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Structural and dielectric properties of Cobaltacarborane Composite Polybenzimidazole Membranes as solid polymer electrolytes at high temperature

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Structural and dielectric properties of Cobaltacarborane Composite Polybenzimidazole Membranes as solid polymer electrolytes at high temperature

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dc.contributor.author Fuentes, I. es_ES
dc.contributor.author Andrio Balado, Andreu es_ES
dc.contributor.author Garcia Bernabe, Abel es_ES
dc.contributor.author Escorihuela Fuentes, Jorge es_ES
dc.contributor.author Viñas, Clara es_ES
dc.contributor.author Teixidor, F. es_ES
dc.contributor.author Compañ Moreno, Vicente es_ES
dc.date.accessioned 2020-06-03T05:52:45Z
dc.date.available 2020-06-03T05:52:45Z
dc.date.issued 2018-04-21 es_ES
dc.identifier.issn 1463-9076 es_ES
dc.identifier.uri http://hdl.handle.net/10251/145106
dc.description.abstract [EN] The conductivity of a series of composite membranes, based on polybenzimidazole (PBI) containing the metallacarborane salt M[Co(C2B9H11)(2)], M[COSANE] and tetraphenylborate, M[B(C6H5)(4)], M[TPB] both anions having the same number of atoms and the same negative charge, has been investigated. Different cations (M = H+, Li+ and Na+) have been studied and the composite membranes have been characterized by water uptake, swelling ratios, ATR FT-IR, thermogravimetric analysis and electrochemical impedance spectroscopy to explore the dielectric response and ion dynamics in composite membranes. Our results show that conductivity increases with increasing temperature and it is higher for H+ than for Li+ and Na+ for all temperatures under study. The mobility of Li+ is greater in [COSANE](-) than in [TPB](-) composite PBI@membranes while for Na+ it is the opposite. The temperature dependence of the conductivity of the composite was followed by a typical Arrhenius behaviour with two different regions: (1) between 20 and 100 degrees C, and (2) between 100 and 150 degrees C. Using the analysis of electrode polarization (EP) based on the Thrukhan theory we have calculated the ionic diffusion coefficients and the density of carriers. From the double logarithmic plot of the imaginary part of the conductivity (sigma '') versus frequency in the entire range of temperatures studied we have determined for each sample at each temperature, the frequency values of the onset (f(ON)) and full development of electrode polarization (f(MAX)), respectively, which permit us to calculate static permittivity. es_ES
dc.description.sponsorship We gratefully acknowledge Spanish Ministerio de Economia y Competitividad (MINECO) for financial support by the ENE/2015-69203-R project and CTQ2016-75150-R project, and Generalitat de Catalunya (2014/SGR/149). I. Fuentes is enrolled in the PhD program of the UAB. The authors acknowledge Dr Oscar Sahuquillo for technical assistance in TGA. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Physical Chemistry Chemical Physics es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Structural and dielectric properties of Cobaltacarborane Composite Polybenzimidazole Membranes as solid polymer electrolytes at high temperature es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8cp00372f es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Generalitat de Catalunya//2014 SGR 149/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2016-75150-R/ES/MATERIALES BASADOS EN CLUSTERES DE BORO PARA ENERGIA SOSTENIBLE Y APLICACIONES MEDIOAMBIENTALES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2015-69203-R/ES/DESARROLLO Y EVALUACION DE NUEVAS MEMBRANAS POLIMERICAS REFORZADAS CON NANOFIBRAS PARA SU APLICACION EN PILAS DE COMBUSTIBLE CON ELEVADA ESTABILIDAD TERMICA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.description.bibliographicCitation Fuentes, I.; Andrio Balado, A.; Garcia Bernabe, A.; Escorihuela Fuentes, J.; Viñas, C.; Teixidor, F.; Compañ Moreno, V. (2018). Structural and dielectric properties of Cobaltacarborane Composite Polybenzimidazole Membranes as solid polymer electrolytes at high temperature. Physical Chemistry Chemical Physics. 20(15):10173-10185. https://doi.org/10.1039/c8cp00372f es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8cp00372f es_ES
dc.description.upvformatpinicio 10173 es_ES
dc.description.upvformatpfin 10185 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 20 es_ES
dc.description.issue 15 es_ES
dc.identifier.pmid 29594295 es_ES
dc.relation.pasarela S\372598 es_ES
dc.contributor.funder Generalitat de Catalunya es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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