- -

Isostructural compartmentalized spin-crossover coordination polymers for gas confinement

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Isostructural compartmentalized spin-crossover coordination polymers for gas confinement

Mostrar el registro sencillo del ítem

Ficheros en el ítem

Thumbnail
Nombre: Calvo;Giménez-Mar ...
Tamaño: 561.7Kb
Formato: PDF
Descripción: Versión del Autor.
Abrir
[Cerrado]
Nombre: Inorg. Chem. Front., ...
Tamaño: 2.076Mb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
dc.contributor.author Calvo Galve, Néstor es_ES
dc.contributor.author Giménez-Marqués, Mónica es_ES
dc.contributor.author Palomino Roca, Miguel es_ES
dc.contributor.author Valencia Valencia, Susana es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Mínguez Espallargas, Guillermo es_ES
dc.contributor.author Coronado, Eugenio es_ES
dc.date.accessioned 2020-09-15T03:32:45Z
dc.date.available 2020-09-15T03:32:45Z
dc.date.issued 2016 es_ES
dc.identifier.issn 2052-1545 es_ES
dc.identifier.uri http://hdl.handle.net/10251/150054
dc.description.abstract [EN] Here we present two FeII coordination polymers that possess discrete compartments suitable for CO2 physisorption despite the lack of permanent channels. The two crystalline materials, of general formula [Fe(btzbp)3](X)2 (X = ClO4 or BF4), present voids of ca. 250 Å3, which each can accommodate up to two CO2 molecules. The abrupt spin transition can be modified upon CO2 sorption, and different magnetic behaviour is observed depending on the number of molecules sorbed. es_ES
dc.description.sponsorship Financial support from the Spanish MINECO (CTQ2014-59209-P, MAT2014-56143-R and MAT2012-38567-C02-01), the Generalitat Valenciana (Prometeo and ISIC-Nano programs) and the VLC/Campus Program is gratefully acknowledged. We thank the Spanish government for the provision of a Severo Ochoa project (SEV-2012-0267) and a Maria de Maeztu project (MDM-2015-0538). G.M.E. acknowledges the Blaise Pascal International Chair for financial support. M.G.-M. thanks MICINN for a predoctoral FPU grant and the EU for a Marie Sklodowska-Curie postdoctoral fellowship (H2020-MSCA-IF-EF-658224). N.C.G. thanks the Generalitat Valenciana for a Val-i+d predoctoral fellowship. J. M. Martinez-Agudo and G. Agusti from the University of Valencia are gratefully acknowledged for magnetic measurements. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Inorganic Chemistry Frontiers es_ES
dc.rights Reserva de todos los derechos es_ES
dc.title Isostructural compartmentalized spin-crossover coordination polymers for gas confinement es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/C5QI00277J es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/658224/EU/Rational design of novel heterometallic MOFs for their use in heterogeneous catalysis for cascade reactions/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2014-59209-P/ES/OLIMEROS DE COORDINACION MAGNETICOS SENSIBLES A ESTIMULOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2012-38567-C02-01/ES/MATERIALES ZEOLITICOS COMO ESTRUCTURAS ANFITRIONAS DE NANOPARTICULAS. SINTESIS Y APLICACIONES NANOTECNOLOGICAS, CATALITICAS Y MEDIOAMBIENTALES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MDM-2015-0538/ES/INSTITUTO DE CIENCIA MOLECULAR/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2014-56143-R/ES/INGENIERIA MOLECULAR EN MATERIALES 2D Y EN DISPOSITIVOS ESPINTRONICOS HIBRIDOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Calvo Galve, N.; Giménez-Marqués, M.; Palomino Roca, M.; Valencia Valencia, S.; Rey Garcia, F.; Mínguez Espallargas, G.; Coronado, E. (2016). Isostructural compartmentalized spin-crossover coordination polymers for gas confinement. Inorganic Chemistry Frontiers. 3(6):808-813. https://doi.org/10.1039/C5QI00277J es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/C5QI00277J es_ES
dc.description.upvformatpinicio 808 es_ES
dc.description.upvformatpfin 813 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 3 es_ES
dc.description.issue 6 es_ES
dc.relation.pasarela S\313863 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Université Blaise Pascal es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.description.references Hoskins, B. F., & Robson, R. (1989). Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. Journal of the American Chemical Society, 111(15), 5962-5964. doi:10.1021/ja00197a079 es_ES
dc.description.references Hoskins, B. F., & Robson, R. (1990). Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4’,4’’,4’’’-tetracyanotetraphenylmethane]BF4.xC6H5NO2. Journal of the American Chemical Society, 112(4), 1546-1554. doi:10.1021/ja00160a038 es_ES
dc.description.references Coronado, E., Giménez-Marqués, M., Espallargas, G. M., & Brammer, L. (2012). Tuning the magneto-structural properties of non-porous coordination polymers by HCl chemisorption. Nature Communications, 3(1). doi:10.1038/ncomms1827 es_ES
dc.description.references Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013). The Chemistry and Applications of Metal-Organic Frameworks. Science, 341(6149), 1230444-1230444. doi:10.1126/science.1230444 es_ES
dc.description.references Slater, A. G., & Cooper, A. I. (2015). Function-led design of new porous materials. Science, 348(6238), aaa8075-aaa8075. doi:10.1126/science.aaa8075 es_ES
dc.description.references Hu, Z., Deibert, B. J., & Li, J. (2014). Luminescent metal–organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev., 43(16), 5815-5840. doi:10.1039/c4cs00010b es_ES
dc.description.references Coronado, E., & Mínguez Espallargas, G. (2013). Dynamic magnetic MOFs. Chem. Soc. Rev., 42(4), 1525-1539. doi:10.1039/c2cs35278h es_ES
dc.description.references Li, J.-R., Kuppler, R. J., & Zhou, H.-C. (2009). Selective gas adsorption and separation in metal–organic frameworks. Chemical Society Reviews, 38(5), 1477. doi:10.1039/b802426j es_ES
dc.description.references Murray, L. J., Dincă, M., & Long, J. R. (2009). Hydrogen storage in metal–organic frameworks. Chemical Society Reviews, 38(5), 1294. doi:10.1039/b802256a es_ES
dc.description.references Giménez-Marqués, M., Hidalgo, T., Serre, C., & Horcajada, P. (2016). Nanostructured metal–organic frameworks and their bio-related applications. Coordination Chemistry Reviews, 307, 342-360. doi:10.1016/j.ccr.2015.08.008 es_ES
dc.description.references Smulders, M. M. J., Riddell, I. A., Browne, C., & Nitschke, J. R. (2013). Building on architectural principles for three-dimensional metallosupramolecular construction. Chem. Soc. Rev., 42(4), 1728-1754. doi:10.1039/c2cs35254k es_ES
dc.description.references Cook, T. R., & Stang, P. J. (2015). Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination. Chemical Reviews, 115(15), 7001-7045. doi:10.1021/cr5005666 es_ES
dc.description.references Inokuma, Y., Yoshioka, S., Ariyoshi, J., Arai, T., Hitora, Y., Takada, K., … Fujita, M. (2013). X-ray analysis on the nanogram to microgram scale using porous complexes. Nature, 495(7442), 461-466. doi:10.1038/nature11990 es_ES
dc.description.references Yoshioka, S., Inokuma, Y., Hoshino, M., Sato, T., & Fujita, M. (2015). Absolute structure determination of compounds with axial and planar chirality using the crystalline sponge method. Chemical Science, 6(7), 3765-3768. doi:10.1039/c5sc01681a es_ES
dc.description.references Coronado, E., Giménez-Marqués, M., Mínguez Espallargas, G., Rey, F., & Vitórica-Yrezábal, I. J. (2013). Spin-Crossover Modification through Selective CO2 Sorption. Journal of the American Chemical Society, 135(43), 15986-15989. doi:10.1021/ja407135k es_ES
dc.description.references M. Giménez-Marqués , N.Calvo Galve, M.Palomino, S.Valencia, F.Rey, G.Sastre, I. J.Vitórica-Yrezábal, M.Jiménez-Ruiz, J. A.Rodríguez-Velamazán, M. A.González, E.Coronado and G.Mínguez Espallargas es_ES
dc.description.references Sheldrick, G. M. (2007). A short history ofSHELX. Acta Crystallographica Section A Foundations of Crystallography, 64(1), 112-122. doi:10.1107/s0108767307043930 es_ES
dc.description.references Pawley, G. S. (1981). Unit-cell refinement from powder diffraction scans. Journal of Applied Crystallography, 14(6), 357-361. doi:10.1107/s0021889881009618 es_ES
dc.description.references Klinowski, J., Almeida Paz, F. A., Silva, P., & Rocha, J. (2011). Microwave-Assisted Synthesis of Metal–Organic Frameworks. Dalton Trans., 40(2), 321-330. doi:10.1039/c0dt00708k es_ES
dc.description.references Aromí, G., Barrios, L. A., Roubeau, O., & Gamez, P. (2011). Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials. Coordination Chemistry Reviews, 255(5-6), 485-546. doi:10.1016/j.ccr.2010.10.038 es_ES
dc.description.references Palomino, M., Corma, A., Rey, F., & Valencia, S. (2010). New Insights on CO2−Methane Separation Using LTA Zeolites with Different Si/Al Ratios and a First Comparison with MOFs. Langmuir, 26(3), 1910-1917. doi:10.1021/la9026656 es_ES
dc.description.references Morris, R. E., & Wheatley, P. S. (2008). Gas Storage in Nanoporous Materials. Angewandte Chemie International Edition, 47(27), 4966-4981. doi:10.1002/anie.200703934 es_ES
dc.description.references Mason, J. A., McDonald, T. M., Bae, T.-H., Bachman, J. E., Sumida, K., Dutton, J. J., … Long, J. R. (2015). Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO2, N2, and H2O. Journal of the American Chemical Society, 137(14), 4787-4803. doi:10.1021/jacs.5b00838 es_ES
dc.description.references Yazaydın, A. O., Snurr, R. Q., Park, T.-H., Koh, K., Liu, J., LeVan, M. D., … Willis, R. R. (2009). Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach. Journal of the American Chemical Society, 131(51), 18198-18199. doi:10.1021/ja9057234 es_ES
dc.description.references Caskey, S. R., Wong-Foy, A. G., & Matzger, A. J. (2008). Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores. Journal of the American Chemical Society, 130(33), 10870-10871. doi:10.1021/ja8036096 es_ES
dc.description.references Calvo Galve, N., Coronado, E., Giménez-Marqués, M., & Mínguez Espallargas, G. (2014). A Mixed-Ligand Approach for Spin-Crossover Modulation in a Linear FeII Coordination Polymer. Inorganic Chemistry, 53(9), 4482-4490. doi:10.1021/ic500141v es_ES
dc.description.references Xiang, Z., & Cao, D. (2013). Porous covalent–organic materials: synthesis, clean energy application and design. J. Mater. Chem. A, 1(8), 2691-2718. doi:10.1039/c2ta00063f es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem