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Engineering active sites on reduced graphene oxide by hydrogen plasma irradiation: mimicking bifunctional metal/supported catalysts in hydrogenation reactions

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Engineering active sites on reduced graphene oxide by hydrogen plasma irradiation: mimicking bifunctional metal/supported catalysts in hydrogenation reactions

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dc.contributor.author Primo Arnau, Ana Maria es_ES
dc.contributor.author Franconetti, Antonio es_ES
dc.contributor.author Magureanu, Monica es_ES
dc.contributor.author Mandache, Nicolae Bogdan es_ES
dc.contributor.author Bucur, Cristina es_ES
dc.contributor.author Rizescu, Cristina es_ES
dc.contributor.author Cojocaru, Bogdan es_ES
dc.contributor.author Parvulescu, Vasile I. es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2020-07-09T03:32:04Z
dc.date.available 2020-07-09T03:32:04Z
dc.date.issued 2018-06-07 es_ES
dc.identifier.issn 1463-9262 es_ES
dc.identifier.uri http://hdl.handle.net/10251/147683
dc.description.abstract [EN] H2 plasma has been used to generate carbon vacancies on reduced graphene oxide to increase its catalytic activity as a hydrogenation catalyst. A relationship between the power of the plasma treatment and the exposure time with the activity of the material was observed for CvC double bond hydrogenation. The activity data in the case of 1-octene, showing skeletal isomerization besides hydrogenation, indicate that H2 plasma treatment can introduce hydrogenating and acid sites rendering a bifunctional catalyst that is reminiscent of the activity of noble metals supported on acid supports. es_ES
dc.description.sponsorship Financial support from the Spanish Ministry of Economy and Competitiveness (Severo Ochoa, CTQ2015-69563-CO2-R1 and Grapas) is gratefully acknowledged. AP thanks the Ministry for a Ramon y Cajal research associate contract. AFG thanks the Center of Supercomputing of Galicia (CESGA) for the computational facilities. MM acknowledges financial support from the PN 16 47 01 04 project. VIP kindly acknowledges UEFISCDI for financial support (project PN-III-P4-ID-PCE-2016-0146, No. 121/2017). es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation MINECO/CTQ2015-69563-CO2-R1 es_ES
dc.relation.ispartof Green Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Graphitic carbon nitride es_ES
dc.subject Oxygen reduction es_ES
dc.subject Skeletal isomerization es_ES
dc.subject Mechanisms es_ES
dc.subject Defects es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Engineering active sites on reduced graphene oxide by hydrogen plasma irradiation: mimicking bifunctional metal/supported catalysts in hydrogenation reactions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c7gc03397d es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UEFISCDI//PN-III-P4-ID-PCE-2016-0146 121%2F2017/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UEFISCDI//PN 16 47 01 04/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Primo Arnau, AM.; Franconetti, A.; Magureanu, M.; Mandache, NB.; Bucur, C.; Rizescu, C.; Cojocaru, B.... (2018). Engineering active sites on reduced graphene oxide by hydrogen plasma irradiation: mimicking bifunctional metal/supported catalysts in hydrogenation reactions. Green Chemistry. 20(11):2611-2623. https://doi.org/10.1039/c7gc03397d es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c7gc03397d es_ES
dc.description.upvformatpinicio 2611 es_ES
dc.description.upvformatpfin 2623 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 20 es_ES
dc.description.issue 11 es_ES
dc.relation.pasarela S\382635 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Executive Agency for Higher Education, Scientific Research, Development and Innovation Funding, Rumanía es_ES
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