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Antibiotics mineralization by electrochemical and UV-based hybrid processes: evaluation of the synergistic effect

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Antibiotics mineralization by electrochemical and UV-based hybrid processes: evaluation of the synergistic effect

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dc.contributor.author da Silva, Salatiel W. es_ES
dc.contributor.author Heberle, Alan N.A. es_ES
dc.contributor.author Santos, Alexia P. es_ES
dc.contributor.author Rodrigues, M.A.S. es_ES
dc.contributor.author Valentín Pérez-Herranz es_ES
dc.contributor.author Bernardes, A.M. es_ES
dc.date.accessioned 2020-06-12T03:33:17Z
dc.date.available 2020-06-12T03:33:17Z
dc.date.issued 2018 es_ES
dc.identifier.issn 0959-3330 es_ES
dc.identifier.uri http://hdl.handle.net/10251/146163
dc.description.abstract [EN] Antibiotics are not efficiently removed in conventional wastewater treatments. In fact, different advanced oxidation process (AOPs), including ozone, peroxide, UV radiation, among others, are being investigated in the elimination of microcontaminants. Most of AOPs proved to be efficient on the degradation of antibiotics, but the mineralization is on the one hand not evaluated or on the other hand not high. At this work, the UV-based hybrid process, namely Photo-assisted electrochemical oxidation (PEO), was applied, aiming the mineralization of microcontaminants such as the antibiotics Amoxicillin (AMX), Norfloxacin (NOR) and Azithromycin (AZI). The influence of the individual contributions of electrochemical oxidation (EO) and the UV-base processes on the hybrid process (PEO) was analysed. Results showed that AMX and NOR presented higher mineralization rate under direct photolysis than AZI due to the high absorption of UV radiation. For the EO processes, a low mineralization was found for all antibiotics, what was associated to a mass-transport limitation related to the low concentration of contaminants (200 ¿g/L). Besides that, an increase in mineralization was found, when heterogeneous photocatalysis and EO are compared, due to the influence of UV radiation, which overcomes the mass-transport limitations. Although the UV-based processes control the reaction pathway that leads to mineralization, the best results to mineralize the antibiotics were achieved by PEO hybrid process. This can be explained by the synergistic effect of the processes that constitute them. A higher mineralization was achieved, which is an important and useful finding to avoid the discharge of microcontaminants in the environment. es_ES
dc.description.sponsorship The authors thank CAPES project number DGPU-2015/7595/14-0, CNPq, FAPERGS, Cyted and FINEP for the financial support. es_ES
dc.language Inglés es_ES
dc.publisher Taylor & Francis es_ES
dc.relation.ispartof Environmental Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject UV-based processes es_ES
dc.subject Electrochemical oxidation es_ES
dc.subject Hybrid process es_ES
dc.subject Photoassisted electrochemical oxidation es_ES
dc.subject Antibiotics es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Antibiotics mineralization by electrochemical and UV-based hybrid processes: evaluation of the synergistic effect es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1080/09593330.2018.1478453 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CAPES//DGPU-2015%2F7595%2F14-0/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Da Silva, SW.; Heberle, AN.; Santos, AP.; Rodrigues, M.; Valentín Pérez-Herranz; Bernardes, A. (2018). Antibiotics mineralization by electrochemical and UV-based hybrid processes: evaluation of the synergistic effect. Environmental Technology. https://doi.org/10.1080/09593330.2018.1478453 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1080/09593330.2018.1478453 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.identifier.pmid 29770731 es_ES
dc.relation.pasarela S\369886 es_ES
dc.contributor.funder Financiadora de Estudos e Projetos, Brasil es_ES
dc.contributor.funder Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul es_ES
dc.contributor.funder CYTED Ciencia y Tecnología para el Desarrollo es_ES
dc.contributor.funder Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, Brasil es_ES
dc.contributor.funder Conselho Nacional de Desenvolvimento Científico e Tecnológico, Brasil es_ES
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