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Gas phase dehydration of glycerol to acrolein over WO3-based catalysts prepared by non-hydrolytic sol-gel synthesis

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Gas phase dehydration of glycerol to acrolein over WO3-based catalysts prepared by non-hydrolytic sol-gel synthesis

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dc.contributor.author Nadji, L. es_ES
dc.contributor.author Masso Ramírez, Amada es_ES
dc.contributor.author Delgado-Muñoz, Daniel es_ES
dc.contributor.author Isaadi, R. es_ES
dc.contributor.author Rodríguez-Aguado, E. es_ES
dc.contributor.author Rodriguez-Castellon, E. es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2020-11-11T04:31:52Z
dc.date.available 2020-11-11T04:31:52Z
dc.date.issued 2018 es_ES
dc.identifier.uri http://hdl.handle.net/10251/154795
dc.description.abstract [EN] Solid acid catalysts based on WO3¿SiO2 and WO3¿ZrO2¿SiO2 were prepared by one-pot non-hydrolytic sol¿gel method and tested in the gas phase glycerol dehydration to acrolein. Their structural and textural characteristics were determined by X-ray diffraction (XRD), N2 adsorption, X-ray energy dispersive spectroscopy (XEDS), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). Their acid characteristics were studied by both temperature programmed desorption of ammonia (NH3-TPD) and FTIR of adsorbed pyridine. Under our operating conditions, all the catalysts were active and selective in the transformation of glycerol to acrolein, which was always the main reaction product. The high selectivity to acrolein is achieved on catalysts presenting a higher proportion of Brønsted acid sites. In addition, the role of oxygen in the feed on catalytic performance of these catalysts is also discussed. es_ES
dc.description.sponsorship The authors would like to acknowledge the DGICYT (CTQ2015-68951-C3-1-R, CTQ2015-68951-C3-3-R and SEV-2016-0683) and Secretary of State for International Cooperation in Spain (Project AP/040992/11) and Ministry of Higher Education and Scientific Research of Algeria for the National Exceptional Program for the fellowships. D. D. thanks MINECO and Severo Ochoa Excellence Program for his fellowship (SVP-2014-068669). Authors also would like to thank the Electron Microscopy Service of Universitat Politecnica de Valencia for their support. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof RSC Advances es_ES
dc.rights Reconocimiento (by) es_ES
dc.title Gas phase dehydration of glycerol to acrolein over WO3-based catalysts prepared by non-hydrolytic sol-gel synthesis es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8ra01575a es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MAEC//AP%2F040992%2F11/ES/PREPARACIÓN, CARACTERIZACIÓN Y PROPIEDADES CATALÍTICAS PARA REACCIONES CATALÍTICAS SOSTENIBLES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-3-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SVP-2014-068669/ES/SVP-2014-068669/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-1-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Nadji, L.; Masso Ramírez, A.; Delgado-Muñoz, D.; Isaadi, R.; Rodríguez-Aguado, E.; Rodriguez-Castellon, E.; López Nieto, JM. (2018). Gas phase dehydration of glycerol to acrolein over WO3-based catalysts prepared by non-hydrolytic sol-gel synthesis. RSC Advances. 8(24):13344-13352. https://doi.org/10.1039/c8ra01575a es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8ra01575a es_ES
dc.description.upvformatpinicio 13344 es_ES
dc.description.upvformatpfin 13352 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 24 es_ES
dc.identifier.eissn 2046-2069 es_ES
dc.relation.pasarela S\376755 es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Asuntos Exteriores y Cooperación es_ES
dc.contributor.funder Ministère de l'Enseignement Supérieur et de la Recherche Scientifique, Argelia es_ES
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