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Electrospun Poly(ethylene-co-vinyl alcohol)/Graphene Nanoplatelets Composites of Interest in Intelligent Food Packaging Applications

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Electrospun Poly(ethylene-co-vinyl alcohol)/Graphene Nanoplatelets Composites of Interest in Intelligent Food Packaging Applications

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dc.contributor.author Torres-Giner, S. es_ES
dc.contributor.author Echegoyen, Y. es_ES
dc.contributor.author TERUEL JUANES, ROBERTO es_ES
dc.contributor.author Badia, Jose D. es_ES
dc.contributor.author Ribes-Greus, A. es_ES
dc.contributor.author Lagaron Cabello, José María es_ES
dc.date.accessioned 2020-07-04T03:31:56Z
dc.date.available 2020-07-04T03:31:56Z
dc.date.issued 2018-09-20 es_ES
dc.identifier.uri http://hdl.handle.net/10251/147424
dc.description.abstract [EN] Graphene nanoplatelets (GNPs) were synthetized from graphite powder and, thereafter, embedded in poly(ethylene-co-vinyl alcohol) (EVOH) fibers by electrospinning in the 0.1-2 wt.-% range. The morphological, chemical, and thermal characterization performed on the electrospun nanocomposite fibers mats revealed that the GNPs were efficiently dispersed and rolled along the EVOH fibrilar matrix up to contents of 0.5 wt.-%. Additionally, the dielectric behavior of the nanocomposite fibers was evaluated as a function of the frequency range and GNPs content. The obtained results indicated that their dielectric constant rapidly decreased with the frequency increase and only increased at low GNPs loadings while the nanocomposite fiber mats became electrically conductive, with the maximum at 0.5 wt.-% GNPs content. Finally, the electrospun mats were subjected to a thermal post-treatment and dark films with a high contact transparency were obtained, suggesting that the nanocomposites can be used either in a nonwoven fibers form or in a continuous film form. This study demonstrates the potential of electrospinning as a promising technology to produce GNPs-containing materials with high electrical conductivity that can be of potential interest in intelligent packaging applications as "smart" labels or tags. es_ES
dc.description.sponsorship This research was funded by the European Regional Development Funds (ERDF) and Ministry of Science, Innovation, and Universities (MICIU) project numbers ENE2014-53734-C2-1-R, ENE2017-86711-C3-1-R, UPOV13-3E-1947, and AGL2015-63855-C2-1-R. S.T.-G. acknowledges the MICIU for his Juan de la Cierva contract (IJCI-2016-29675). J.D.B. and R.T.-J. also thank Generalitat Valenciana (GV) for their projects APOSTD14/041 and GRISOLIA/2012/003, respectively. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Nanomaterials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject EVOH es_ES
dc.subject Graphene es_ES
dc.subject Electrospinning es_ES
dc.subject Smart labels es_ES
dc.subject Intelligent packaging es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Electrospun Poly(ethylene-co-vinyl alcohol)/Graphene Nanoplatelets Composites of Interest in Intelligent Food Packaging Applications es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/nano8100745 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//UPOV13-3E-1947/ES/Cromatrografía por Exclusión de Tamaños/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//AGL2015-63855-C2-1-R/ES/DESARROLLO DE UN CONCEPTO DE ENVASE MULTICAPA ALIMENTARIO DE ALTA BARRERA Y CON CARACTER ACTIVO Y BIOACTIVO DERIVADO DE SUBPRODUCTOS ALIMENTARIOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//GRISOLIA%2F2012%2F003/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//IJCI-2016-29675/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//APOSTD%2F2014%2F041/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2014-53734-C2-1-R/ES/DISEÑO Y VALIDACION DE MEMBRANAS CON CONTROL MORFOLOGICO PARA SU USO EN PILAS DE COMBUSTIBLE DE BAJA TEMPERATURA SOSTENIBLES EN VEHICULOS EFICIENTES NO TRIPULADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2017-86711-C3-1-R/ES/SISTEMA INTEGRADO DE DESCARBONIZACION Y PRODUCCION DE ENERGIA BASADO EN PILAS DE COMBUSTIBLE DE METANOL DIRECTO PARA APLICACIONES NAVALES Y AEROESPACIALES/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Máquinas y Motores Térmicos - Departament de Màquines i Motors Tèrmics es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Torres-Giner, S.; Echegoyen, Y.; Teruel Juanes, R.; Badia, JD.; Ribes-Greus, A.; Lagaron Cabello, JM. (2018). Electrospun Poly(ethylene-co-vinyl alcohol)/Graphene Nanoplatelets Composites of Interest in Intelligent Food Packaging Applications. Nanomaterials. 8(10):1-19. https://doi.org/10.3390/nano8100745 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/nano8100745 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 19 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 10 es_ES
dc.identifier.eissn 2079-4991 es_ES
dc.identifier.pmid 30241290 es_ES
dc.identifier.pmcid PMC6215290 es_ES
dc.relation.pasarela S\379306 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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