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Bio-Polyethylene-Based Composites Reinforced with Alkali and Palmitoyl Chloride-Treated Coffee Silverskin

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Bio-Polyethylene-Based Composites Reinforced with Alkali and Palmitoyl Chloride-Treated Coffee Silverskin

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dc.contributor.author Dominici, Franco es_ES
dc.contributor.author Garcia-Garcia, Daniel es_ES
dc.contributor.author Fombuena, Vicent es_ES
dc.contributor.author Luzi, Francesca es_ES
dc.contributor.author Puglia, Debora es_ES
dc.contributor.author Torre, Luigi es_ES
dc.contributor.author Balart, Rafael es_ES
dc.date.accessioned 2020-06-09T03:32:19Z
dc.date.available 2020-06-09T03:32:19Z
dc.date.issued 2019-08-27 es_ES
dc.identifier.issn 1420-3049 es_ES
dc.identifier.uri http://hdl.handle.net/10251/145750
dc.description.abstract [EN] This work investigates the feasibility of using coffee silverskin (CSS) as a reinforcing agent in biobased polyethylene (BioPE) composites, by adding it in bulk and thin film samples. The effect of two different treatments, alkali bleaching (CSS_A) and esterification with palmitoyl chloride (CSS_P), on mechanical, thermal, morphological and water absorption behavior of produced materials at different CSS loading (10, 20 and 30 wt %) was investigated. A reactive graft copolymerization of BioPE with maleic anhydride was considered in the case of alkali treated CSS. It was found that, when introduced in bulk samples, improvement in the elastic modulus and a reduction in strain at maximum stress were observed with the increase in CSS fraction for the untreated and treated CSS composites, while the low aspect ratio of the CSS particles and their poor adhesion with the polymeric matrix were responsible for reduced ductility in films, decreasing crystallinity values and reduction of elastic moduli. When CSS_A and CSS_P are introduced in the matrix, a substantial reduction in the water uptake is also obtained in films, mainly due to presence of maleated PE, that builds up some interactions to eliminate the amounts of OH groups and hydrophobized CSS, due to the weakened absorption capacity of the functionalized CSS. es_ES
dc.description.sponsorship This research was partially funded by the Ministry of Science, Innovation, and Universities (MICIU) project number MAT2017-84909-C2-2-R. D.G.G. wants to thank the Universitat Politècnica de València for financial support through a postdoctoral contract [PAID-10-18]. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Molecules es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Coffee silverskin es_ES
dc.subject Biopolyethelene es_ES
dc.subject Alkali es_ES
dc.subject Palmitoyl chloride es_ES
dc.subject Composites es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Bio-Polyethylene-Based Composites Reinforced with Alkali and Palmitoyl Chloride-Treated Coffee Silverskin es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/molecules24173113 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-10-18/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Dominici, F.; Garcia-Garcia, D.; Fombuena, V.; Luzi, F.; Puglia, D.; Torre, L.; Balart, R. (2019). Bio-Polyethylene-Based Composites Reinforced with Alkali and Palmitoyl Chloride-Treated Coffee Silverskin. Molecules. 24(17):1-14. https://doi.org/10.3390/molecules24173113 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https:doi.org/10.3390/molecules24173113 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 14 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 24 es_ES
dc.description.issue 17 es_ES
dc.identifier.pmid 31461962 es_ES
dc.identifier.pmcid PMC6749558 es_ES
dc.relation.pasarela S\392405 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
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