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Influence of Phase Composition of Bulk Tungsten Vanadium Oxides on the Aerobic Transformation of Methanol and Glycerol

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Influence of Phase Composition of Bulk Tungsten Vanadium Oxides on the Aerobic Transformation of Methanol and Glycerol

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dc.contributor.author Delgado-Muñoz, Daniel es_ES
dc.contributor.author Chieregato, Alessandro es_ES
dc.contributor.author Soriano Rodríguez, Mª Dolores es_ES
dc.contributor.author Rodríguez-Aguado, E. es_ES
dc.contributor.author Ruiz-Rodríguez, Lidia es_ES
dc.contributor.author Rodriguez-Castellon, E. es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2020-06-12T03:33:07Z
dc.date.available 2020-06-12T03:33:07Z
dc.date.issued 2018-03-14 es_ES
dc.identifier.issn 1434-1948 es_ES
dc.identifier.uri http://hdl.handle.net/10251/146160
dc.description.abstract [EN] A series of W-V-O catalysts with different m-WO3 and h-WO3 phase contents were hydrothermally synthesized by employing different tungsten, vanadium, and ammonium precursors and characterized by powder XRD, N-2 adsorption, SEM, X-ray energy-dispersive spectroscopy, thermogravimetric analysis, Raman and FTIR spectroscopy, NH3 temperature programmed desorption, H-2 temperature-programmed reduction, and XPS. Finally, the acid/redox properties were analyzed by using aerobic transformation of methanol as a characterization reaction. A correlation between phase composition as well as acid and redox properties was observed, which were correlated to the catalytic performance of the title materials in a one-pot oxydehydration reaction of glycerol. The hexagonal tungsten bronze (h-WO3) phase shows a significantly higher concentration of acid sites than monoclinic m-WO3, so that the acid properties of W-V-O oxides are directly related to the presence of h-WO3 crystals. The presence of a higher concentration of acid sites in V-containing h-WO3 crystals is a key factor to achieve high selectivity to both acrolein and acrylic acid during one-pot glycerol oxydehydration. Also, V sites in h-WO3 show higher selectivity in the consecutive reaction (partial oxidation of acrolein to acrylic acid), while V sites in the m-WO3 phase fundamentally lead to the formation of carbon oxides. es_ES
dc.description.sponsorship The authors acknowledge the DGICYT in Spain, CTQ2015-68951-C3-1-R and CTQ2015-68951-C3-3-R. Authors from ITQ also thank Project SEV-2016-0683 for financial support. D. D. thanks MINECO and Severo Ochoa Excellence Program for his fellowship (SVP-2014-068669). The research group of Prof. Fabrizio Cavani (University of Bologna, Italy)and Consorzio INSTM (Firenze) are gratefully acknowledged for a PhD grant to A. C. Authors also thank the Electron Microscopy Service of Universitat Politecnica de Valencia for their support. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof European Journal of Inorganic Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Oxydehydration es_ES
dc.subject Hydrothermal synthesis es_ES
dc.subject Vanadium es_ES
dc.subject Tungsten es_ES
dc.subject Oxidation es_ES
dc.title Influence of Phase Composition of Bulk Tungsten Vanadium Oxides on the Aerobic Transformation of Methanol and Glycerol es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/ejic.201800059 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-3-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SVP-2014-068669/ES/SVP-2014-068669/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-1-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Delgado-Muñoz, D.; Chieregato, A.; Soriano Rodríguez, MD.; Rodríguez-Aguado, E.; Ruiz-Rodríguez, L.; Rodriguez-Castellon, E.; López Nieto, JM. (2018). Influence of Phase Composition of Bulk Tungsten Vanadium Oxides on the Aerobic Transformation of Methanol and Glycerol. European Journal of Inorganic Chemistry. 10:1204-1211. https://doi.org/10.1002/ejic.201800059 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/ejic.201800059 es_ES
dc.description.upvformatpinicio 1204 es_ES
dc.description.upvformatpfin 1211 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.relation.pasarela S\376756 es_ES
dc.contributor.funder Università di Bologna es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali, Italia es_ES
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