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dc.contributor.author | Delgado-Muñoz, Daniel | es_ES |
dc.contributor.author | Fernández-Arroyo, Alberto | es_ES |
dc.contributor.author | Domine, Marcelo Eduardo | es_ES |
dc.contributor.author | García-González, Ester | es_ES |
dc.contributor.author | López Nieto, José Manuel | es_ES |
dc.date.accessioned | 2020-11-11T04:32:21Z | |
dc.date.available | 2020-11-11T04:32:21Z | |
dc.date.issued | 2019-06-21 | es_ES |
dc.identifier.issn | 2044-4753 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/154804 | |
dc.description.abstract | [EN] W-Nb-O oxide bronzes, prepared hydrothermally, have been characterized and studied as catalysts for both the gas-phase dehydration of glycerol and the liquid-phase selective condensation of light oxygenates derived from primary treatments of biomass (a mixture containing acetic acid, ethanol, propanal, hydroxyacetone and water). By controlling the nominal composition of the catalysts, it is possible to tune their textural and acid properties (concentration and nature of acid sites) to selectively produce acrolein from glycerol or C-5-C-10 hydrocarbons (with low O contents and with high yields) from light oxygenates. Interestingly, these catalysts are stable when working in gas phase reactions and they are re-usable, with high resistance to leaching, when working in aqueous media. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Government (CTQ-2015-68951-C3-1, CTQ-2015-67592, MAT2016-78362-C4-4-R and SEV-2016-0683) and Generalitat Valenciana (GVA, PROMETEO/2018/006) is gratefully acknowledged. A. F.-A. and D. D. thank the "La Caixa-Severo Ochoa" Foundation and Severo Ochoa Excellence Program (SVP-2016-0683), respectively, for their fellowships. The authors thank the ICTS Centro Nacional de Microscopia Electronica (UCM) for instrumental facilities. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | The Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Catalysis Science & Technology | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | W-Nb-O oxide catalyst | es_ES |
dc.subject | Acid properties | es_ES |
dc.subject | Transformation of biomass-derived oxygenates | es_ES |
dc.subject | Aqueous phase | es_ES |
dc.title | W-Nb-O oxides with tunable acid properties as efficient catalysts for the transformation of biomass-derived oxygenates in aqueous systems | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/c9cy00367c | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-1-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2018%2F006/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2016-78362-C4-4-R/ES/MATERIALES PARA BATERIAS DE LITIO, POST LITIO Y PILAS DE COMBUSTIBLE: DEL LABORATORIO AL PROTOTIPO/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099668-B-C21/ES/VALORIZACION DE CO2: CAPTURA, Y TRANSFORMACION CATALITICA PARA ALMACENAMIENTO DE ENERGIA, COMBUSTIBLES Y PRODUCTOS QUIMICOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-67592-P/ES/VALORIZACION DE COMPUESTO OXIGENADOS PRESENTES EN FRACCIONES ACUOSAS DERIVADAS DE BIOMASA EN COMBUSTIBLES Y PRODUCTOS QUIMICOS/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Delgado-Muñoz, D.; Fernández-Arroyo, A.; Domine, ME.; García-González, E.; López Nieto, JM. (2019). W-Nb-O oxides with tunable acid properties as efficient catalysts for the transformation of biomass-derived oxygenates in aqueous systems. Catalysis Science & Technology. 9(12):3126-3136. https://doi.org/10.1039/c9cy00367c | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1039/c9cy00367c | es_ES |
dc.description.upvformatpinicio | 3126 | es_ES |
dc.description.upvformatpfin | 3136 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 9 | es_ES |
dc.description.issue | 12 | es_ES |
dc.relation.pasarela | S\405396 | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
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