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Ketone Formation from Carboxylic Acids by Ketonic Decarboxylation: The Exceptional Case of the Tertiary Carboxylic Acids

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Ketone Formation from Carboxylic Acids by Ketonic Decarboxylation: The Exceptional Case of the Tertiary Carboxylic Acids

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Oliver-Tomás, B.; Renz, M.; Corma Canós, A. (2017). Ketone Formation from Carboxylic Acids by Ketonic Decarboxylation: The Exceptional Case of the Tertiary Carboxylic Acids. Chemistry - A European Journal. 23(52):12900-12908. https://doi.org/10.1002/chem.201702680

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/148183

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Title: Ketone Formation from Carboxylic Acids by Ketonic Decarboxylation: The Exceptional Case of the Tertiary Carboxylic Acids
Author: Oliver-Tomás, Borja Renz, Michael Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] For the reaction mechanism of the ketonic decarboxylation of two carboxylic acids, a -keto acid is favored as key intermediate in many experimental and theoretical studies. Hydrogen atoms in the -position are an ...[+]
Subjects: Biomass , Cyclization , Green chemistry , Surface chemistry , Lactones , Reaction mechanisms
Copyrigths: Reserva de todos los derechos
Source:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.201702680
Publisher:
John Wiley & Sons
Publisher version: https://doi.org/10.1002/chem.201702680
Description: "This is the peer reviewed version of the following article: Oliver-Tomas, Borja, Michael Renz, and Avelino Corma. 2017. Ketone Formation from Carboxylic Acids by Ketonic Decarboxylation: The Exceptional Case of the Tertiary Carboxylic Acids. Chemistry - A European Journal 23 (52). Wiley: 12900 908. doi:10.1002/chem.201702680, which has been published in final form at https://doi.org/10.1002/chem.201702680. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."
Thanks:
The authors thank MINECO (CTQ2015-67591-P and Severo Ochoa program, SEV-2016-0683) and Generalitat Valenciana (PROMETEO II/2013/011 Project) for funding this work. B.O.-T. is grateful to the CSIC (JAE program) for his PhD ...[+]
Type: Artículo

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