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Readily available Ti-beta as an efficient catalyst for greener and sustainable production of campholenic aldehyde

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Readily available Ti-beta as an efficient catalyst for greener and sustainable production of campholenic aldehyde

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dc.contributor.author Puche Panadero, Marta es_ES
dc.contributor.author Velty, Alexandra es_ES
dc.date.accessioned 2020-11-11T04:32:17Z
dc.date.available 2020-11-11T04:32:17Z
dc.date.issued 2019-08-21 es_ES
dc.identifier.issn 2044-4753 es_ES
dc.identifier.uri http://hdl.handle.net/10251/154803
dc.description.abstract [EN] Different Ti-beta zeolite samples were prepared following a convenient and optimized post-synthetic route and starting from commercial Al-beta zeolite. Lewis acid sites have been successfully incorporated into vacant tetrahedral (T)-sites of a dealuminated beta-framework by ball-milling solid-state ion-exchange. A tribology-ball milling process was used in order to increase the interaction between dealuminated-beta zeolite and the Ti-precursor. Thermal treatments with water and aqueous solution of NaNO or Li NO allowed optimization of the catalytic properties of the Ti-Lewis active sites which exhibited excellent catalytic activity and stability for the isomerization of ¿-pinene oxide into campholenic aldehyde in both batch and fixed bed reactor systems. Additionally, the catalytic performance of the post-synthesised Ti-beta zeolite was compared to a Ti-beta zeolite prepared in fluoride media. From different points of view such as preparation of readily, highly active, selective and stable catalysts, throughput, sustainability and cost, herein we report the selective solid catalysed ¿-PO isomerization with excellent results, 88% selectivity and yield, a CA production of 225 g g h and new opportunities. es_ES
dc.description.sponsorship The authors are grateful for financial support from the Spanish Government by MAT2017-82288-C2-1-P and Severo Ochoa Excellence Program SEV-2016-0683. The contribution of Mr. Pablo Ramos to the experimental work is also gratefully acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science & Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Ti-beta zeolite es_ES
dc.subject Ball-milling solid-state ion-exchange es_ES
dc.subject Batch and fixed bed reactor es_ES
dc.subject Isomerization of alpha-pinene oxide into campholenic aldehyde es_ES
dc.subject Excellent results es_ES
dc.subject Catalytic activity es_ES
dc.title Readily available Ti-beta as an efficient catalyst for greener and sustainable production of campholenic aldehyde es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c9cy00957d es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Puche Panadero, M.; Velty, A. (2019). Readily available Ti-beta as an efficient catalyst for greener and sustainable production of campholenic aldehyde. Catalysis Science & Technology. 9(16):4293-4303. https://doi.org/10.1039/c9cy00957d es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c9cy00957d es_ES
dc.description.upvformatpinicio 4293 es_ES
dc.description.upvformatpfin 4303 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 16 es_ES
dc.relation.pasarela S\410676 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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