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Enantioselective alkynylation of benzo[e][1,2,3]-oxathiazine 2,2-dioxides catalysed by (R)-VAPOL-Zn complexes: synthesis of chiral propargylic cyclic sulfamidates

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Enantioselective alkynylation of benzo[e][1,2,3]-oxathiazine 2,2-dioxides catalysed by (R)-VAPOL-Zn complexes: synthesis of chiral propargylic cyclic sulfamidates

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De Munck, L.; Monleón, A.; Vila, C.; Muñoz Roca, MDC.; Pedro, JR. (2015). Enantioselective alkynylation of benzo[e][1,2,3]-oxathiazine 2,2-dioxides catalysed by (R)-VAPOL-Zn complexes: synthesis of chiral propargylic cyclic sulfamidates. Organic & Biomolecular Chemistry. 13(27):7393-7396. https://doi.org/10.1039/c5ob01012h

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Title: Enantioselective alkynylation of benzo[e][1,2,3]-oxathiazine 2,2-dioxides catalysed by (R)-VAPOL-Zn complexes: synthesis of chiral propargylic cyclic sulfamidates
Author: De Munck, Lode Monleón, A. Vila, C. Muñoz Roca, María Del Carmen Pedro, J. R.
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
[EN] (R)-VAPOL-Zn(II) complexes catalysed the enantioselective addition of terminal alkynes to cyclic benzoxathiazine 2,2-dioxides, providing the corresponding chiral propargylic sulfamidates with high yields (up to 93%) ...[+]
Copyrigths: Cerrado
Source:
Organic & Biomolecular Chemistry. (issn: 1477-0520 )
DOI: 10.1039/c5ob01012h
Publisher:
The Royal Society of Chemistry
Publisher version: https://doi.org/10.1039/c5ob01012h
Project ID:
info:eu-repo/grantAgreement/GVA//ISIC2012%2F001/
info:eu-repo/grantAgreement/MINECO//CTQ2013-47494-P/ES/NUEVOS RETOS EN EL DESARROLLO DE PROCESOS ENANTIOSELECTIVOS DE FORMACION DE ENLACES C-C MEDIANTE CATALISIS DUAL COOPERATIVA./
Thanks:
Financial support from the MINECO (Gobierno de Espana; CTQ2013-47494-P) and from Generalitat Valenciana (ISIC2012/001) is gratefully acknowledged. L. M. and A. M. thank the Generalitat Valenciana for predoctoral grants. ...[+]
Type: Artículo

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