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Formic acid oxidation on platinum electrodes: A detailed mechanism supported by experiments and calculations on well-defined surfaces

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Formic acid oxidation on platinum electrodes: A detailed mechanism supported by experiments and calculations on well-defined surfaces

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Ferre Vilaplana, A.; Perales, JV.; Buso-Rogero, C.; Feliu, J.; Herrero, E. (2017). Formic acid oxidation on platinum electrodes: A detailed mechanism supported by experiments and calculations on well-defined surfaces. Journal of Materials Chemistry A. 5(41):21773-21784. https://doi.org/10.1039/c7ta07116g

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Title: Formic acid oxidation on platinum electrodes: A detailed mechanism supported by experiments and calculations on well-defined surfaces
Author: Ferre Vilaplana, Adolfo Perales, Juan Víctor Buso-Rogero, Carlos Feliu, Juan Herrero, Enrique
UPV Unit: Universitat Politècnica de València. Departamento de Sistemas Informáticos y Computación - Departament de Sistemes Informàtics i Computació
Issued date:
Abstract:
[EN] In spite of the fact that the formic acid oxidation reaction on electrode surfaces has been extensively investigated, a detailed mechanism explaining all the available experimental evidence on platinum has not been ...[+]
Subjects: Single-Crystal electrodes , Irreversibly adsorbed adatoms , Modified stepped electrodes , Poison formation reaction , Noble-Metal electrodes , Electrocatalytic oxidation , Infrared-Spectroscopy , Pt(111) electrodes , Heterogeneous electrocatalysis , Adsorption behavior
Copyrigths: Reserva de todos los derechos
Source:
Journal of Materials Chemistry A. (issn: 2050-7488 )
DOI: 10.1039/c7ta07116g
Publisher:
The Royal Society of Chemistry
Publisher version: https://doi.org/10.1039/c7ta07116g
Project ID:
MICINN/CTQ2016-76221-P
GV/PROMETEOII/2014/013
Thanks:
This work has been financially supported by the MCINN-FEDER (Spain) and Generalitat Valenciana (Feder) through projects CTQ2016-76221-P and PROMETEOII/2014/013, respectively.
Type: Artículo

References

Bagotzky, V. S., Vassiliev, Y. B., & Khazova, O. A. (1977). Generalized scheme of chemisorption, electrooxidation and electroreduction of simple organic compounds on platinum group metals. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 81(2), 229-238. doi:10.1016/s0022-0728(77)80019-3

Beden, B., Bewick, A., & Lamy, C. (1983). A comparative study of formic acid adsorption on a platinum electrode by both electrochemical and emirs techniques. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 150(1-2), 505-511. doi:10.1016/s0022-0728(83)80230-7

Capon, A., & Parsons, R. (1973). The oxidation of formic acid at noble metal electrodes Part III. Intermediates and mechanism on platinum electrodes. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 45(2), 205-231. doi:10.1016/s0022-0728(73)80158-5 [+]
Bagotzky, V. S., Vassiliev, Y. B., & Khazova, O. A. (1977). Generalized scheme of chemisorption, electrooxidation and electroreduction of simple organic compounds on platinum group metals. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 81(2), 229-238. doi:10.1016/s0022-0728(77)80019-3

Beden, B., Bewick, A., & Lamy, C. (1983). A comparative study of formic acid adsorption on a platinum electrode by both electrochemical and emirs techniques. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 150(1-2), 505-511. doi:10.1016/s0022-0728(83)80230-7

Capon, A., & Parsons, R. (1973). The oxidation of formic acid at noble metal electrodes Part III. Intermediates and mechanism on platinum electrodes. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 45(2), 205-231. doi:10.1016/s0022-0728(73)80158-5

Capon, A., & Parson, R. (1973). The oxidation of formic acid at noble metal electrodes. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 44(1), 1-7. doi:10.1016/s0022-0728(73)80508-x

Wolter, O., Willsau, J., & Heitbaum, J. (1985). Reaction Pathways of the Anodic Oxidation of Formic Acid on Pt Evidenced by 18O Labeling—A DEMS Study. Journal of The Electrochemical Society, 132(7), 1635-1638. doi:10.1149/1.2114179

Willsau, J., & Heitbaum, J. (1986). Analysis of adsorbed intermediates and determination of surface potential shifts by dems. Electrochimica Acta, 31(8), 943-948. doi:10.1016/0013-4686(86)80008-1

Chen, Y. X., Miki, A., Ye, S., Sakai, H., & Osawa, M. (2003). Formate, an Active Intermediate for Direct Oxidation of Methanol on Pt Electrode. Journal of the American Chemical Society, 125(13), 3680-3681. doi:10.1021/ja029044t

Samjeské, G., & Osawa, M. (2005). Current Oscillations during Formic Acid Oxidation on a Pt Electrode: Insight into the Mechanism by Time-Resolved IR Spectroscopy. Angewandte Chemie International Edition, 44(35), 5694-5698. doi:10.1002/anie.200501009

Cuesta, A., Cabello, G., Gutiérrez, C., & Osawa, M. (2011). Adsorbed formate: the key intermediate in the oxidation of formic acid on platinum electrodes. Physical Chemistry Chemical Physics, 13(45), 20091. doi:10.1039/c1cp22498k

Cuesta, A., Cabello, G., Osawa, M., & Gutiérrez, C. (2012). Mechanism of the Electrocatalytic Oxidation of Formic Acid on Metals. ACS Catalysis, 2(5), 728-738. doi:10.1021/cs200661z

Chen, Y.-X., Heinen, M., Jusys, Z., & Behm, R. J. (2006). Bridge-Bonded Formate:  Active Intermediate or Spectator Species in Formic Acid Oxidation on a Pt Film Electrode?†. Langmuir, 22(25), 10399-10408. doi:10.1021/la060928q

Chen, Y. X., Heinen, M., Jusys, Z., & Behm, R. J. (2006). Kinetics and Mechanism of the Electrooxidation of Formic Acid—Spectroelectrochemical Studies in a Flow Cell. Angewandte Chemie International Edition, 45(6), 981-985. doi:10.1002/anie.200502172

Chen, Y.-X., Heinen, M., Jusys, Z., & Behm, R. J. (2007). Kinetic Isotope Effects in Complex Reaction Networks: Formic Acid Electro-Oxidation. ChemPhysChem, 8(3), 380-385. doi:10.1002/cphc.200600520

Joo, J., Uchida, T., Cuesta, A., Koper, M. T. M., & Osawa, M. (2013). Importance of Acid–Base Equilibrium in Electrocatalytic Oxidation of Formic Acid on Platinum. Journal of the American Chemical Society, 135(27), 9991-9994. doi:10.1021/ja403578s

Joo, J., Uchida, T., Cuesta, A., Koper, M. T. M., & Osawa, M. (2014). The effect of pH on the electrocatalytic oxidation of formic acid/formate on platinum: A mechanistic study by surface-enhanced infrared spectroscopy coupled with cyclic voltammetry. Electrochimica Acta, 129, 127-136. doi:10.1016/j.electacta.2014.02.040

Brimaud, S., Solla-Gullón, J., Weber, I., Feliu, J. M., & Behm, R. J. (2014). Formic Acid Electrooxidation on Noble-Metal Electrodes: Role and Mechanistic Implications of pH, Surface Structure, and Anion Adsorption. ChemElectroChem, 1(6), 1075-1083. doi:10.1002/celc.201400011

Perales-Rondón, J. V., Brimaud, S., Solla-Gullón, J., Herrero, E., Jürgen Behm, R., & Feliu, J. M. (2015). Further Insights into the Formic Acid Oxidation Mechanism on Platinum: pH and Anion Adsorption Effects. Electrochimica Acta, 180, 479-485. doi:10.1016/j.electacta.2015.08.155

Clavilier, J., Parsons, R., Durand, R., Lamy, C., & Leger, J. M. (1981). Formic acid oxidation on single crystal platinum electrodes. Comparison with polycrystalline platinum. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 124(1-2), 321-326. doi:10.1016/s0022-0728(81)80311-7

Adžić, R. R., Tripković, A. V., & O’Grady, W. E. (1982). Structural effects in electrocatalysis. Nature, 296(5853), 137-138. doi:10.1038/296137a0

Ferre-Vilaplana, A., Perales-Rondón, J. V., Feliu, J. M., & Herrero, E. (2014). Understanding the Effect of the Adatoms in the Formic Acid Oxidation Mechanism on Pt(111) Electrodes. ACS Catalysis, 5(2), 645-654. doi:10.1021/cs501729j

Perales-Rondón, J. V., Herrero, E., & Feliu, J. M. (2015). On the activation energy of the formic acid oxidation reaction on platinum electrodes. Journal of Electroanalytical Chemistry, 742, 90-96. doi:10.1016/j.jelechem.2015.02.003

Clavilier, J., Armand, D., Sun, S. G., & Petit, M. (1986). Electrochemical adsorption behaviour of platinum stepped surfaces in sulphuric acid solutions. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 205(1-2), 267-277. doi:10.1016/0022-0728(86)90237-8

C. Korzeniewski , V.Climent and J. M.Feliu, in Electroanalytical Chemistry: A Series of Advances, ed. A. J. Bard and C. Zoski, CRC Press, Boca Raton, 2012, vol. 24, pp. 75–169

N. Garcia-Araez , V.Climent and J.Feliu, in Mod Asp Electrochem, ed. C. G. Vayenas, Springer, New York, 2011, vol. 51, ch. 1, pp. 1–105

Grozovski, V., Climent, V., Herrero, E., & Feliu, J. M. (2009). Intrinsic Activity and Poisoning Rate for HCOOH Oxidation at Pt(100) and Vicinal Surfaces Containing Monoatomic (111) Steps. ChemPhysChem, 10(11), 1922-1926. doi:10.1002/cphc.200900261

Delley, B. (1990). An all‐electron numerical method for solving the local density functional for polyatomic molecules. The Journal of Chemical Physics, 92(1), 508-517. doi:10.1063/1.458452

Delley, B. (2002). Hardness conserving semilocal pseudopotentials. Physical Review B, 66(15). doi:10.1103/physrevb.66.155125

Hammer, B., Hansen, L. B., & Nørskov, J. K. (1999). Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals. Physical Review B, 59(11), 7413-7421. doi:10.1103/physrevb.59.7413

Delley, B. (2000). From molecules to solids with the DMol3 approach. The Journal of Chemical Physics, 113(18), 7756-7764. doi:10.1063/1.1316015

Delley, B. (2006). The conductor-like screening model for polymers and surfaces. Molecular Simulation, 32(2), 117-123. doi:10.1080/08927020600589684

Neugebauer, J., & Scheffler, M. (1992). Adsorbate-substrate and adsorbate-adsorbate interactions of Na and K adlayers on Al(111). Physical Review B, 46(24), 16067-16080. doi:10.1103/physrevb.46.16067

Henkelman, G., & Jónsson, H. (2000). Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle points. The Journal of Chemical Physics, 113(22), 9978-9985. doi:10.1063/1.1323224

Keith, J. A., & Jacob, T. (2010). Theoretical Studies of Potential-Dependent and Competing Mechanisms of the Electrocatalytic Oxygen Reduction Reaction on Pt(111). Angewandte Chemie International Edition, 49(49), 9521-9525. doi:10.1002/anie.201004794

Monkhorst, H. J., & Pack, J. D. (1976). Special points for Brillouin-zone integrations. Physical Review B, 13(12), 5188-5192. doi:10.1103/physrevb.13.5188

Grozovski, V., Vidal-Iglesias, F. J., Herrero, E., & Feliu, J. M. (2011). Adsorption of Formate and Its Role as Intermediate in Formic Acid Oxidation on Platinum Electrodes. ChemPhysChem, 12(9), 1641-1644. doi:10.1002/cphc.201100257

Rodes, A., Pastor, E., & Iwasita, T. (1994). An FTIR study on the adsorption of acetate at the basal planes of platinum single-crystal electrodes. Journal of Electroanalytical Chemistry, 376(1-2), 109-118. doi:10.1016/0022-0728(94)03585-7

Xu, J., Yuan, D., Yang, F., Mei, D., Zhang, Z., & Chen, Y.-X. (2013). On the mechanism of the direct pathway for formic acid oxidation at a Pt(111) electrode. Physical Chemistry Chemical Physics, 15(12), 4367. doi:10.1039/c3cp44074e

Perales-Rondón, J. V., Herrero, E., & Feliu, J. M. (2014). Effects of the anion adsorption and pH on the formic acid oxidation reaction on Pt(111) electrodes. Electrochimica Acta, 140, 511-517. doi:10.1016/j.electacta.2014.06.057

Herrero, E., Franaszczuk, K., & Wieckowski, A. (1994). Electrochemistry of Methanol at Low Index Crystal Planes of Platinum: An Integrated Voltammetric and Chronoamperometric Study. The Journal of Physical Chemistry, 98(19), 5074-5083. doi:10.1021/j100070a022

Wang, H.-F., & Liu, Z.-P. (2009). Formic Acid Oxidation at Pt/H2O Interface from Periodic DFT Calculations Integrated with a Continuum Solvation Model. The Journal of Physical Chemistry C, 113(40), 17502-17508. doi:10.1021/jp9059888

Schwarz, K. A., Sundararaman, R., Moffat, T. P., & Allison, T. C. (2015). Formic acid oxidation on platinum: a simple mechanistic study. Physical Chemistry Chemical Physics, 17(32), 20805-20813. doi:10.1039/c5cp03045e

Perales-Rondón, J. V., Ferre-Vilaplana, A., Feliu, J. M., & Herrero, E. (2014). Oxidation Mechanism of Formic Acid on the Bismuth Adatom-Modified Pt(111) Surface. Journal of the American Chemical Society, 136(38), 13110-13113. doi:10.1021/ja505943h

Clavilier, J. (1987). Pulsed linear sweep voltammetry with pulses of constant level in a potential scale, a polarization demanding condition in the study of platinum single crystal electrodes. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 236(1-2), 87-94. doi:10.1016/0022-0728(87)88020-8

Fernandez-Vega, A., Feliu, J. M., Aldaz, A., & Clavilier, J. (1991). Heterogeneous electrocatalysis on well-defined platinum surfaces modified by controlled amounts of irreversibly adsorbed adatoms. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 305(2), 229-240. doi:10.1016/0022-0728(91)85521-p

Grozovski, V., Climent, V., Herrero, E., & Feliu, J. M. (2010). Intrinsic activity and poisoning rate for HCOOH oxidation on platinum stepped surfaces. Physical Chemistry Chemical Physics, 12(31), 8822. doi:10.1039/b925472b

Grozovski, V., Solla-Gullón, J., Climent, V., Herrero, E., & Feliu, J. M. (2010). Formic Acid Oxidation on Shape-Controlled Pt Nanoparticles Studied by Pulsed Voltammetry. The Journal of Physical Chemistry C, 114(32), 13802-13812. doi:10.1021/jp104755b

Koper, M. T. M. (2013). Theory of multiple proton–electron transfer reactions and its implications for electrocatalysis. Chemical Science, 4(7), 2710. doi:10.1039/c3sc50205h

Koper, M. T. M. (2015). Volcano Activity Relationships for Proton-Coupled Electron Transfer Reactions in Electrocatalysis. Topics in Catalysis, 58(18-20), 1153-1158. doi:10.1007/s11244-015-0489-3

Neurock, M., Janik, M., & Wieckowski, A. (2009). A first principles comparison of the mechanism and site requirements for the electrocatalytic oxidation of methanol and formic acid over Pt. Faraday Discuss., 140, 363-378. doi:10.1039/b804591g

Gao, W., Keith, J. A., Anton, J., & Jacob, T. (2010). Theoretical Elucidation of the Competitive Electro-oxidation Mechanisms of Formic Acid on Pt(111). Journal of the American Chemical Society, 132(51), 18377-18385. doi:10.1021/ja1083317

Gamboa-Aldeco, M. E., Herrero, E., Zelenay, P. S., & Wieckowski, A. (1993). Adsorption of bisulfate anion on a Pt(100) electrode: A comparison with Pt(111) and Pt(poly). Journal of Electroanalytical Chemistry, 348(1-2), 451-457. doi:10.1016/0022-0728(93)80151-7

Clavilier, J., & Sun, S. G. (1986). Electrochemical study of the chemisorbed species formed from formic acid dissociation at platinum single crystal electrodes. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 199(2), 471-480. doi:10.1016/0022-0728(86)80021-3

Sun, S. G., Clavilier, J., & Bewick, A. (1988). The mechanism of electrocatalytic oxidation of formic acid on Pt (100) and Pt (111) in sulphuric acid solution: an emirs study. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 240(1-2), 147-159. doi:10.1016/0022-0728(88)80319-x

Herrero, E., Fernández-Vega, A., Feliu, J. M., & Aldaz, A. (1993). Poison formation reaction from formic acid and methanol on Pt(111) electrodes modified by irreversibly adsorbed Bi and As. Journal of Electroanalytical Chemistry, 350(1-2), 73-88. doi:10.1016/0022-0728(93)80197-p

Herrero, E., Feliu, J. M., & Aldaz, A. (1994). Poison formation reaction from formic acid on Pt(100) electrodes modified by irreversibly adsorbed bismuth and antimony. Journal of Electroanalytical Chemistry, 368(1-2), 101-108. doi:10.1016/0022-0728(93)03032-k

Iwasita, T., Xia, X., Herrero, E., & Liess, H.-D. (1996). Early Stages during the Oxidation of HCOOH on Single-Crystal Pt Electrodes As Characterized by Infrared Spectroscopy. Langmuir, 12(17), 4260-4265. doi:10.1021/la960264s

Corrigan, D. S., & Weaver, M. J. (1988). Mechanisms of formic acid, methanol, and carbon monoxide electrooxidation at platinum as examined by single potential alteration infrared spectroscopy. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 241(1-2), 143-162. doi:10.1016/0022-0728(88)85123-4

Chang, S. C., Leung, L. W. H., & Weaver, M. J. (1990). Metal crystallinity effects in electrocatalysis as probed by real-time FTIR spectroscopy: electrooxidation of formic acid, methanol, and ethanol on ordered low-index platinum surfaces. The Journal of Physical Chemistry, 94(15), 6013-6021. doi:10.1021/j100378a072

Clavilier, J., Fernandez-Vega, A., Feliu, J. M., & Aldaz, A. (1989). Heterogeneous electrocatalysis on well defined platinum surfaces modified by controlled amounts of irreversibly adsorbed adatoms. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 258(1), 89-100. doi:10.1016/0022-0728(89)85164-2

Herrero, E., Climent, V., & Feliu, J. M. (2000). On the different adsorption behavior of bismuth, sulfur, selenium and tellurium on a Pt(775) stepped surface. Electrochemistry Communications, 2(9), 636-640. doi:10.1016/s1388-2481(00)00093-x

Maciá, M. (1999). Formic acid self-poisoning on bismuth-modified Pt(755) and Pt(775) electrodes. Electrochemistry Communications, 1(2), 87-89. doi:10.1016/s1388-2481(99)00009-0

Maciá, M. D., Herrero, E., Feliu, J. M., & Aldaz, A. (2001). Formic acid self-poisoning on bismuth-modified stepped electrodes. Journal of Electroanalytical Chemistry, 500(1-2), 498-509. doi:10.1016/s0022-0728(00)00389-2

Maciá, M. ., Herrero, E., & Feliu, J. . (2002). Formic acid self-poisoning on adatom-modified stepped electrodes. Electrochimica Acta, 47(22-23), 3653-3661. doi:10.1016/s0013-4686(02)00335-3

Garcia-Araez, N., Climent, V., Herrero, E., Feliu, J. M., & Lipkowski, J. (2005). Determination of the Gibbs excess of H adsorbed at a Pt(111) electrode surface in the presence of co-adsorbed chloride. Journal of Electroanalytical Chemistry, 582(1-2), 76-84. doi:10.1016/j.jelechem.2005.01.031

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