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Heterogeneous catalysis based on supramolecular association

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dc.contributor.author Parvulescu, Vasile I. es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2020-07-09T03:32:07Z
dc.date.available 2020-07-09T03:32:07Z
dc.date.issued 2018 es_ES
dc.identifier.issn 2044-4753 es_ES
dc.identifier.uri http://hdl.handle.net/10251/147684
dc.description.abstract [EN] Heterogeneous catalysis is based mostly on materials built with strong covalent bonds. However, supramolecular aggregation in which individual components self-assemble due to non-covalent interactions to create a larger entity offers also considerable potential for the preparation of materials with application in catalysis. The present article provides a perspective on the use of supramolecular aggregation for the development of heterogeneous catalysts. One of the main advantages of this approach is that the preparation procedure based on spontaneous self-assembly is frequently simpler than those that require the formation of covalent bonds. The emphasis in this article has been placed on the use in the preparation of heterogeneous catalysts of not only carbon materials, particularly graphene and carbon nanotubes, but also dendrimers and organic capsules. Examples of hybrid organic-inorganic materials such as mesoporous organosilicas, metal-organic frameworks and heteropolyacids are also briefly described. The purpose is to illustrate the breadth of the field and the diverse array of possibilities already developed to apply the concepts of supramolecular association in heterogeneous catalysis. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2015-69153-CO2-R1) and Generalitat Valenciana (Prometeo 2017-083) is gratefully acknowledged. Prof Parvulescu thanks UEFISCDI for the Projects 121/2017 and 32PCCD1/2018. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science & Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Metal-Organic frameworks es_ES
dc.subject Walled carbon nanotubes es_ES
dc.subject Pi-Pi interactions es_ES
dc.subject Ionic-Liquid es_ES
dc.subject Noncovalent functionalization es_ES
dc.subject Hydrogen evolution es_ES
dc.subject Nanoparticles es_ES
dc.subject Graphene es_ES
dc.subject Surface es_ES
dc.subject Efficient es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Heterogeneous catalysis based on supramolecular association es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8cy01295d es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UEFISCDI//PN-III-P4-ID-PCE-2016-0146 121%2F2017/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-1-R/ES/EXPLOTANDO EL USO DEL GRAFENO EN CATALISIS. USO DEL GRAFENO COMO CARBOCATALIZADOR O COMO SOPORTE/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UEFISCDI//32PCCD1%2F2018/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Parvulescu, VI.; García Gómez, H. (2018). Heterogeneous catalysis based on supramolecular association. Catalysis Science & Technology. 8(19):4834-4857. https://doi.org/10.1039/c8cy01295d es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8cy01295d es_ES
dc.description.upvformatpinicio 4834 es_ES
dc.description.upvformatpfin 4857 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 19 es_ES
dc.relation.pasarela S\382648 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Executive Agency for Higher Education, Scientific Research, Development and Innovation Funding, Rumanía es_ES
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