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Effect of an organotin catalyst on the physicochemical properties and biocompatibility of castor oil-based polyurethane/cellulose composites

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Effect of an organotin catalyst on the physicochemical properties and biocompatibility of castor oil-based polyurethane/cellulose composites

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dc.contributor.author Villegas-Villalobos, S. es_ES
dc.contributor.author Diaz, L.E. es_ES
dc.contributor.author Vilariño, Guillermo es_ES
dc.contributor.author Vallés Lluch, Ana es_ES
dc.contributor.author Gómez-Tejedor, José-Antonio es_ES
dc.contributor.author Valero, M.F. es_ES
dc.date.accessioned 2020-06-11T03:33:49Z
dc.date.available 2020-06-11T03:33:49Z
dc.date.issued 2018-09-14 es_ES
dc.identifier.issn 0884-2914 es_ES
dc.identifier.uri http://hdl.handle.net/10251/145999
dc.description.abstract [EN] Polyurethane/cellulose composites were synthesized from castor-oil-derived polyols and isophorone diisocyanate using dibutyltin dilaurate (DBTDL) as the catalyst. Materials were obtained by adding 2% cellulose in the form of either microcrystals (20 lm) or nanocrystals obtained by acid hydrolysis. The aim was to assess the effects of filler particle size and the use of a catalyst on the physicochemical properties and biological response of these composites. The addition of the catalyst was found to be essential to prevent filler aggregations and to enhance the tensile strength and elongation at break. The cellulose particle size influenced the composite properties, as its nanocrystals heighten hydrogen bond interactions between the filler surface and polyurethane domains, improving resistance to hydrolytic degradation. All hybrids retained cell viability, and the addition of DBTDL did not impair their biocompatibility. The samples were prone to calcification, which suggests that they could find application in the development of bioactive materials. es_ES
dc.description.sponsorship Universidad de La Sabana supported this work under Grant No. ING-176-2016. S.V.V. acknowledges the Universidad de La Sabana for the Teaching Assistant Scholarship for his master's studies. J.A.G.T. and A.V.L. acknowledge the support of the Spanish Ministry of Economy and Competitiveness (MINECO) through project DPI2015-65401-C3-2-R (including FEDER financial support). The authors acknowledge the assistance and advice of the Electron Microscopy Service of the UPV. CIBER-BBN is an initiative funded by the VI National R&D&I Plan 2008-2011, Iniciativa Ingenio 2010, Consolider Program. CIBER Actions are financed by the Instituto de Salud Carlos III with assistance from the European Regional Development Fund. es_ES
dc.language Inglés es_ES
dc.publisher Cambridge University Press (Materials Research Society) es_ES
dc.relation.ispartof Journal of Materials Research es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Polymer es_ES
dc.subject Composite es_ES
dc.subject Organometallic-catalyst es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Effect of an organotin catalyst on the physicochemical properties and biocompatibility of castor oil-based polyurethane/cellulose composites es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1557/jmr.2018.286 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Universidad de La Sabana//ING-176-2016/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//DPI2015-65401-C3-2-R/ES/SOPORTES POLIMERICOS MULTIFUNCIONALES PARA CO-CULTIVO CELULAR INDIRECTO Y ESTIMULACION QUIMICA DESTINADOS A MIMETIZAR TEJIDO RENAL IN VITRO/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Villegas-Villalobos, S.; Diaz, L.; Vilariño, G.; Vallés Lluch, A.; Gómez-Tejedor, J.; Valero, M. (2018). Effect of an organotin catalyst on the physicochemical properties and biocompatibility of castor oil-based polyurethane/cellulose composites. Journal of Materials Research. 33(17):2598-2611. https://doi.org/10.1557/jmr.2018.286 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1557/jmr.2018.286 es_ES
dc.description.upvformatpinicio 2598 es_ES
dc.description.upvformatpfin 2611 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 33 es_ES
dc.description.issue 17 es_ES
dc.relation.pasarela S\368669 es_ES
dc.contributor.funder Universidad de La Sabana es_ES
dc.contributor.funder Instituto de Salud Carlos III es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
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