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Iridium complexes catalysed the selective dehydrogenation of glucose to gluconic acid in water

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Iridium complexes catalysed the selective dehydrogenation of glucose to gluconic acid in water

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dc.contributor.author Borja, Pilar es_ES
dc.contributor.author Vicent, Cristian es_ES
dc.contributor.author Baya, Miguel es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Mata, Jose A. es_ES
dc.date.accessioned 2020-06-20T03:30:39Z
dc.date.available 2020-06-20T03:30:39Z
dc.date.issued 2018-09-07 es_ES
dc.identifier.issn 1463-9262 es_ES
dc.identifier.uri http://hdl.handle.net/10251/146716
dc.description.abstract [EN] We describe an unprecedented catalytic dehydrogenation of glucose by homogeneous catalysts. Iridium(iii) complexes containing the fragment [Cp*Ir(NHC)](2+) (NHC = N-heterocyclic carbene ligand) are shown to be very active and highly selective catalysts for the dehydrogenation of glucose to gluconic acid and molecular hydrogen. Glucose is converted to gluconic acid at a catalyst loading of 2 mol%, at reflux in water, without additives and with a selectivity of over 95%. Experimental evidence obtained by H-1 NMR spectroscopy and mass spectrometry (ESI/MS) reveals the formation of iridium coordinated to glucose and gluconic acid species. A plausible mechanism is proposed, based on the experimental evidence and supported by DFT calculations. es_ES
dc.description.sponsorship The authors thank the MINECO (Severo Ochoa, CTQ2015-69153-C2-1-R, CTQ2015-69153-C2-2-R and CTQ2015-67461-P), Diputacion General de Aragon (Grupo Consolidado E21) and Universitat Jaume I (P1.1B2015-09) for financial support. P. Borja thanks the Universitat Jaume I for a postdoctoral grant. The authors are very grateful to the 'Serveis Centrals d'Instrumentacio Cientifica (SCIC)' of the Universitat Jaume I, S. Fuertes (Universidad of Zaragoza) for data collection of the X-ray structure of 4 and to the Instituto de Biocomputacion y Fisica de Sistemas Complejos (BIFI) and the Centro de Supercomputacion de Galicia (CESGA) for the generous allocation of computational resources. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Green Chemistry es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Iridium complexes catalysed the selective dehydrogenation of glucose to gluconic acid in water es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8gc01933a es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-2-R/ES/APLICACIONES CATALITICAS DE COMPUESTOS ORGANOMETALICOS INMOVILIZADOS EN LA SUFPERFICIE DE GRAFENOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-67461-P/ES/COMPUESTOS ORGANOMETALICOS IMPLICADOS EN PROCESOS REDOX Y%2FO FOTOINDUCIDOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DGA//E21/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UJI//P1.1B2015-09/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-1-R/ES/EXPLOTANDO EL USO DEL GRAFENO EN CATALISIS. USO DEL GRAFENO COMO CARBOCATALIZADOR O COMO SOPORTE/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Borja, P.; Vicent, C.; Baya, M.; García Gómez, H.; Mata, JA. (2018). Iridium complexes catalysed the selective dehydrogenation of glucose to gluconic acid in water. Green Chemistry. 20(17):4094-4101. https://doi.org/10.1039/c8gc01933a es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8gc01933a es_ES
dc.description.upvformatpinicio 4094 es_ES
dc.description.upvformatpfin 4101 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 20 es_ES
dc.description.issue 17 es_ES
dc.relation.pasarela S\382649 es_ES
dc.contributor.funder Universitat Jaume I es_ES
dc.contributor.funder Diputación General de Aragón es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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