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Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance

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Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance

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Gallego-Sánchez, EM.; Li, C.; Paris, C.; Martín-García, N.; Martínez-Triguero, J.; Boronat Zaragoza, M.; Moliner Marin, M.... (2018). Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance. Chemistry - A European Journal. 24(55):14631-14635. https://doi.org/10.1002/chem.201803637

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Título: Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance
Autor: Gallego-Sánchez, Eva María Li, Chengeng Paris, Cecilia Martín-García, Nuria Martínez-Triguero, Joaquín Boronat Zaragoza, Mercedes Moliner Marin, Manuel Corma Canós, Avelino
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Fecha difusión:
Resumen:
[EN] From theoretical calculations and a rational synthesis methodology, it has been possible to prepare nanocrystalline (60-80 nm) chabazite with an optimized framework Al distribution that has a positive impact on its ...[+]
Palabras clave: Aluminum , Chabazite , Light olefins , Methanol-to-olefin process , Zeolites
Derechos de uso: Reserva de todos los derechos
Fuente:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.201803637
Editorial:
John Wiley & Sons
Versión del editor: https://doi.org/10.1002/chem.201803637
Código del Proyecto:
info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
info:eu-repo/grantAgreement/MINECO//MAT2015-71261-R/ES/DISEÑO RACIONAL DE MATERIALES ZEOLITICOS CON CENTROS METALICOS PARA SU APLICACION EN PROCESOS QUIMICOS SOSTENIBLES, MEDIOAMBIENTALES Y ENERGIAS RENOVABLES/
info:eu-repo/grantAgreement/MINECO//BES-2013-064347/ES/BES-2013-064347/
info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/
Agradecimientos:
This work has been supported by the EU through ERC-AdG-2014-671093, by the Spanish Government-MINECO through "Severo Ochoa" (SEV-2016-0683) and MAT2015-71261-R, and by the Fundacion Ramon Areces through a research contract ...[+]
Tipo: Artículo

References

Tian, P., Wei, Y., Ye, M., & Liu, Z. (2015). Methanol to Olefins (MTO): From Fundamentals to Commercialization. ACS Catalysis, 5(3), 1922-1938. doi:10.1021/acscatal.5b00007

Olsbye, U., Svelle, S., Bjørgen, M., Beato, P., Janssens, T. V. W., Joensen, F., … Lillerud, K. P. (2012). Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity. Angewandte Chemie International Edition, 51(24), 5810-5831. doi:10.1002/anie.201103657

Olsbye, U., Svelle, S., Bjørgen, M., Beato, P., Janssens, T. V. W., Joensen, F., … Lillerud, K. P. (2012). Umwandlung von Methanol in Kohlenwasserstoffe: Wie Zeolith-Hohlräume und Porengröße die Produktselektivität bestimmen. Angewandte Chemie, 124(24), 5910-5933. doi:10.1002/ange.201103657 [+]
Tian, P., Wei, Y., Ye, M., & Liu, Z. (2015). Methanol to Olefins (MTO): From Fundamentals to Commercialization. ACS Catalysis, 5(3), 1922-1938. doi:10.1021/acscatal.5b00007

Olsbye, U., Svelle, S., Bjørgen, M., Beato, P., Janssens, T. V. W., Joensen, F., … Lillerud, K. P. (2012). Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity. Angewandte Chemie International Edition, 51(24), 5810-5831. doi:10.1002/anie.201103657

Olsbye, U., Svelle, S., Bjørgen, M., Beato, P., Janssens, T. V. W., Joensen, F., … Lillerud, K. P. (2012). Umwandlung von Methanol in Kohlenwasserstoffe: Wie Zeolith-Hohlräume und Porengröße die Produktselektivität bestimmen. Angewandte Chemie, 124(24), 5910-5933. doi:10.1002/ange.201103657

Moliner, M., Martínez, C., & Corma, A. (2013). Synthesis Strategies for Preparing Useful Small Pore Zeolites and Zeotypes for Gas Separations and Catalysis. Chemistry of Materials, 26(1), 246-258. doi:10.1021/cm4015095

Stöcker, M. (1999). Methanol-to-hydrocarbons: catalytic materials and their behavior. Microporous and Mesoporous Materials, 29(1-2), 3-48. doi:10.1016/s1387-1811(98)00319-9

Wilson, S., & Barger, P. (1999). The characteristics of SAPO-34 which influence the conversion of methanol to light olefins. Microporous and Mesoporous Materials, 29(1-2), 117-126. doi:10.1016/s1387-1811(98)00325-4

Hemelsoet, K., Van der Mynsbrugge, J., De Wispelaere, K., Waroquier, M., & Van Speybroeck, V. (2013). Unraveling the Reaction Mechanisms Governing Methanol-to-Olefins Catalysis by Theory and Experiment. ChemPhysChem, 14(8), 1526-1545. doi:10.1002/cphc.201201023

Haw, J. F., & Marcus, D. M. (2005). Well-defined (supra)molecular structures in zeolite methanol-to-olefin catalysis. Topics in Catalysis, 34(1-4), 41-48. doi:10.1007/s11244-005-3798-0

Bleken, F., Bjørgen, M., Palumbo, L., Bordiga, S., Svelle, S., Lillerud, K.-P., & Olsbye, U. (2009). The Effect of Acid Strength on the Conversion of Methanol to Olefins Over Acidic Microporous Catalysts with the CHA Topology. Topics in Catalysis, 52(3), 218-228. doi:10.1007/s11244-008-9158-0

Lok, B. M., Messina, C. A., Patton, R. L., Gajek, R. T., Cannan, T. R., & Flanigen, E. M. (1984). Silicoaluminophosphate molecular sieves: another new class of microporous crystalline inorganic solids. Journal of the American Chemical Society, 106(20), 6092-6093. doi:10.1021/ja00332a063

Chen, J. Q., Bozzano, A., Glover, B., Fuglerud, T., & Kvisle, S. (2005). Recent advancements in ethylene and propylene production using the UOP/Hydro MTO process. Catalysis Today, 106(1-4), 103-107. doi:10.1016/j.cattod.2005.07.178

S. I. Zones L. T. Yuen S. J. Miller WO/2003/020641 2003

Takata, T., Tsunoji, N., Takamitsu, Y., Sadakane, M., & Sano, T. (2016). Nanosized CHA zeolites with high thermal and hydrothermal stability derived from the hydrothermal conversion of FAU zeolite. Microporous and Mesoporous Materials, 225, 524-533. doi:10.1016/j.micromeso.2016.01.045

Wu, L., Degirmenci, V., Magusin, P. C. M. M., Szyja, B. M., & Hensen, E. J. M. (2012). Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction. Chemical Communications, 48(76), 9492. doi:10.1039/c2cc33994c

Li, Z., Navarro, M. T., Martínez-Triguero, J., Yu, J., & Corma, A. (2016). Synthesis of nano-SSZ-13 and its application in the reaction of methanol to olefins. Catalysis Science & Technology, 6(15), 5856-5863. doi:10.1039/c6cy00433d

Zhu, X., Kosinov, N., Hofmann, J. P., Mezari, B., Qian, Q., Rohling, R., … Hensen, E. J. M. (2016). Fluoride-assisted synthesis of bimodal microporous SSZ-13 zeolite. Chemical Communications, 52(15), 3227-3230. doi:10.1039/c6cc00201c

Di Iorio, J. R., & Gounder, R. (2016). Controlling the Isolation and Pairing of Aluminum in Chabazite Zeolites Using Mixtures of Organic and Inorganic Structure-Directing Agents. Chemistry of Materials, 28(7), 2236-2247. doi:10.1021/acs.chemmater.6b00181

Di Iorio, J. R., Nimlos, C. T., & Gounder, R. (2017). Introducing Catalytic Diversity into Single-Site Chabazite Zeolites of Fixed Composition via Synthetic Control of Active Site Proximity. ACS Catalysis, 7(10), 6663-6674. doi:10.1021/acscatal.7b01273

D. Xie S. I. Zones R. J. Saxton WO2016/032565 2016

Martín, N., Li, Z., Martínez-Triguero, J., Yu, J., Moliner, M., & Corma, A. (2016). Nanocrystalline SSZ-39 zeolite as an efficient catalyst for the methanol-to-olefin (MTO) process. Chemical Communications, 52(36), 6072-6075. doi:10.1039/c5cc09719c

S. I. Zones US4544538 1985

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