Mostrar el registro sencillo del ítem
dc.contributor.author | Jouve, Andrea | es_ES |
dc.contributor.author | Cattaneo, Stefano | es_ES |
dc.contributor.author | Delgado-Muñoz, Daniel | es_ES |
dc.contributor.author | Scotti, Nicola | es_ES |
dc.contributor.author | Evangelisti, Claudio | es_ES |
dc.contributor.author | López Nieto, José Manuel | es_ES |
dc.contributor.author | Prati, Laura | es_ES |
dc.date.accessioned | 2020-11-04T04:32:02Z | |
dc.date.available | 2020-11-04T04:32:02Z | |
dc.date.issued | 2019-06-01 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/154024 | |
dc.description.abstract | [EN] In this study, niobia-based materials have been used as supports for Pt nanoparticles and used in the hydrogenation of furfural. The incorporation of dopants (W6+ and Ti4+) in the Nb2O5 structure induced modifications in the surface acidity of the support; in particular, the addition of W6+ increased the amount of Lewis acid sites, while the addition of Ti4+ decreased the number of Lewis acid sites. As a result, the catalytic activity towards the hydrogenation of furfural was affected; high surface acidity resulted in high catalytic activity. The selectivity of the reaction changed with the support acidity as well, with higher amount of furfuryl alcohol produced decreasing the Lewis acid sites. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | MDPI AG | es_ES |
dc.relation.ispartof | Applied Sciences | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Platinum | es_ES |
dc.subject | Niobia | es_ES |
dc.subject | Niobium oxide | es_ES |
dc.subject | Furfural | es_ES |
dc.subject | Hydrogenation | es_ES |
dc.subject | Furfuryl alcohol | es_ES |
dc.subject | Pentanediol | es_ES |
dc.subject | Lewis acid | es_ES |
dc.title | Furfural Hydrogenation on Modified Niobia | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.3390/app9112287 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099668-B-C21/ES/VALORIZACION DE CO2: CAPTURA, Y TRANSFORMACION CATALITICA PARA ALMACENAMIENTO DE ENERGIA, COMBUSTIBLES Y PRODUCTOS QUIMICOS/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Jouve, A.; Cattaneo, S.; Delgado-Muñoz, D.; Scotti, N.; Evangelisti, C.; López Nieto, JM.; Prati, L. (2019). Furfural Hydrogenation on Modified Niobia. Applied Sciences. 9(11):1-14. https://doi.org/10.3390/app9112287 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.3390/app9112287 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 14 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 9 | es_ES |
dc.description.issue | 11 | es_ES |
dc.identifier.eissn | 2076-3417 | es_ES |
dc.relation.pasarela | S\405411 | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.description.references | Binder, J. B., & Raines, R. T. (2009). Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals. Journal of the American Chemical Society, 131(5), 1979-1985. doi:10.1021/ja808537j | es_ES |
dc.description.references | Cao, Q., Guo, X., Guan, J., Mu, X., & Zhang, D. (2011). A process for efficient conversion of fructose into 5-hydroxymethylfurfural in ammonium salts. Applied Catalysis A: General, 403(1-2), 98-103. doi:10.1016/j.apcata.2011.06.018 | es_ES |
dc.description.references | Cattaneo, S., Naslhajian, H., Somodi, F., Evangelisti, C., Villa, A., & Prati, L. (2018). Ruthenium on Carbonaceous Materials for the Selective Hydrogenation of HMF. Molecules, 23(8), 2007. doi:10.3390/molecules23082007 | es_ES |
dc.description.references | Qi, X., Watanabe, M., Aida, T. M., & Smith, R. L. (2012). Synergistic conversion of glucose into 5-hydroxymethylfurfural in ionic liquid–water mixtures. Bioresource Technology, 109, 224-228. doi:10.1016/j.biortech.2012.01.034 | es_ES |
dc.description.references | Ormsby, R., Kastner, J. R., & Miller, J. (2012). Hemicellulose hydrolysis using solid acid catalysts generated from biochar. Catalysis Today, 190(1), 89-97. doi:10.1016/j.cattod.2012.02.050 | es_ES |
dc.description.references | Lavarack, B. P., Griffin, G. J., & Rodman, D. (2002). The acid hydrolysis of sugarcane bagasse hemicellulose to produce xylose, arabinose, glucose and other products. Biomass and Bioenergy, 23(5), 367-380. doi:10.1016/s0961-9534(02)00066-1 | es_ES |
dc.description.references | Carà, P. D., Pagliaro, M., Elmekawy, A., Brown, D. R., Verschuren, P., Shiju, N. R., & Rothenberg, G. (2013). Hemicellulose hydrolysis catalysed by solid acids. Catalysis Science & Technology, 3(8), 2057. doi:10.1039/c3cy20838a | es_ES |
dc.description.references | O’Neill, R., Ahmad, M. N., Vanoye, L., & Aiouache, F. (2009). Kinetics of Aqueous Phase Dehydration of Xylose into Furfural Catalyzed by ZSM-5 Zeolite. Industrial & Engineering Chemistry Research, 48(9), 4300-4306. doi:10.1021/ie801599k | es_ES |
dc.description.references | Weingarten, R., Cho, J., Conner, Jr., W. C., & Huber, G. W. (2010). Kinetics of furfural production by dehydration of xylose in a biphasic reactor with microwave heating. Green Chemistry, 12(8), 1423. doi:10.1039/c003459b | es_ES |
dc.description.references | Gómez Bernal, H., Bernazzani, L., & Raspolli Galletti, A. M. (2014). Furfural from corn stover hemicelluloses. A mineral acid-free approach. Green Chem., 16(8), 3734-3740. doi:10.1039/c4gc00450g | es_ES |
dc.description.references | Delbecq, F., Wang, Y., Muralidhara, A., El Ouardi, K., Marlair, G., & Len, C. (2018). Hydrolysis of Hemicellulose and Derivatives—A Review of Recent Advances in the Production of Furfural. Frontiers in Chemistry, 6. doi:10.3389/fchem.2018.00146 | es_ES |
dc.description.references | Mariscal, R., Maireles-Torres, P., Ojeda, M., Sádaba, I., & López Granados, M. (2016). Furfural: a renewable and versatile platform molecule for the synthesis of chemicals and fuels. Energy & Environmental Science, 9(4), 1144-1189. doi:10.1039/c5ee02666k | es_ES |
dc.description.references | Yan, K., Wu, G., Lafleur, T., & Jarvis, C. (2014). Production, properties and catalytic hydrogenation of furfural to fuel additives and value-added chemicals. Renewable and Sustainable Energy Reviews, 38, 663-676. doi:10.1016/j.rser.2014.07.003 | es_ES |
dc.description.references | Bui, L., Luo, H., Gunther, W. R., & Román-Leshkov, Y. (2013). Domino Reaction Catalyzed by Zeolites with Brønsted and Lewis Acid Sites for the Production of γ-Valerolactone from Furfural. Angewandte Chemie International Edition, 52(31), 8022-8025. doi:10.1002/anie.201302575 | es_ES |
dc.description.references | Taylor, M. J., Durndell, L. J., Isaacs, M. A., Parlett, C. M. A., Wilson, K., Lee, A. F., & Kyriakou, G. (2016). Highly selective hydrogenation of furfural over supported Pt nanoparticles under mild conditions. Applied Catalysis B: Environmental, 180, 580-585. doi:10.1016/j.apcatb.2015.07.006 | es_ES |
dc.description.references | Schäfer, H., Gruehn, R., & Schulte, F. (1966). The Modifications of Niobium Pentoxide. Angewandte Chemie International Edition in English, 5(1), 40-52. doi:10.1002/anie.196600401 | es_ES |
dc.description.references | Allpress, J. G., Sanders, J. V., & Wadsley, A. D. (1968). Electron microscopy of high-temperature Nb2O5 and related phases. Physica Status Solidi (b), 25(2), 541-550. doi:10.1002/pssb.19680250206 | es_ES |
dc.description.references | Jehng, J.-M., & Wachs, I. E. (1990). The molecular structures and reactivity of supported niobium oxide catalysts. Catalysis Today, 8(1), 37-55. doi:10.1016/0920-5861(90)87006-o | es_ES |
dc.description.references | Jehng, J. M., & Wachs, I. E. (1991). Molecular structures of supported niobium oxide catalysts under in situ conditions. The Journal of Physical Chemistry, 95(19), 7373-7379. doi:10.1021/j100172a049 | es_ES |
dc.description.references | Carniti, P., Gervasini, A., & Marzo, M. (2010). Silica–niobia oxides as viable acid catalysts in water: Effective vs. intrinsic acidity. Catalysis Today, 152(1-4), 42-47. doi:10.1016/j.cattod.2009.07.111 | es_ES |
dc.description.references | Gupta, N. K., Fukuoka, A., & Nakajima, K. (2017). Amorphous Nb2O5 as a Selective and Reusable Catalyst for Furfural Production from Xylose in Biphasic Water and Toluene. ACS Catalysis, 7(4), 2430-2436. doi:10.1021/acscatal.6b03682 | es_ES |
dc.description.references | Marzo, M., Gervasini, A., & Carniti, P. (2012). Improving stability of Nb2O5 catalyst in fructose dehydration reaction in water solvent by ion-doping. Catalysis Today, 192(1), 89-95. doi:10.1016/j.cattod.2011.12.014 | es_ES |
dc.description.references | CARNITI, P., GERVASINI, A., BIELLA, S., & AUROUX, A. (2006). Niobic acid and niobium phosphate as highly acidic viable catalysts in aqueous medium: Fructose dehydration reaction. Catalysis Today, 118(3-4), 373-378. doi:10.1016/j.cattod.2006.07.024 | es_ES |
dc.description.references | Omata, K., Izumi, S., Murayama, T., & Ueda, W. (2013). Hydrothermal synthesis of W–Nb complex metal oxides and their application to catalytic dehydration of glycerol to acrolein. Catalysis Today, 201, 7-11. doi:10.1016/j.cattod.2012.06.004 | es_ES |
dc.description.references | García-Sancho, C., Cecilia, J. A., Moreno-Ruiz, A., Mérida-Robles, J. M., Santamaría-González, J., Moreno-Tost, R., & Maireles-Torres, P. (2015). Influence of the niobium supported species on the catalytic dehydration of glycerol to acrolein. Applied Catalysis B: Environmental, 179, 139-149. doi:10.1016/j.apcatb.2015.05.014 | es_ES |
dc.description.references | Silva, Â., Wilson, K., Lee, A. F., dos Santos, V. C., Cons Bacilla, A. C., Mantovani, K. M., & Nakagaki, S. (2017). Nb2O5/SBA-15 catalyzed propanoic acid esterification. Applied Catalysis B: Environmental, 205, 498-504. doi:10.1016/j.apcatb.2016.12.066 | es_ES |
dc.description.references | Noronha, F. ., Aranda, D. A. ., Ordine, A. ., & Schmal, M. (2000). The promoting effect of Nb2O5 addition to Pd/Al2O3 catalysts on propane oxidation. Catalysis Today, 57(3-4), 275-282. doi:10.1016/s0920-5861(99)00337-5 | es_ES |
dc.description.references | Molina, M. J. C., Granados, M. L., Gervasini, A., & Carniti, P. (2015). Exploitment of niobium oxide effective acidity for xylose dehydration to furfural. Catalysis Today, 254, 90-98. doi:10.1016/j.cattod.2015.01.018 | es_ES |
dc.description.references | Stošić, D., Bennici, S., Rakić, V., & Auroux, A. (2012). CeO2–Nb2O5 mixed oxide catalysts: Preparation, characterization and catalytic activity in fructose dehydration reaction. Catalysis Today, 192(1), 160-168. doi:10.1016/j.cattod.2011.10.040 | es_ES |
dc.description.references | Stošić, D., Bennici, S., Pavlović, V., Rakić, V., & Auroux, A. (2014). Tuning the acidity of niobia: Characterization and catalytic activity of Nb2O5–MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides. Materials Chemistry and Physics, 146(3), 337-345. doi:10.1016/j.matchemphys.2014.03.033 | es_ES |
dc.description.references | Li, H., Fang, Z., Smith, R. L., & Yang, S. (2016). Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials. Progress in Energy and Combustion Science, 55, 98-194. doi:10.1016/j.pecs.2016.04.004 | es_ES |
dc.description.references | Evangelisti, C., Aronica, L. A., Botavina, M., Martra, G., Battocchio, C., & Polzonetti, G. (2013). Chemoselective hydrogenation of halonitroaromatics over γ-Fe2O3-supported platinum nanoparticles: The role of the support on their catalytic activity and selectivity. Journal of Molecular Catalysis A: Chemical, 366, 288-293. doi:10.1016/j.molcata.2012.10.007 | es_ES |
dc.description.references | Emeis, C. A. (1993). Determination of Integrated Molar Extinction Coefficients for Infrared Absorption Bands of Pyridine Adsorbed on Solid Acid Catalysts. Journal of Catalysis, 141(2), 347-354. doi:10.1006/jcat.1993.1145 | es_ES |
dc.description.references | Oberhauser, W., Evangelisti, C., Jumde, R. P., Psaro, R., Vizza, F., Bevilacqua, M., … Serp, P. (2015). Platinum on carbonaceous supports for glycerol hydrogenolysis: Support effect. Journal of Catalysis, 325, 111-117. doi:10.1016/j.jcat.2015.03.003 | es_ES |
dc.description.references | Oberhauser, W., Evangelisti, C., Tiozzo, C., Vizza, F., & Psaro, R. (2016). Lactic Acid from Glycerol by Ethylene-Stabilized Platinum-Nanoparticles. ACS Catalysis, 6(3), 1671-1674. doi:10.1021/acscatal.5b02914 | es_ES |
dc.description.references | La Salvia, N., Delgado, D., Ruiz-Rodríguez, L., Nadji, L., Massó, A., & Nieto, J. M. L. (2017). V- and Nb-containing tungsten bronzes catalysts for the aerobic transformation of ethanol and glycerol. Bulk and supported materials. Catalysis Today, 296, 2-9. doi:10.1016/j.cattod.2017.04.009 | es_ES |
dc.description.references | Fernández-Arroyo, A., Delgado, D., Domine, M. E., & López-Nieto, J. M. (2017). Upgrading of oxygenated compounds present in aqueous biomass-derived feedstocks over NbOx-based catalysts. Catalysis Science & Technology, 7(23), 5495-5499. doi:10.1039/c7cy00916j | es_ES |
dc.description.references | Shannon, R. D. (1976). Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica Section A, 32(5), 751-767. doi:10.1107/s0567739476001551 | es_ES |
dc.description.references | Botella, P., Solsona, B., López Nieto, J. M., Concepción, P., Jordá, J. L., & Doménech-Carbó, M. T. (2010). Mo–W-containing tetragonal tungsten bronzes through isomorphic substitution of molybdenum by tungsten. Catalysis Today, 158(1-2), 162-169. doi:10.1016/j.cattod.2010.05.024 | es_ES |
dc.description.references | Jehng, J. M., & Wachs, I. E. (1991). Structural chemistry and Raman spectra of niobium oxides. Chemistry of Materials, 3(1), 100-107. doi:10.1021/cm00013a025 | es_ES |
dc.description.references | Delgado, D., Fernández-Arroyo, A., Domine, M. E., García-González, E., & López Nieto, J. M. (2019). W–Nb–O oxides with tunable acid properties as efficient catalysts for the transformation of biomass-derived oxygenates in aqueous systems. Catalysis Science & Technology, 9(12), 3126-3136. doi:10.1039/c9cy00367c | es_ES |
dc.description.references | Scotti, N., Dangate, M., Gervasini, A., Evangelisti, C., Ravasio, N., & Zaccheria, F. (2014). Unraveling the Role of Low Coordination Sites in a Cu Metal Nanoparticle: A Step toward the Selective Synthesis of Second Generation Biofuels. ACS Catalysis, 4(8), 2818-2826. doi:10.1021/cs500581a | es_ES |
dc.description.references | Crépeau, G., Montouillout, V., Vimont, A., Mariey, L., Cseri, T., & Maugé, F. (2006). Nature, Structure and Strength of the Acidic Sites of Amorphous Silica Alumina: An IR and NMR Study. The Journal of Physical Chemistry B, 110(31), 15172-15185. doi:10.1021/jp062252d | es_ES |
dc.description.references | Ravindra Reddy, C., Nagendrappa, G., & Jai Prakash, B. S. (2007). Surface acidity study of M+-montmorillonite clay catalysts by FT-IR spectroscopy: Correlation with esterification activity. Catalysis Communications, 8(3), 241-246. doi:10.1016/j.catcom.2006.06.023 | es_ES |
dc.description.references | Gervasini, A., Carniti, P., Bossola, F., Imparato, C., Pernice, P., Clayden, N. J., & Aronne, A. (2018). New Nb-P-Si ternary oxide materials and their use in heterogeneous acid catalysis. Molecular Catalysis, 458, 280-286. doi:10.1016/j.mcat.2017.10.006 | es_ES |
dc.description.references | Carniti, P., Gervasini, A., Bossola, F., & Dal Santo, V. (2016). Cooperative action of Brønsted and Lewis acid sites of niobium phosphate catalysts for cellobiose conversion in water. Applied Catalysis B: Environmental, 193, 93-102. doi:10.1016/j.apcatb.2016.04.012 | es_ES |