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Compatibilization of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)-poly(lactic acid) blends with diisocyanates

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Compatibilization of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)-poly(lactic acid) blends with diisocyanates

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dc.contributor.author González-Ausejo, J. es_ES
dc.contributor.author Sánchez-Safont, E. es_ES
dc.contributor.author Lagarón, J.M. es_ES
dc.contributor.author Balart, Rafael es_ES
dc.contributor.author Cabedo, Luis es_ES
dc.contributor.author Gámez-Pérez, J. es_ES
dc.date.accessioned 2020-07-30T03:34:28Z
dc.date.available 2020-07-30T03:34:28Z
dc.date.issued 2017-05-20 es_ES
dc.identifier.issn 0021-8995 es_ES
dc.identifier.uri http://hdl.handle.net/10251/148873
dc.description "This is the peer reviewed version of the following article: González-Ausejo, Jennifer, Estefania Sánchez-Safont, José Maria Lagarón, Rafael Balart, Luis Cabedo, and José Gámez-Pérez. 2017. Compatibilization of Poly(3-Hydroxybutyrate-Co-3-Hydroxyvalerate)-Poly(Lactic Acid) Blends with Diisocyanates. Journal of Applied Polymer Science 134 (20). Wiley. doi:10.1002/app.44806, which has been published in final form at https://doi.org/10.1002/app.44806. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving." es_ES
dc.description.abstract [EN] Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) was blended with poly(lactic acid) (PLA) with various reactive processing agents to decrease its brittleness and enhance its processability. Three diisocyanates, namely, hexamethylene diisocyanate, poly(hexamethylene diisocyanate), and 1,4-phenylene diisocyanate, were used as compatibilizing agents. The morphology, thermomechanical properties, and rheological behavior were investigated with scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, tensile testing, dynamomechanical thermal analysis in torsion mode (dynamic mechanical analysis), and oscillatory rheometry with a parallel-plate setup. The presence of the diisocyanates resulted in an enhanced polymer blend compatibility; this led to an improvement in the overall mechanical performance but did not affect the thermal stability of the system. A slight reduction in the PHBV crystallinity was observed with the incorporation of the diisocyanates. The addition of diisocyanates to the PHBV-PLA blend resulted in a notable increase in the final complex viscosity at low frequencies when compared with the same system without compatibilizers. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44806. es_ES
dc.description.sponsorship Financial support for this research from the Ministerio de Economia y Competitividad (project AGL2015-63855-C2-2-R), the Generalitat Valenciana (contract grant GV/2014/123), and the Pla de Promocio de la Investigacio de la Universitat Jaume I (contract grant numbers PREDOC/2012/32 and E-2015-22) is gratefully acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Journal of Applied Polymer Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Biodegradable es_ES
dc.subject Biopolymers and renewable polymers es_ES
dc.subject Blends es_ES
dc.subject Compatibilization es_ES
dc.subject Packaging es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Compatibilization of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)-poly(lactic acid) blends with diisocyanates es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/app.44806 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//AGL2015-63855-C2-2-R/ES/DESARROLLO Y CARACTERIZACION DE UN MULTICAPA BIODEGRADABLE DE ALTA BARRERA CON PROPIEDADES ACTIVAS Y BIOACTIVAS PARA ENVASADO ALIMENTARIO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UJI//PREDOC%2F2012%2F32/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//GV%2F2014%2F012/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UJI//E-2015-22/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation González-Ausejo, J.; Sánchez-Safont, E.; Lagarón, J.; Balart, R.; Cabedo, L.; Gámez-Pérez, J. (2017). Compatibilization of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)-poly(lactic acid) blends with diisocyanates. Journal of Applied Polymer Science. 134(20):1-11. https://doi.org/10.1002/app.44806 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/app.44806 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 11 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 134 es_ES
dc.description.issue 20 es_ES
dc.relation.pasarela S\346757 es_ES
dc.contributor.funder Universitat Jaume I es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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