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A Heterogeneous Carbon Nitride Nickel Photocatalyst for Efficient Low-Temperature CO2 Methanation

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A Heterogeneous Carbon Nitride Nickel Photocatalyst for Efficient Low-Temperature CO2 Methanation

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Nombre: Barrio;Mateo-Mate ...
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dc.contributor.author Barrio, Jesus es_ES
dc.contributor.author Mateo-Mateo, Diego es_ES
dc.contributor.author Albero-Sancho, Josep es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Shalom, Menny es_ES
dc.date.accessioned 2020-10-27T04:31:59Z
dc.date.available 2020-10-27T04:31:59Z
dc.date.issued 2019-11-27 es_ES
dc.identifier.uri http://hdl.handle.net/10251/153223
dc.description.abstract [EN] The Sabatier reaction, i.e., the hydrogenation of CO2 to methane (CH4) using hydrogen (H-2), constitutes a potentially scalable method to store energy in a product with a high energy density. However, up to today, this reaction has been mainly thermally driven and conducted at high temperatures (typically 400-600 degrees C). Using light as a renewable energy source will allow for a more sustainable process by lowering the reaction temperature. Here, it is demonstrated that Ni nanoparticles support on graphitic carbon nitride (g-CN) are a highly efficient and stable photocatalyst for the gas-phase CO2 methanation at low temperature (150 degrees C). Detailed mechanistic studies reveal a very low activation energy for the reaction and high activity under visible light, leading to a remarkable and continuous CH4 production of 28 mu mol g(-1) h(-1) of CH4 for 24 h. es_ES
dc.description.sponsorship J.B. and D.M. contributed equally to this work. The authors would like to thank the technical staff of the Instituto de Tecnología Química for assistance with the experimental characterization. This research was funded by the Israel Science Foundation (ISF), grant No. 1161/17, and supported by the Minerva Center No. 117873. Financial support from the Spanish Ministry of Economy and Competitiveness (Severo Ochoa, and CTQ2015-69563-CO2-R1) and the Generalitat Valenciana (Prometeo 2017/083) is also gratefully acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation MINECO/CTQ2015-69563-CO2-R1 es_ES
dc.relation.ispartof Advanced energy materials (Online) es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Carbon nitride es_ES
dc.subject CO2 reduction es_ES
dc.subject Ni nanoparticles es_ES
dc.subject Photocatalysis es_ES
dc.subject Sabatier reaction es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title A Heterogeneous Carbon Nitride Nickel Photocatalyst for Efficient Low-Temperature CO2 Methanation es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/aenm.201902738 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ISF//1161%2F17/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Minerva Foundation//117873/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Barrio, J.; Mateo-Mateo, D.; Albero-Sancho, J.; García Gómez, H.; Shalom, M. (2019). A Heterogeneous Carbon Nitride Nickel Photocatalyst for Efficient Low-Temperature CO2 Methanation. Advanced energy materials (Online). 9(44):1-7. https://doi.org/10.1002/aenm.201902738 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/aenm.201902738 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 7 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 44 es_ES
dc.identifier.eissn 1614-6840 es_ES
dc.relation.pasarela S\407314 es_ES
dc.contributor.funder Minerva Foundation es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Israel Science Foundation es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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