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Estimating CO2/N2 Permselectivity through Si/Al = 5 Small-Pore Zeolites/PTMSP Mixed Matrix Membranes: Influence of Temperature and Topology

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Estimating CO2/N2 Permselectivity through Si/Al = 5 Small-Pore Zeolites/PTMSP Mixed Matrix Membranes: Influence of Temperature and Topology

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dc.contributor.author Casado, Clara es_ES
dc.contributor.author Fernández-Barquín, Ana es_ES
dc.contributor.author Valencia Valencia, Susana es_ES
dc.contributor.author Irabien, Ángel es_ES
dc.date.accessioned 2020-07-09T03:32:23Z
dc.date.available 2020-07-09T03:32:23Z
dc.date.issued 2018-06 es_ES
dc.identifier.uri http://hdl.handle.net/10251/147690
dc.description.abstract [EN] In the present work, the effect of zeolite type and topology on CO2 and N-2 permeability using zeolites of different topology (CHA, RHO, and LTA) in the same Si/Al = 5, embedded in poly(trimethylsilyl-1-propyne) (PTMSP) is evaluated with temperature. Several models are compared on the prediction of CO2/N-2 separation performance and then the modified Maxwell models are selected. The CO2 and N-2 permeabilities through these membranes are predicted with an average absolute relative error (AARE) lower than 0.6% taking into account the temperature and zeolite loading and topology on non-idealities such as membrane rigidification, zeolite-polymer compatibility and sieve pore blockage. The evolution of this structure-performance relationship with temperature has also been predicted. es_ES
dc.description.sponsorship This research was funded by Spanish MINECO-General Secretariat for Research, Development and Innovation under project CTQ2016-76231-C2-1-R at the University of Cantabria, and MAT2015-71842-P, at the Instituto de Tecnologia Quimica. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Membranes es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Mixed matrix membranes es_ES
dc.subject Poly(trimethylsilyl-1-propyne) (PTMSP) es_ES
dc.subject Small-pore zeolites (CHA, RHO, LTA) es_ES
dc.subject Temperature es_ES
dc.subject Modeling es_ES
dc.title Estimating CO2/N2 Permselectivity through Si/Al = 5 Small-Pore Zeolites/PTMSP Mixed Matrix Membranes: Influence of Temperature and Topology es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/membranes8020032 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2016-76231-C2-1-R/ES/DISEÑO MULTIESCALA DE PROCESOS DE CAPTURA Y UTILIZACION DE DIOXIDO DE CARBONO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-71842-P/ES/SINTESIS Y CARACTERIZACION AVANZADA DE NUEVOS MATERIALES ZEOLITICOS Y APLICACIONES EN ADSORCION, MEDIOAMBIENTE Y EN LA CONSERVACION DE ALIMENTOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Casado, C.; Fernández-Barquín, A.; Valencia Valencia, S.; Irabien, Á. (2018). Estimating CO2/N2 Permselectivity through Si/Al = 5 Small-Pore Zeolites/PTMSP Mixed Matrix Membranes: Influence of Temperature and Topology. Membranes. 8(2). https://doi.org/10.3390/membranes8020032 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/membranes8020032 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 2 es_ES
dc.identifier.eissn 2077-0375 es_ES
dc.identifier.pmid 29914166 es_ES
dc.identifier.pmcid PMC6027413 es_ES
dc.relation.pasarela S\385913 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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