superior, Ciencia, Tecnología e Innovación, Ecuador | es_ES |
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dc.subject.ods | 12.- Garantizar las pautas de consumo y de producción sostenibles | es_ES |