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Thermo- and photo-modulation of exciplex fluorescence in a 3D spin crossover Hofmann-type coordination polymer

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Thermo- and photo-modulation of exciplex fluorescence in a 3D spin crossover Hofmann-type coordination polymer

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dc.contributor.author Delgado, T. es_ES
dc.contributor.author Meneses-Sánchez, M. es_ES
dc.contributor.author Piñeiro-López, L. es_ES
dc.contributor.author Bartual-Murgui, C. es_ES
dc.contributor.author Muñoz Roca, María Del Carmen es_ES
dc.contributor.author Real, J.A. es_ES
dc.date.accessioned 2020-07-08T03:32:39Z
dc.date.available 2020-07-08T03:32:39Z
dc.date.issued 2018-11-28 es_ES
dc.identifier.issn 2041-6520 es_ES
dc.identifier.uri http://hdl.handle.net/10251/147639
dc.description.abstract [EN] The search for bifunctional materials showing synergies between spin crossover (SCO) and luminescence has attracted substantial interest since they could be promising platforms for new switching electronic and optical technologies. In this context, we present the first three-dimensional Fe-II Hofmann-type coordination polymer exhibiting SCO properties and luminescence. The complex {Fe-II(bpben)[Au(CN)(2)]}@pyr (bpben = 1,4-bis(4-pyridyl)benzene) functionalized with pyrene (pyr) guests undergoes a cooperative multi-step SCO, which has been investigated by single crystal X-ray diffraction, single crystal UV-Vis absorption spectroscopy, and magnetic and calorimetric measurements. The resulting fluorescence from pyrene and exciplex emissions are controlled by the thermal and light irradiation (LIESST effect) dependence of the high/low-spin state population of Fe-II. Conversely, the SCO can be tracked by monitoring the fluorescence emission. This ON-OFF interplay between SCO and luminescence combined with the amenability of Hofmann-type materials to be processed at the nano-scale may be relevant for the generation of SCO-based sensors, actuators and spintronic devices. es_ES
dc.description.sponsorship This work was supported by the Spanish Ministerio de Economia y Competitividad (MINECO), FEDER (CTQ2013-46275-P and CTQ2016-78341-P), Unidad de Excelencia Maria de Maeztu (MDM-2015-0538), Generalitat Valenciana (PROMETEO/2016/147) and the Swiss National Science Foundation (Project number 200021-169033). es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.subject FE(ABPT)(2)(NCX)(2) X es_ES
dc.subject State es_ES
dc.subject Transition es_ES
dc.subject Complexes es_ES
dc.subject Behavior es_ES
dc.subject Nanocomposite es_ES
dc.subject Hysteresis es_ES
dc.subject Pressure es_ES
dc.subject Emission es_ES
dc.subject Networks es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Thermo- and photo-modulation of exciplex fluorescence in a 3D spin crossover Hofmann-type coordination polymer es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8sc02677g es_ES
dc.relation.projectID info:eu-repo/grantAgreement/SNSF//200021_169033/CH/Fundamental studies of boron hydrogen compounds from BH4- to B12H122- and derived compounds and luminescence studies on energy transfer in rare earth containing phosphors/
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2013-46275-P/ES/SENSORES Y MEMORIAS BASADOS EN MATERIALES BIESTABLES CON TRANSICION DE ESPIN/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO2016%2F147/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2016-78341-P/ES/MATERIALES SPIN CROSSOVER BIESTABLES: DE LAS PROPIEDADES MACROSCOPICAS A LA ESPINTRONICA MOLECULAR/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MDM-2015-0538/ES/INSTITUTO DE CIENCIA MOLECULAR/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Delgado, T.; Meneses-Sánchez, M.; Piñeiro-López, L.; Bartual-Murgui, C.; Muñoz Roca, MDC.; Real, J. (2018). Thermo- and photo-modulation of exciplex fluorescence in a 3D spin crossover Hofmann-type coordination polymer. Chemical Science. 9(44):8446-8452. https://doi.org/10.1039/c8sc02677g es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8sc02677g es_ES
dc.description.upvformatpinicio 8446 es_ES
dc.description.upvformatpfin 8452 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 44 es_ES
dc.identifier.pmid 30542594 es_ES
dc.identifier.pmcid PMC6247521 es_ES
dc.relation.pasarela S\373561 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Swiss National Science Foundation es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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