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Vanadium Supported on Alumina and/or Zirconia Catalysts for the Selective Transformation of Ethane and Methanol

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Vanadium Supported on Alumina and/or Zirconia Catalysts for the Selective Transformation of Ethane and Methanol

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dc.contributor.author Benomar, S. es_ES
dc.contributor.author Masso Ramírez, Amada es_ES
dc.contributor.author Solsona Espriu, Benjamin Eduardo es_ES
dc.contributor.author Isaadi, R. es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2020-07-08T03:32:19Z
dc.date.available 2020-07-08T03:32:19Z
dc.date.issued 2018-04 es_ES
dc.identifier.uri http://hdl.handle.net/10251/147629
dc.description.abstract [EN] Vanadium supported on pure (Al2O3, ZrO2) or mixed zirconia-alumina (with Al/(Al + Zr) ratio of 0.75 or 0.25) catalysts have been prepared by wet impregnation, using homemade prepared supports. The catalysts have been characterized and tested in the oxidative dehydrogenation (ODH) of ethane and in the methanol aerobic transformation. The catalytic performance strongly depends on the nature of the metal oxide support. Thus, activity decreases in the order: VOx/ZrO2 > VOx/(Al,Zr-oxides) > VOx/Al2O3. On the other hand, at low and medium ethane conversions, the selectivity to ethylene presents an opposite trend: VOx/Al2O3 > VOx/(Al,Zr-oxides) > VOx/ZrO2. The different selectivity to ethylene at high conversion is due to the lower/higher initial ethylene formation and to the extent of the ethylene decomposition. Interestingly, VOx/(Al,Zr-oxides) with low Zr-loading present the lowest ethylene decomposition. The catalytic results obtained mainly depend on the nature of the supports whereas the role of the dispersion of vanadium species is unclear. In methanol oxidation, the catalysts tested present similar catalytic activity regardless of the support (Al2O3, ZrO2 or mixed Al2O3-ZrO2) but strong differences in the selectivity to the reaction products. Thus, dimethyl ether was mainly observed on alumina-supported vanadium oxide catalysts (which is associated to the presence of acidic sites on the surface of the catalyst, as determined by TPD-NH3). Formaldehyde was the main reaction product on catalysts supported on Zr-containing oxides (which can be related to a low presence of acid sites). In this article, the importance of the presence of acid sites in ethane ODH, which can be estimated using the methanol transformation reaction, is also discussed. es_ES
dc.description.sponsorship The authors would like to acknowledge the DGICYT (CTQ2015-68951-C3-1-R and MAT2017-84118-C2-1-R projects), the Secretary of State for International Cooperation in Spain (Project AP/040992/11) and FEDER for financial support. B.S. also thanks the University of Valencia (UV-INV-AE16-484416). es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Catalysts es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject ODH of ethane es_ES
dc.subject Ethylene es_ES
dc.subject Methanol transformation es_ES
dc.subject Formaldehyde es_ES
dc.subject Dimethyl ether es_ES
dc.subject Vanadium es_ES
dc.subject Zirconia es_ES
dc.subject Alumina es_ES
dc.title Vanadium Supported on Alumina and/or Zirconia Catalysts for the Selective Transformation of Ethane and Methanol es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/catal8040126 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84118-C2-1-R/ES/VALORIZACION DE RECURSOS NATURALES COMO NUEVOS MATERIALES AVANZADOS :APLICACIONES CATALITICAS Y ELECTROQUIMICAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MAEC//AP%2F040992%2F11/ES/PREPARACIÓN, CARACTERIZACIÓN Y PROPIEDADES CATALÍTICAS PARA REACCIONES CATALÍTICAS SOSTENIBLES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UV//INV-AE16-484416/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-1-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Benomar, S.; Masso Ramírez, A.; Solsona Espriu, BE.; Isaadi, R.; López Nieto, JM. (2018). Vanadium Supported on Alumina and/or Zirconia Catalysts for the Selective Transformation of Ethane and Methanol. Catalysts. 8(4):1-18. https://doi.org/10.3390/catal8040126 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/catal8040126 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 18 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 4 es_ES
dc.identifier.eissn 2073-4344 es_ES
dc.relation.pasarela S\383056 es_ES
dc.contributor.funder Universitat de València es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Asuntos Exteriores y Cooperación es_ES
dc.contributor.funder Agencia Española de Cooperación Internacional para el Desarrollo es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.description.references Chieregato, A., López Nieto, J. M., & Cavani, F. (2015). Mixed-oxide catalysts with vanadium as the key element for gas-phase reactions. Coordination Chemistry Reviews, 301-302, 3-23. doi:10.1016/j.ccr.2014.12.003 es_ES
dc.description.references Nieto, J. M. L. (2006). The selective oxidative activation of light alkanes. From supported vanadia to multicomponent bulk V-containing catalysts. Topics in Catalysis, 41(1-4), 3-15. doi:10.1007/s11244-006-0088-4 es_ES
dc.description.references Wachs, I. E. (2013). Catalysis science of supported vanadium oxide catalysts. Dalton Transactions, 42(33), 11762. doi:10.1039/c3dt50692d es_ES
dc.description.references James, O. O., Mandal, S., Alele, N., Chowdhury, B., & Maity, S. (2016). Lower alkanes dehydrogenation: Strategies and reaction routes to corresponding alkenes. Fuel Processing Technology, 149, 239-255. doi:10.1016/j.fuproc.2016.04.016 es_ES
dc.description.references Blasco, T., & Nieto, J. M. L. (1997). Oxidative dyhydrogenation of short chain alkanes on supported vanadium oxide catalysts. Applied Catalysis A: General, 157(1-2), 117-142. doi:10.1016/s0926-860x(97)00029-x es_ES
dc.description.references Kung, H. H., & Kung, M. C. (1997). Oxidative dehydrogenation of alkanes over vanadium-magnesium-oxides. Applied Catalysis A: General, 157(1-2), 105-116. doi:10.1016/s0926-860x(97)00028-8 es_ES
dc.description.references Cavani, F., & Trifirò, F. (1997). Some aspects that affect the selective oxidation of paraffins. Catalysis Today, 36(4), 431-439. doi:10.1016/s0920-5861(96)00234-9 es_ES
dc.description.references Bañares, M. A. (1999). Supported metal oxide and other catalysts for ethane conversion: a review. Catalysis Today, 51(2), 319-348. doi:10.1016/s0920-5861(99)00053-x es_ES
dc.description.references Bhasin, M. ., McCain, J. ., Vora, B. ., Imai, T., & Pujadó, P. . (2001). Dehydrogenation and oxydehydrogenation of paraffins to olefins. Applied Catalysis A: General, 221(1-2), 397-419. doi:10.1016/s0926-860x(01)00816-x es_ES
dc.description.references Cavani, F., Ballarini, N., & Cericola, A. (2007). Oxidative dehydrogenation of ethane and propane: How far from commercial implementation? Catalysis Today, 127(1-4), 113-131. doi:10.1016/j.cattod.2007.05.009 es_ES
dc.description.references Gärtner, C. A., van Veen, A. C., & Lercher, J. A. (2013). Oxidative Dehydrogenation of Ethane: Common Principles and Mechanistic Aspects. ChemCatChem, 5(11), 3196-3217. doi:10.1002/cctc.201200966 es_ES
dc.description.references Galli, A., López Nieto, J. M., Dejoz, A., & Vazquez, M. I. (1995). The effect of potassium on the selective oxidation ofn-butane and ethane over Al2O3-supported vanadia catalysts. Catalysis Letters, 34(1-2), 51-58. doi:10.1007/bf00808321 es_ES
dc.description.references Argyle, M. D., Chen, K., Bell, A. T., & Iglesia, E. (2002). Ethane Oxidative Dehydrogenation Pathways on Vanadium Oxide Catalysts. The Journal of Physical Chemistry B, 106(21), 5421-5427. doi:10.1021/jp0144552 es_ES
dc.description.references Dinse, A., Ozarowski, A., Hess, C., Schomäcker, R., & Dinse, K.-P. (2008). Potential of High-Frequency EPR for Investigation of Supported Vanadium Oxide Catalysts. The Journal of Physical Chemistry C, 112(45), 17664-17671. doi:10.1021/jp807159f es_ES
dc.description.references Chen, K., Bell, A. T., & Iglesia, E. (2002). The Relationship between the Electronic and Redox Properties of Dispersed Metal Oxides and Their Turnover Rates in Oxidative Dehydrogenation Reactions. Journal of Catalysis, 209(1), 35-42. doi:10.1006/jcat.2002.3620 es_ES
dc.description.references López Nieto, J. M., Soler, J., Concepción, P., Herguido, J., Menéndez, M., & Santamarı́a, J. (1999). Oxidative Dehydrogenation of Alkanes over V-based Catalysts: Influence of Redox Properties on Catalytic Performance. Journal of Catalysis, 185(2), 324-332. doi:10.1006/jcat.1999.2467 es_ES
dc.description.references Argyle, M. D., Chen, K., Iglesia, E., & Bell, A. T. (2005). In situ UV−Visible Spectroscopic Measurements of Kinetic Parameters and Active Sites for Catalytic Oxidation of Alkanes on Vanadium Oxides†. The Journal of Physical Chemistry B, 109(6), 2414-2420. doi:10.1021/jp040166c es_ES
dc.description.references Al-Ghamdi, S. A., & de Lasa, H. I. (2014). Propylene production via propane oxidative dehydrogenation over VOx/γ-Al2O3 catalyst. Fuel, 128, 120-140. doi:10.1016/j.fuel.2014.02.033 es_ES
dc.description.references SOLSONA, B., DEJOZ, A., GARCIA, T., CONCEPCION, P., NIETO, J., VAZQUEZ, M., & NAVARRO, M. (2006). Molybdenum–vanadium supported on mesoporous alumina catalysts for the oxidative dehydrogenation of ethane. Catalysis Today, 117(1-3), 228-233. doi:10.1016/j.cattod.2006.05.025 es_ES
dc.description.references Chen, S., Ma, F., Xu, A., Wang, L., Chen, F., & Lu, W. (2014). Study on the structure, acidic properties of V–Zr nanocrystal catalysts in oxidative dehydrogenation of propane. Applied Surface Science, 289, 316-325. doi:10.1016/j.apsusc.2013.10.158 es_ES
dc.description.references Elbadawi, A. H., Ba-Shammakh, M. S., Al-Ghamdi, S., Razzak, S. A., & Hossain, M. M. (2016). Reduction kinetics and catalytic activity of VO x /γ-Al 2 O 3 -ZrO 2 for gas phase oxygen free ODH of ethane. Chemical Engineering Journal, 284, 448-457. doi:10.1016/j.cej.2015.08.048 es_ES
dc.description.references Rostom, S., & de Lasa, H. I. (2017). Propane Oxidative Dehydrogenation Using Consecutive Feed Injections and Fluidizable VOx/γAl2O3 and VOx/ZrO2–γAl2O3 Catalysts. Industrial & Engineering Chemistry Research, 56(45), 13109-13124. doi:10.1021/acs.iecr.7b01369 es_ES
dc.description.references HERACLEOUS, E., & LEMONIDOU, A. (2006). Ni–Nb–O mixed oxides as highly active and selective catalysts for ethene production via ethane oxidative dehydrogenation. Part I: Characterization and catalytic performance. Journal of Catalysis, 237(1), 162-174. doi:10.1016/j.jcat.2005.11.002 es_ES
dc.description.references Skoufa, Z., Heracleous, E., & Lemonidou, A. A. (2015). On ethane ODH mechanism and nature of active sites over NiO-based catalysts via isotopic labeling and methanol sorption studies. Journal of Catalysis, 322, 118-129. doi:10.1016/j.jcat.2014.11.014 es_ES
dc.description.references Ipsakis, D., Heracleous, E., Silvester, L., Bukur, D. B., & Lemonidou, A. A. (2017). Reduction and oxidation kinetic modeling of NiO-based oxygen transfer materials. Chemical Engineering Journal, 308, 840-852. doi:10.1016/j.cej.2016.09.114 es_ES
dc.description.references Delgado, D., Solsona, B., Ykrelef, A., Rodríguez-Gómez, A., Caballero, A., Rodríguez-Aguado, E., … López Nieto, J. M. (2017). Redox and Catalytic Properties of Promoted NiO Catalysts for the Oxidative Dehydrogenation of Ethane. The Journal of Physical Chemistry C, 121(45), 25132-25142. doi:10.1021/acs.jpcc.7b07066 es_ES
dc.description.references Solsona, B., Concepción, P., López Nieto, J. M., Dejoz, A., Cecilia, J. A., Agouram, S., … Rodríguez Castellón, E. (2016). Nickel oxide supported on porous clay heterostructures as selective catalysts for the oxidative dehydrogenation of ethane. Catalysis Science & Technology, 6(10), 3419-3429. doi:10.1039/c5cy01811k es_ES
dc.description.references Gärtner, C. A., van Veen, A. C., & Lercher, J. A. (2014). Oxidative Dehydrogenation of Ethane on Dynamically Rearranging Supported Chloride Catalysts. Journal of the American Chemical Society, 136(36), 12691-12701. doi:10.1021/ja505411s es_ES
dc.description.references Tatibouët, J. M. (1997). Methanol oxidation as a catalytic surface probe. Applied Catalysis A: General, 148(2), 213-252. doi:10.1016/s0926-860x(96)00236-0 es_ES
dc.description.references Forzatti, P., Tronconi, E., Elmi, A. S., & Busca, G. (1997). Methanol oxidation over vanadia-based catalysts. Applied Catalysis A: General, 157(1-2), 387-408. doi:10.1016/s0926-860x(97)00026-4 es_ES
dc.description.references Wachs, I. E., Chen, Y., Jehng, J.-M., Briand, L. E., & Tanaka, T. (2003). Molecular structure and reactivity of the Group V metal oxides. Catalysis Today, 78(1-4), 13-24. doi:10.1016/s0920-5861(02)00337-1 es_ES
dc.description.references Shah, P. R., Baldychev, I., Vohs, J. M., & Gorte, R. J. (2009). Comparison of redox isotherms for vanadia supported on zirconia and titania. Applied Catalysis A: General, 361(1-2), 13-17. doi:10.1016/j.apcata.2009.03.036 es_ES
dc.description.references Baldychev, I., Gorte, R. J., & Vohs, J. M. (2010). The impact of redox properties on the reactivity of V2O5/Al2O3 catalysts. Journal of Catalysis, 269(2), 397-403. doi:10.1016/j.jcat.2009.11.022 es_ES
dc.description.references Hess, C. (2009). Nanostructured Vanadium Oxide Model Catalysts for Selective Oxidation Reactions. ChemPhysChem, 10(2), 319-326. doi:10.1002/cphc.200800585 es_ES
dc.description.references Smith, M. A., Zoelle, A., Yang, Y., Rioux, R. M., Hamilton, N. G., Amakawa, K., … Trunschke, A. (2014). Surface roughness effects in the catalytic behavior of vanadia supported on SBA-15. Journal of Catalysis, 312, 170-178. doi:10.1016/j.jcat.2014.01.011 es_ES
dc.description.references Wang, N., Qiu, J., Wu, J., You, K., & Luo, H. (2015). A Comparison of the Redox Properties of Bulk Vanadium Mixed Oxide Catalysts. Catalysis Letters, 145(9), 1792-1797. doi:10.1007/s10562-015-1584-6 es_ES
dc.description.references Beck, B., Harth, M., Hamilton, N. G., Carrero, C., Uhlrich, J. J., Trunschke, A., … Schomäcker, R. (2012). Partial oxidation of ethanol on vanadia catalysts on supporting oxides with different redox properties compared to propane. Journal of Catalysis, 296, 120-131. doi:10.1016/j.jcat.2012.09.008 es_ES
dc.description.references KIM, T., & WACHS, I. (2008). CH3OH oxidation over well-defined supported V2O5/Al2O3 catalysts: Influence of vanadium oxide loading and surface vanadium–oxygen functionalities. Journal of Catalysis, 255(2), 197-205. doi:10.1016/j.jcat.2008.02.007 es_ES
dc.description.references Baldychev, I., Vohs, J. M., & Gorte, R. J. (2011). The effect of support on redox properties and methanol-oxidation activity of vanadia catalysts. Applied Catalysis A: General, 391(1-2), 86-91. doi:10.1016/j.apcata.2010.05.051 es_ES
dc.description.references Zhang, F., Chupas, P. J., Lui, S. L. A., Hanson, J. C., Caliebe, W. A., Lee, P. L., & Chan, S.-W. (2007). In situ Study of the Crystallization from Amorphous to Cubic Zirconium Oxide:  Rietveld and Reverse Monte Carlo Analyses. Chemistry of Materials, 19(13), 3118-3126. doi:10.1021/cm061739w es_ES
dc.description.references Pieck, C. L., del Val, S., López Granados, M., Bañares, M. A., & Fierro, J. L. G. (2002). Bulk and Surface Structures of V2O5/ZrO2Systems and Their Relevance foro-Xylene Oxidation. Langmuir, 18(7), 2642-2648. doi:10.1021/la0114631 es_ES
dc.description.references Soriano, M. D., Rodríguez-Castellón, E., García-González, E., & López Nieto, J. M. (2014). Catalytic behavior of NaV6O15 bronze for partial oxidation of hydrogen sulfide. Catalysis Today, 238, 62-68. doi:10.1016/j.cattod.2014.02.030 es_ES
dc.description.references Kanervo, J. M., Harlin, M. E., Krause, A. O. I., & Bañares, M. A. (2003). Characterisation of alumina-supported vanadium oxide catalysts by kinetic analysis of H2-TPR data. Catalysis Today, 78(1-4), 171-180. doi:10.1016/s0920-5861(02)00326-7 es_ES
dc.description.references Hess, C., Tzolova-Müller, G., & Herbert, R. (2007). The Influence of Water on the Dispersion of Vanadia Supported on Silica SBA-15:  A Combined XPS and Raman Study. The Journal of Physical Chemistry C, 111(26), 9471-9479. doi:10.1021/jp0713920 es_ES


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